In one aspect, the present disclosure pertains to methods of making various noble metal nanoprisms, e.g., gold nanoprisms. In various aspects, the methods can comprise incubating, under dark conditions, a growth solution comprising: (a) a plurality of gold seed structures; (b) a gold precursor, and (c) a photocatalytic intermediary, such that during the incubating step multiply-twinned gold seed structures in the growth solution are preferentially enlarged. The disclosed methods can comprise separating the multiply-twinned gold seed structures from the growth solution based upon the size of the gold seed structures to produce an enriched growth solution. In some aspects, the methods comprise irradiating the enriched growth solution to produce the gold nanoprisms. In some aspects, the disclosed nanoprisms comprise silver.

A process for recovery of one or more elements, selected from precious metals and chalcophile metals, as herein defined, from materials containing precious and/or chalcophile metal/s, said process including: (i) contacting the material with an alkaline solution containing a lixiviant comprising an amino acid, or derivative thereof, and an alkali stable transition metal complex in order to form a leachate containing the precious metal and/or chalcophile metal; and (ii) recovering the precious metal and/or chalcophile metal from the leachate.

A method, and systems in which such method may be practiced, allow for the separation of elemental metals from metal alloy. A metal alloy is atomized to form metal alloy particulates. The metal alloy particulates are exposed to an oxidizing agent, such as chlorine gas in the presence of a salt, such as NaCl, an acid, such as HCl, and water. The resulting solution may be filtered to remove particulates, reduced, filtered, reduced, filtered, and so on. In aspects, the method is used to refine gold alloy by oxidation of elemental sponge gold to gold chloride followed by reduction to pure elemental gold.

A method of recovering gold from gold-containing sulphide minerals in an ore that has a recovery-oxidation curve in a graph of % recovery of gold versus % oxidation of the minerals that has a slope of less than 1:1 in a higher % oxidation part of the curve, includes operating at least one oxidation unit to achieve a target % oxidation for sulphur in the ore that is in a higher oxidation part of the curve and producing an output having liberated gold as a consequence of sulphur oxidation in the oxidation unit and allowing variations of the % oxidation in the oxidation unit during the method.

In one aspect, the present disclosure pertains to methods of making various noble metal nanoprisms, e.g., gold nanoprisms. In various aspects, the methods can comprise incubating, under dark conditions, a growth solution comprising: (a) a plurality of gold seed structures; (b) a gold precursor, and (c) a photocatalytic intermediary, such that during the incubating step multiply-twinned gold seed structures in the growth solution are preferentially enlarged. The disclosed methods can comprise separating the multiply-twinned gold seed structures from the growth solution based upon the size of the gold seed structures to produce an enriched growth solution. In some aspects, the methods comprise irradiating the enriched growth solution to produce the gold nanoprisms. In some aspects, the disclosed nanoprisms comprise silver.

A method for breaking down a mixture, which is present in the form of solid particles, consisting of: (A) 0 to 99% by weight of metallic ruthenium, (B) 0 to 50% by weight of at least one element other than ruthenium, which is present in elementary form, selected from the group of elements of the atomic numbers 13, 21-30, 39-42, 45-52, and 72-83, (C) 0 to 99% by weight of ruthenium oxide, (D) 0 to 70% by weight of at least one solid element oxide other than ruthenium, (E) 0 to 30% by weight of at least one inorganic substance other than (A) to (D), and (F) 0 to 3% by weight of at least one organic substance, wherein the sum of the % by weight of the compounds (A) to (F) is 100% by weight and the ruthenium content of the mixture is 2 to 99% by weight, and wherein the method comprises the steps of: (1) optionally mixing said mixture with alkali carbonate by forming a blend, (2) alkaline oxidizing breakdown of the mixture or of the blend, respectively, formed in optional step (1) into molten potassium hydroxide using a gaseous oxidizing agent selected from the group consisting of air, oxygen, and air/oxygen mixtures, and without use of nitrate, and (3) cooling down the breakdown material formed in step (2) to a temperature below its solidification temperature, wherein the gaseous oxidizing agent is introduced into the melt in step (2).

The present disclosure provides a method of recovering copper, molybdenum, and a precious metal value from a metal-bearing material, the method comprising bulk flotation of the metal-bearing material to form a flotation product, wherein the metal-bearing material comprises a copper compound, a molybdenum compound, and at least one precious metal value, pressure oxidizing the flotation product to form a pressure oxidized discharge, separating the pressure oxidized discharge to form a separated liquid and separated solid, extracting molybdenum, via a molybdenum solution extraction, from the separated liquid to form a molybdenum-containing stream and a copper-containing stream, extracting copper, via a copper solution extraction, from the copper-containing stream, and extracting the precious metal value, via a cyanide leaching process, from the separated solid.

In described embodiments, a process for recovery of a metal from a grounded ore comprises leaching the grounded ore with a leaching reagent, an oxidant and an oxygen vector. In particular, a process for recovery of gold from a grounded gold ore, comprises leaching the grounded gold ore with a cyanide salt, an oxidant and an oxygen vector. The oxygen vector is selected from dodecane, decane, hexadecane, or the like.

The present disclosure provides a method of recovering copper, molybdenum, and a precious metal value from a metal-bearing material, the method comprising bulk flotation of the metal-bearing material to form a flotation product, wherein the metal-bearing material comprises a copper compound, a molybdenum compound, at least one precious metal value, and a silicate, pressure oxidizing the flotation product to form a pressure oxidized discharge, separating the pressure oxidized discharge to form a separated liquid and separated solid, extracting molybdenum, via a molybdenum solution extraction, from the separated liquid to form a molybdenum-containing stream and a copper-containing stream, extracting copper, via a copper solution extraction, from the copper-containing stream, and extracting the precious metal value, via a cyanide leaching process, from the separated solid.

An adsorbent composition comprising particles consisting of a core which is at least partially coated with an adsorbent material is disclosed. The core is selected so that it has at least one of: (i) wear resistance; (ii) resistance to corrosive conditions; (iii) at least one thermoplastic material; and (iv) a low porosity. A suitable core material is polystyrene. Adsorbent materials suitable for the coating include activated carbon and metal oxides such as silica and alumina. The adsorbent composition may be used for the adsorption of metals and metal ions in ore processing, for instance for the separation of precious metals such as gold.