The present invention relates to a process for reducing the amounts of zinc and lead in starting materials comprising iron which comprises the steps of: selectively leaching Zn and Pb comprised in the starting materials by mixing the starting materials with hydrochloric acid and an oxidizing agent comprising at least 5 wt-% of manganese dioxide in one or several reactor(s) at a temperature superior or equal to 35 C. and at a p H comprised between 0.5 and 3.5, filtrating the mixture obtained in order to separate the solid and the filtrate, washing the solid with water, the resulting solid comprising mainly Fe, a reduced amount of Zn and Pb compared to the original starting materials, recovering the filtrate of step b) and the washing water of step c) which comprise chloride, solubilized Zn and Pb in one or several reactor(s), precipitating solubilized Zn, Pb in the recovered filtrate and the washing water by mixing with a neutralizing agent, filtrating and washing the solid residues obtained in step e) in order to remove the chloride from the solid residues which comprise at least Pb and Zn. The present invention also refers to the use of the materials obtained after treatment in a in a sinter plant and blast furnace or in all pyrometallurgical furnace which value iron such as electrical arc furnace (EAF), cupola furnace, oxycup furnace, submerged arc furnace (SAF), a plasma furnace, rotary hearth furnace.

The present invention relates to a process for reducing the amounts of zinc and lead in starting materials comprising iron which comprises the steps of: selectively leaching Zn and Pb comprised in the starting materials by mixing the starting materials with hydrochloric acid and an oxidizing agent comprising at least 5 wt-% of manganese dioxide in one or several reactor(s) at a temperature superior or equal to 35 C. and at a p H comprised between 0.5 and 3.5, filtrating the mixture obtained in order to separate the solid and the filtrate, washing the solid with water, the resulting solid comprising mainly Fe, a reduced amount of Zn and Pb compared to the original starting materials, recovering the filtrate of step b) and the washing water of step c) which comprise chloride, solubilized Zn and Pb in one or several reactor(s), precipitating solubilized Zn, Pb in the recovered filtrate and the washing water by mixing with a neutralizing agent, filtrating and washing the solid residues obtained in step e) in order to remove the chloride from the solid residues which comprise at least Pb and Zn. The present invention also refers to the use of the materials obtained after treatment in a in a sinter plant and blast furnace or in all pyrometallurgical furnace which value iron such as electrical arc furnace (EAF), cupola furnace, oxycup furnace, submerged arc furnace (SAF), a plasma furnace, rotary hearth furnace.

A continuous process for converting metal compound particles into a mixture of elemental metals. Metal compound particles and a reductant are introduced into an ultra-high temperature reaction zone having a temperature greater than 2,700 C. and an oxygen content less than 3 vol. %. The metal compound particles have particle sizes of d90 500 m. The metal compound particles have a residence time less than 1 minute in the ultra-high temperature reaction zone sufficient to mix with and react with the reductant to reduce the metal compound particles to form a mixture of elemental metals. The mixture of elemental metals is removed from the ultra-high temperature reaction zone. One or more elemental metals are separated or concentrated from the mixture of elemental metals within one or more separation zones based on differential size and density of the one or more elemental metals and the remaining mixture of elemental metals.

A continuous process for converting metal compound particles into a mixture of elemental metals. Metal compound particles and a reductant are introduced into an ultra-high temperature reaction zone having a temperature greater than 2,700 C. and an oxygen content less than 3 vol. %. The metal compound particles have particle sizes of d90 500 m. The metal compound particles have a residence time less than 1 minute in the ultra-high temperature reaction zone sufficient to mix with and react with the reductant to reduce the metal compound particles to form a mixture of elemental metals. The mixture of elemental metals is removed from the ultra-high temperature reaction zone. One or more elemental metals are separated or concentrated from the mixture of elemental metals within one or more separation zones based on differential size and density of the one or more elemental metals and the remaining mixture of elemental metals.

A method for recycling processing of dust generated in a converter furnace, includes: crushing and drying a cake formed by adding a binder to a slurry containing iron powder-containing dust that is generated at the time of converter blowing and wet-collected to produce a mixed slurry and subjecting the produced mixed slurry to a dehydration treatment in a filter press; accumulating the cake in an accumulation tank; and charging the cake into a converter furnace 10, the crushed product in the accumulation tank 25 is kept at a temperature of less than 90 C. by forcibly passing air into the accumulation tank 25 and charged into a converter furnace according to the converter operation.

An apparatus for manufacturing molten metal has a stationary electric furnace, a raw material charging chute, and exhaust duct and a secondary combustion burner in the furnace top, and a shock generator. The raw material charging chute is in one end of the furnace in a width direction and an electric heating region is spaced from the raw material charging chute in the width direction. A raw material layer having a sloping surface extends downward from the one end of the furnace having the raw material charging chute toward the electric heating region, the sloping surface supporting a metal agglomerate raw material layer. The shock generator is provided at least partially within the raw material and extends to the sloping surface, to be in contact with the metal agglomerate raw material layer, and to mechanically overcome hanging of the metal agglomerate raw material layer on the sloping surface.

A method of the invention for treatment of particulate material for metal recovery includes heating a furnace to a first temperature, feeding a particulate material into the furnace, and before or after heating of the raw material, feeding a reducing gas flow through the furnace. The particulate material is heated in the furnace for volatilizing one or more metals contained in the ash into the gas flow, and the volatilized particles are recovered in one or more collection units. A system for treatment of particulate material for metal recovery includes a heated furnace for receiving flows of reduction gas and particulate material, a collection unit for volatilized particles, and a collection unit for non-volatilized material.

A method of the invention for treatment of particulate material for metal recovery includes heating a furnace to a first temperature, feeding a particulate material into the furnace, and before or after heating of the raw material, feeding a reducing gas flow through the furnace. The particulate material is heated in the furnace for volatilizing one or more metals contained in the ash into the gas flow, and the volatilized particles are recovered in one or more collection units. A system for treatment of particulate material for metal recovery includes a heated furnace for receiving flows of reduction gas and particulate material, a collection unit for volatilized particles, and a collection unit for non-volatilized material.

Methods and system for recovering metals from combustion ash containing ferrous and nonferrous metals, including the steps of providing a feedstock source of ash, comminuting the ash to substantially reduce the particle size and liberate metal particles therein, separating the metal particles from the comminuted ash by particle size to obtain ash with a reduced metal content, at least one ferrous product and at least one nonferrous product.

Methods and system for recovering metals from combustion ash containing ferrous and nonferrous metals, including the steps of providing a feedstock source of ash, comminuting the ash to substantially reduce the particle size and liberate metal particles therein, separating the metal particles from the comminuted ash by particle size to obtain ash with a reduced metal content, at least one ferrous product and at least one nonferrous product.