Patent classifications
C22B23/02
Recovery of nickel and cobalt from Li-ion batteries or their waste
The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
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This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.
Recovery of nickel and cobalt from Li-ion batteries or their waste
The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
##STR00001##
##STR00002##
##STR00003##
##STR00004##
##STR00005##
##STR00006##
This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.
METHOD FOR RECOVERING VALUABLE METAL
Provided is a method that allows for efficient removal of an impurity metal, and further, the recovery of a valuable metal with high efficiency. The method for recovering a valuable metal (Cu, Ni, and Co) includes the steps of: preparing a charge comprising at least a valuable metal as a raw material; heating and melting the raw material to form an alloy and a slag; and separating the slag to recover the alloy containing the valuable metal, wherein the heating and melting of the raw material comprises charging the raw material into a furnace of an electric furnace equipped with an electrode therein, and further melting the raw material by means of Joule heat generated by applying an electric current to the electrode, or heat generation of an arc itself, and thereby separating the raw material into a molten alloy and a molten slag present over the alloy.
METHOD FOR RECOVERING VALUABLE METAL
Provided is a method that allows for efficient removal of an impurity metal, and further, the recovery of a valuable metal with high efficiency. The method for recovering a valuable metal (Cu, Ni, and Co) includes the steps of: preparing a charge comprising at least a valuable metal as a raw material; heating and melting the raw material to form an alloy and a slag; and separating the slag to recover the alloy containing the valuable metal, wherein the heating and melting of the raw material comprises charging the raw material into a furnace of an electric furnace equipped with an electrode therein, and further melting the raw material by means of Joule heat generated by applying an electric current to the electrode, or heat generation of an arc itself, and thereby separating the raw material into a molten alloy and a molten slag present over the alloy.
PROCESSING THERMALLY PRETREATED AND UNTREATED BATTERIES AND THEIR PRODUCTION REJECTS
Embodiments of the present invention relate to a system for processing battery waste. The system comprises a decomposing device for mechanically decomposing the battery waste to a, in particular strip-shaped or flake-shaped, lightweight portion and a heavyweight portion. The decomposing device comprises an outlet for commonly discharging the lightweight portion and the heavyweight portion. The system further comprises a separating unit for separating the lightweight portion from the heavyweight portion, wherein the separating unit is coupled with the decomposing device for receiving the lightweight portion and the heavyweight portion. The system further comprises a fiber compactor unit, wherein the fiber compactor unit is coupled with the separating unit for receiving the lightweight portion. The fiber compactor unit is configured for compacting the lightweight portion under a separation of a further active material.
PROCESSING THERMALLY PRETREATED AND UNTREATED BATTERIES AND THEIR PRODUCTION REJECTS
Embodiments of the present invention relate to a system for processing battery waste. The system comprises a decomposing device for mechanically decomposing the battery waste to a, in particular strip-shaped or flake-shaped, lightweight portion and a heavyweight portion. The decomposing device comprises an outlet for commonly discharging the lightweight portion and the heavyweight portion. The system further comprises a separating unit for separating the lightweight portion from the heavyweight portion, wherein the separating unit is coupled with the decomposing device for receiving the lightweight portion and the heavyweight portion. The system further comprises a fiber compactor unit, wherein the fiber compactor unit is coupled with the separating unit for receiving the lightweight portion. The fiber compactor unit is configured for compacting the lightweight portion under a separation of a further active material.
PROCESS FOR SEPARATING A MIXURE OF OXALATES OF TWO OR MORE OF NI, CO, AND MN
The present disclosure is directed to processes for separating a mixture of oxalates of two or more of Ni (nickel), Co (cobalt) and Mn (manganese). Such processes are useful, for example, to separate recovery of two or more of Ni, Co and Mn from used ithium ion batteries or from waste of the production of lithium ion batteries or of cells or components of lithium ion batteries.
METHOD OF RECYCLING NICKEL FROM WASTE BATTERY MATERIAL
A method is described for recycling nickel from waste battery material. The method includes providing waste battery material comprising a nickel-containing oxide, reducing the nickel in the waste battery material to the zero oxidation state to provide a reduced waste battery material, reacting the reduced waste battery material with carbon monoxide to form Ni(CO).sub.4, and reacting the Ni(CO).sub.4 with a source of sulfate to form NiSO.sub.4. The NiSO.sub.4 product is useful as a nickel feedstock in various processes which require a nickel source, including processes which prepare new battery materials.
LOW TEMPERATURE REDUCTION OF METAL OXIDES
Disclosed herein is a method for reducing a metal oxide in a metal containing precursor. The method comprises providing a reaction mixture comprising the metal oxide containing precursorand an aluminium reductant; heating the reaction mixture in the presence of solid or gaseous aluminium chloride to temperature at which reactionsthatresultin the metal oxide being reduced are initiated; controlling reaction conditions whereby the reaction mixture is prevented from reaching a temperature at which thermal runaway can occur; and isolating reaction products that include reduced metal oxide.
LOW TEMPERATURE REDUCTION OF METAL OXIDES
Disclosed herein is a method for reducing a metal oxide in a metal containing precursor. The method comprises providing a reaction mixture comprising the metal oxide containing precursorand an aluminium reductant; heating the reaction mixture in the presence of solid or gaseous aluminium chloride to temperature at which reactionsthatresultin the metal oxide being reduced are initiated; controlling reaction conditions whereby the reaction mixture is prevented from reaching a temperature at which thermal runaway can occur; and isolating reaction products that include reduced metal oxide.