A method of recycling a waste of an HSS processing process includes a pre-treating step of pre-treating the waste of the HSS processing process, a primary melting step of forming a primary melt by primarily melting at least one of ferro molybdenum, ferro tungsten, and ferro cobalt and the pre-treated waste of the HSS processing process at 1500 to 2500 degrees Celsius (? C.), and a preparing step of preparing the HSS master alloy by ingot casting the primary melt, wherein the pre-treating step includes: a separating step of separating the waste of the HSS processing process according to a composition, and a mixing step of forming a mixture by mixing oxides containing at least one of K.sub.2O, CaO, MgO, SiO.sub.2, Al.sub.2O.sub.3, and Fe.sub.2O.sub.3 and the separated waste of the HSS processing process with each other, the mixture having a melting point of 800 to 1700? C.

The invention relates to a method for preparing titanium alloys based on aluminothermic self-propagating gradient reduction and slag-washing refining, and belongs to the technical field of titanium-aluminum alloys. The method comprises the following steps of pre-treating raw materials, weighing the raw materials in the mass ratio of rutile or high-titanium slags or titanium dioxide to aluminum powder to V.sub.2O.sub.5 powder to CaO to KClO.sub.3 being 1.0:(0.60-0.24):(0.042-0.048):(0.12-0.26):(0.22-0.30), performing an aluminothermic self-propagating reaction in a gradient feeding manner to obtain high-temperature melt, performing a gradient reduction melting, performing heat insulation and separating the melt after the feeding is completed, then adding CaF.sub.2CaOTiO.sub.2V.sub.2O.sub.5 based refining slags into the high-temperature melt, performing slag washing refining, and finally removing slags to obtain titanium alloys. This method has the advantages including short flow, low energy consumption, easy operation, easy control on Al and V contained in alloys, and so on.

The disclosure relates to a method for concentrating rare earth elements (REEs) from a coal byproduct. The method includes mixing the coal byproduct input with aluminum phosphate, sulfur and/or other compounds used as an additive; heating the coal byproduct input in air for a period of 3 minutes or longer at a temperature above a liquid starting temperature of the coal byproduct input, forming a molten coal byproduct; cooling the molten coal byproduct at a rate slower than critical glass transition cooling rate of the melt, forming REE phosphate product; heating the coal byproduct input above the liquid starting temperature of the coal byproduct after REE phosphate product is formed; and cooling the coal byproduct input at a rate faster than the critical glass transition cooling rate of the melt, minimizing forming unwanted solids.

The disclosure relates to a method for concentrating rare earth elements (REEs) from a coal byproduct. The method includes mixing the coal byproduct input with aluminum phosphate, sulfur and/or other compounds used as an additive; heating the coal byproduct input in air for a period of 3 minutes or longer at a temperature above a liquid starting temperature of the coal byproduct input, forming a molten coal byproduct; cooling the molten coal byproduct at a rate slower than critical glass transition cooling rate of the melt, forming REE phosphate product; heating the coal byproduct input above the liquid starting temperature of the coal byproduct after REE phosphate product is formed; and cooling the coal byproduct input at a rate faster than the critical glass transition cooling rate of the melt, minimizing forming unwanted solids.

The processes can comprise feeding a furnace with a raw material. These materials can contain impurities and valuable metals (base metals, precious metals, platinum group metals, minor metals). The processes can allow the volatilization of arsenic and indium contained therein. Before volatilizing the material, composition of the material is optionally modified so as to obtain a ratio % S/(% (Cu/2)+% Ni+% Co) of about 0.5 to about 2. The processes can comprise feeding a melting device with the depleted material, and with a source of carbon in order to obtain a multi-layer product and an off gas. Before melting the depleted material, the depleted material composition is optionally modified so as to obtain a ratio % S/(% (Cu/2)+% Ni+% Co) of about 0.5 to about 2. Thus, it is possible to recover Cu, Ni and Co as well as several other metals, including In, Ge, Pb, Bi, precious metals and platinum group metals.

The processes can comprise feeding a furnace with a raw material. These materials can contain impurities and valuable metals (base metals, precious metals, platinum group metals, minor metals). The processes can allow the volatilization of arsenic and indium contained therein. Before volatilizing the material, composition of the material is optionally modified so as to obtain a ratio % S/(% (Cu/2)+% Ni+% Co) of about 0.5 to about 2. The processes can comprise feeding a melting device with the depleted material, and with a source of carbon in order to obtain a multi-layer product and an off gas. Before melting the depleted material, the depleted material composition is optionally modified so as to obtain a ratio % S/(% (Cu/2)+% Ni+% Co) of about 0.5 to about 2. Thus, it is possible to recover Cu, Ni and Co as well as several other metals, including In, Ge, Pb, Bi, precious metals and platinum group metals.

A method and an apparatus for recycling magnesium alloy cuttings are provided. A structure of the apparatus includes: a smelting furnace, configured to hold molten magnesium, where the smelting furnace is segmented into a refining chamber and a molten metal tapping chamber in communication with each other; a mixing unit, rotatably disposed in the refining chamber, and configured to generate a sinking whirlpool toward a bottom of the smelting furnace during rotation; and a waste material treatment unit, including a feeding module, where the feeding module includes a material rod capable of continuously rotating and a material channel in communication with the refining chamber, the material rod is configured to drive magnesium cuttings to enter the refining chamber through the material channel, and the material channel is configured to feed a protective gas.

Provided is a method for producing valuable metal from raw materials including, for example, waste lithium ion batteries by a pyrometallurgical method, said method making it possible to efficiently separate manganese included in the raw materials from metal into slag without lowering the valuable metal recovery rate. The present invention is a method for producing valuable metal from raw materials comprising: a reduction melting step for subjecting the raw materials to a reduction melting process so as to obtain a reduction product containing slag and molten metal that contains valuable metal; a slag separation step for recovering the molten metal from the reduction product; and an oxidation purification step for adding silicon dioxide (SiO.sub.2) as flux to the recovered molten metal and performing an oxidation melting process. In the oxidation purification step, SiO.sub.2 is added as the flux such that the SiO.sub.2/MnO weight ratio is 0.4-1.0 in the slag.

Provided is a more efficient dry refining process for improving the recovery rate of phosphorus-free valuable metals from waste lithium ion batteries. The present invention provides a method for recovering valuable metals from waste lithium ion batteries, said method comprises a melting step S4 for melting the waste lithium ion batteries and obtaining a molten substance and a slag separation step S5 for separating slag from the molten substance and recovering an alloy containing valuable metals, wherein in the melting step, flux containing a calcium compound is added to the waste lithium ion batteries such that the mass ratio between silicon dioxide and calcium oxide in the slag becomes 0.50 or less and the mass ratio between calcium oxide and aluminum oxide falls in the range of 0.30 to 2.00.

Provided is a more efficient dry refining process for improving the recovery rate of phosphorus-free valuable metals from waste lithium ion batteries. The present invention provides a method for recovering valuable metals from waste lithium ion batteries, said method comprises a melting step S4 for melting the waste lithium ion batteries and obtaining a molten substance and a slag separation step S5 for separating slag from the molten substance and recovering an alloy containing valuable metals, wherein in the melting step, flux containing a calcium compound is added to the waste lithium ion batteries such that the mass ratio between silicon dioxide and calcium oxide in the slag becomes 0.50 or less and the mass ratio between calcium oxide and aluminum oxide falls in the range of 0.30 to 2.00.