The method for recovering lithium hydroxide from a lithium secondary battery allows a powder comprising lithium and valuable metals to be prepared from the lithium secondary battery. The powder is reduced to form a preliminary precursor mixture including a preliminary lithium precursor and valuable metal-containing particles. The preliminary precursor mixture is primarily washed with water (H.sub.2O) to generate a lithium precursor aqueous solution and a precipitate. The lithium precursor is recovered through solid-liquid separation of the lithium precursor aqueous solution and the precipitate. The lithium precursor is recovered, through additional washing and solid-liquid separation, from the precipitate obtained through the solid-liquid separation. A calcium compound is added in the primary washing operation or the additional washing operation. Therefore, a highly-pure lithium precursor can be obtained without a complex leaching process and additional processes resulting from a wet process of an acid solution.

The present invention relates to a method for obtaining calcium aluminates for metallurgical use from non-saline aluminum slags by means of reactive grinding and thermal treatment.

The present invention relates to a method for obtaining calcium aluminates for metallurgical use from non-saline aluminum slags by means of reactive grinding and thermal treatment.

A process and system are disclosed for producing a lithium product from a solution comprising lithium nitrate. The solution comprising lithium nitrate can be obtained by reacting a lithium-containing metal silicate with nitric acid. The process and system comprise subjecting the solution comprising lithium nitrate to a first thermal treatment procedure (in one or more heated vessels) in which water and nitric acid (when present) are removed, and whereby a resultant lithium nitrate-rich crystal slurry is heated to produce a molten liquid. The process and system also comprise passing the molten liquid to a second thermal treatment procedure (in a further-heated vessel) in which the molten liquid is heated to substantially decompose lithium nitrate to lithium oxide.

A process and system are disclosed for producing a lithium product from a solution comprising lithium nitrate. The solution comprising lithium nitrate can be obtained by reacting a lithium-containing metal silicate with nitric acid. The process and system comprise subjecting the solution comprising lithium nitrate to a first thermal treatment procedure (in one or more heated vessels) in which water and nitric acid (when present) are removed, and whereby a resultant lithium nitrate-rich crystal slurry is heated to produce a molten liquid. The process and system also comprise passing the molten liquid to a second thermal treatment procedure (in a further-heated vessel) in which the molten liquid is heated to substantially decompose lithium nitrate to lithium oxide.

An alumina- or magnesia-reducing process in which a greenhouse gas or substance harmful to the human body is not emitted, which can achieve improved energy efficiency in comparison with the Hall-Heroult or Pidgeon methods. The process includes: introducing an alumina or magnesia powder with a carrier gas to the upstream side of a throat provided on a reducing unit; pressure-transferring the powder and carrier gas to the throat by an operative gas introduced to the upstream side of the throat; irradiating the throat with a laser beam to convert the alumina or magnesia into a plasma state and dissociate the alumina or magnesia thermally; jetting the thermally dissociated product through a nozzle provided on the downstream side of the throat at a supersonic speed to form a frozen flow; and isolating aluminum or magnesium. Hydrogen may be added to the operative gas to accelerate the reduction of alumina or magnesia.

An alumina- or magnesia-reducing process in which a greenhouse gas or substance harmful to the human body is not emitted, which can achieve improved energy efficiency in comparison with the Hall-Heroult or Pidgeon methods. The process includes: introducing an alumina or magnesia powder with a carrier gas to the upstream side of a throat provided on a reducing unit; pressure-transferring the powder and carrier gas to the throat by an operative gas introduced to the upstream side of the throat; irradiating the throat with a laser beam to convert the alumina or magnesia into a plasma state and dissociate the alumina or magnesia thermally; jetting the thermally dissociated product through a nozzle provided on the downstream side of the throat at a supersonic speed to form a frozen flow; and isolating aluminum or magnesium. Hydrogen may be added to the operative gas to accelerate the reduction of alumina or magnesia.

A process and system are disclosed for producing a lithium product from a solution comprising lithium nitrate. The solution comprising lithium nitrate can be obtained by reacting a lithium-containing metal silicate with nitric acid. The process and system comprise subjecting the solution comprising lithium nitrate to a first thermal treatment procedure (in one or more heated vessels) in which water and nitric acid (when present) are removed, and whereby a resultant lithium nitrate-rich crystal slurry is heated to produce a molten liquid. The process and system also comprise passing the molten liquid to a second thermal treatment procedure (in a further-heated vessel) in which the molten liquid is heated to substantially decompose lithium nitrate to lithium oxide.

The present invention concerns a process for the recovery of metals and of heat from spent rechargeable batteries, in particular from spent Li-ion batteries containing relatively low amounts of cobalt. It has in particular been found that such cobalt-depleted Li-ion batteries can be processed on a copper smelter by: feeding a useful charge and slag formers to the smelter; adding heating and reducing agents; whereby at least part of the heating and/or reducing agents is replaced by Li-ion batteries containing one or more of metallic Fe, metallic Al, and carbon. Using spent LFP or LMO batteries as a feed on the Cu smelter, the production rate of Cu blister is increased, while the energy consumption from fossil sources is decreased.

The present invention concerns a process for the recovery of metals and of heat from spent rechargeable batteries, in particular from spent Li-ion batteries containing relatively low amounts of cobalt. It has in particular been found that such cobalt-depleted Li-ion batteries can be processed on a copper smelter by: feeding a useful charge and slag formers to the smelter; adding heating and reducing agents; whereby at least part of the heating and/or reducing agents is replaced by Li-ion batteries containing one or more of metallic Fe, metallic Al, and carbon. Using spent LFP or LMO batteries as a feed on the Cu smelter, the production rate of Cu blister is increased, while the energy consumption from fossil sources is decreased.