Methods of removing oxygen from a metal are described. In one example, a method (100) can include forming a mixture (110) including a metal, a calcium de-oxygenation agent, and a salt. The mixture can be heated (120) at a de-oxygenation temperature for a period of time to reduce an oxygen content of the metal, thus forming a de-oxygenated metal. The de-oxygenation temperature can be above a melting point of the salt and below a melting point of the calcium de-oxygenation agent. The de-oxygenated metal can then be cooled (130). The de-oxygenated metal can then be leached with water and acid to remove by-products and obtain a product (140).

Systems, methods, and apparatus for treating a molten metal are provided. A metal treatment system, comprising: a wire feeding subsystem; and a cored wire; wherein the wire feeding subsystem feeds the cored wire into a metal bath at a controlled wire feed rate, and wherein the metal bath comprises a molten metal; wherein the cored wire comprises: a consumable outer sheath having a tubular cross section; and a core fill material coupled to an inner surface of the outer sheath, wherein the core fill material comprises a refining agent for refining the molten metal; and wherein the refining agent reacts with the molten metal, thereby causing an impurity to be removable from the metal bath.

Systems, methods, and apparatus for treating a molten metal are provided. A metal treatment system, comprising: a wire feeding subsystem; and a cored wire; wherein the wire feeding subsystem feeds the cored wire into a metal bath at a controlled wire feed rate, and wherein the metal bath comprises a molten metal; wherein the cored wire comprises: a consumable outer sheath having a tubular cross section; and a core fill material coupled to an inner surface of the outer sheath, wherein the core fill material comprises a refining agent for refining the molten metal; and wherein the refining agent reacts with the molten metal, thereby causing an impurity to be removable from the metal bath.

Integrated PGM converting process. The process includes smelting a catalyst material in a primary furnace, smelting the primary furnace slag in a secondary furnace, converting the collector alloys from the primary and secondary furnaces in a converter to recover PGM enriched alloy and converter slag, separating the recovered converter slag into first and second converter slag portions, and supplying the first converter slag portion to the secondary furnace for smelting with the primary furnace slag. The process can also include low- or no-flux converting; refractory protectant addition; magnetic slag separation; partial feed pre-oxidation; staged slagging; and/or jacketing the converter.

Integrated PGM converting process. The process includes smelting a catalyst material in a primary furnace, smelting the primary furnace slag in a secondary furnace, converting the collector alloys from the primary and secondary furnaces in a converter to recover PGM enriched alloy and converter slag, separating the recovered converter slag into first and second converter slag portions, and supplying the first converter slag portion to the secondary furnace for smelting with the primary furnace slag. The process can also include low- or no-flux converting; refractory protectant addition; magnetic slag separation; partial feed pre-oxidation; staged slagging; and/or jacketing the converter.

The process includes melting an initial collector alloy charge to start a converter cycle, introducing feed and injecting oxygen into the alloy pool, allowing ferrous slag to collect, terminating feed introduction and oxygen injection to tap the slag, repeating the feed introduction/oxygen injection/slag tapping sequence a plurality of times, and then tapping the alloy to end the cycle. A delay before non-final slag tappings allows any entrained alloy to settle back into the alloy pool, but the final slag tapping is commenced promptly and alloy is optionally entrained. Slag from the final tapping that may contain entrained alloy can be recycled to the converter, e.g., in a subsequent cycle. The process can also include low- or no-flux converting; refractory protectant addition; slag separation; partial feed pre-oxidation; smelting the slag in a secondary furnace with primary furnace slag; and/or jacketing the converter.

The process includes melting an initial collector alloy charge to start a converter cycle, introducing feed and injecting oxygen into the alloy pool, allowing ferrous slag to collect, terminating feed introduction and oxygen injection to tap the slag, repeating the feed introduction/oxygen injection/slag tapping sequence a plurality of times, and then tapping the alloy to end the cycle. A delay before non-final slag tappings allows any entrained alloy to settle back into the alloy pool, but the final slag tapping is commenced promptly and alloy is optionally entrained. Slag from the final tapping that may contain entrained alloy can be recycled to the converter, e.g., in a subsequent cycle. The process can also include low- or no-flux converting; refractory protectant addition; slag separation; partial feed pre-oxidation; smelting the slag in a secondary furnace with primary furnace slag; and/or jacketing the converter.

Converting process with slag separation and recycle to the converter. The process includes introducing converter feed into the pot holding a molten alloy pool, oxygen injection into the pool, tapping the slag, and tapping the PGM-enriched alloy. The collector alloy contains no less than 0.5 wt % PGM, 40 wt % iron, and 0.5 wt % nickel, and no more than 3 wt % sulfur and 3 wt % copper, and the recovered slag is separated into recycle and non-recycle portions. The recycle slag portion preferably contains more PGM than the non-recycle portion. The process can also include low- or no-flux converting; using a refractory protectant in the converter; magnetic separation of slag; partial pre-oxidation of the converter feed; smelting catalyst material in a primary furnace to produce the collector alloy; and/or smelting the converter slag in a secondary furnace with slag from the primary furnace.

Converting process with slag separation and recycle to the converter. The process includes introducing converter feed into the pot holding a molten alloy pool, oxygen injection into the pool, tapping the slag, and tapping the PGM-enriched alloy. The collector alloy contains no less than 0.5 wt % PGM, 40 wt % iron, and 0.5 wt % nickel, and no more than 3 wt % sulfur and 3 wt % copper, and the recovered slag is separated into recycle and non-recycle portions. The recycle slag portion preferably contains more PGM than the non-recycle portion. The process can also include low- or no-flux converting; using a refractory protectant in the converter; magnetic separation of slag; partial pre-oxidation of the converter feed; smelting catalyst material in a primary furnace to produce the collector alloy; and/or smelting the converter slag in a secondary furnace with slag from the primary furnace.

Converting process with partial pre-oxidation of PGM collector alloy. The process includes partially pre-oxidizing a raw alloy, introducing an initial charge of the partially pre-oxidized alloy into a converter pot, melting the initial charge, introducing converter feed to the pool, oxygen injection into the pool, tapping the slag, and tapping the PGM-enriched alloy. The collector alloy contains no less than 0.5 wt % PGM, 40 wt % iron, and 0.5 wt % nickel, and no more than 3 wt % sulfur and 3 wt % copper. The process can also include low- or no-flux converting; using a refractory protectant in the converter; magnetic separation of slag; recycling part of the slag to the converter; smelting catalyst material in a primary furnace to produce the collector alloy; and/or smelting the converter slag in a secondary furnace with slag from the primary furnace.