A disclosed process produces at least one concentrated copper product together with at least one crude solder product, starting from a black copper composition with at least 50% of copper together with at least 1.0% wt of tin and at least 1.0% wt of lead The process includes the step of partially oxidizing the black copper thereby forming a first copper refining slag, followed by partially reducing the first copper refining slag to form a first lead-tin based metal composition and a first spent slag. The total feed to the reducing step includes an amount of copper that is at least 1.5 times as high as the sum of the amounts of Sn plus Pb present, and the first spent slag includes at most 20% wt total of copper, tin and lead together.

A method, apparatus and system for processing a composite waste source, such as e-waste, is disclosed. The composite waste source may comprise low-, moderate and high-melting point constituents, such as plastics, metals and ceramics. The composite waste source is heated to a first temperature zone, causing at least some of the low-melting point constituents to at least partially thermally transform. The composite waste source is subsequently heated to a second, higher, temperature zone, causing at least some of the moderate-melting point constituents to at least partially thermally transform. At least some of the at least partially thermally transformed constituents may be recovered. The method, apparatus and system disclosed may provide for the recovery and reuse of materials which would otherwise be sent to landfill or incinerated.

A method, apparatus and system for processing a composite waste source, such as e-waste, is disclosed. The composite waste source may comprise low-, moderate and high-melting point constituents, such as plastics, metals and ceramics. The composite waste source is heated to a first temperature zone, causing at least some of the low-melting point constituents to at least partially thermally transform. The composite waste source is subsequently heated to a second, higher, temperature zone, causing at least some of the moderate-melting point constituents to at least partially thermally transform. At least some of the at least partially thermally transformed constituents may be recovered. The method, apparatus and system disclosed may provide for the recovery and reuse of materials which would otherwise be sent to landfill or incinerated.

A disclosed dilute copper metal composition has 57-85% wt Cu, ≥3.0% wt Ni, ≤0.8% wt Fe, 7-25% wt Sn and 3-15% wt Pb. A process includes partially b) oxidizing a black copper composition to obtain a first copper refining slag and a first enriched copper metal. The process further includes oxidizing h) the first enriched copper metal to obtain a second copper refining slag, whereby at least 37.0% wt of the amount of tin and lead processed through steps b) and/or h) is retrieved in the first and second copper refining slags together, partially reducing c) the first copper refining slag to form a first lead-tin based metal composition and a first spent slag, adding the second copper refining slag to the first lead-tin based metal composition thereby forming a first liquid bath, partially oxidizing d) the first liquid bath, thereby obtaining the dilute copper metal composition.

A process for a producing crude solder product and a copper product includes the steps of providing a black copper comprising >=50% wt of copper together with >=1.0% wt of tin and/or >=1.0% wt of lead, and refining a first portion of the black copper to obtain a refined copper product together with at least one copper refining slag. The process further includes the steps of recovering a first crude solder product from the copper refining slag, thereby forming a solder refining slag in equilibrium with the first crude solder product, and contacting a different portion of the black copper with the solder refining slag thereby forming a spent slag and a lead-tin based metal, followed by separating the spent slag from the lead-tin based metal.

A process for a producing crude solder product and a copper product includes the steps of providing a black copper comprising >=50% wt of copper together with >=1.0% wt of tin and/or >=1.0% wt of lead, and refining a first portion of the black copper to obtain a refined copper product together with at least one copper refining slag. The process further includes the steps of recovering a first crude solder product from the copper refining slag, thereby forming a solder refining slag in equilibrium with the first crude solder product, and contacting a different portion of the black copper with the solder refining slag thereby forming a spent slag and a lead-tin based metal, followed by separating the spent slag from the lead-tin based metal.

A process for producing a solder product and a copper product from a first lead-tin based metal composition having at least 40% wt of copper and at least 5.0% wt together of tin and lead. The process includes the steps of partially oxidizing a first liquid bath having the first lead-tin based metal composition, thereby forming a first dilute copper metal composition and a first solder refining slag, followed by separating the slag from the metal composition, and partially oxidizing a second liquid bath having the first dilute copper metal composition, thereby forming a first high-copper metal composition and a third solder refining slag, followed by separating the third solder refining slag from the first high-copper metal composition,
whereby the solder product is derived from the first solder refining slag.

A process for producing a solder product and a copper product from a first lead-tin based metal composition having at least 40% wt of copper and at least 5.0% wt together of tin and lead. The process includes the steps of partially oxidizing a first liquid bath having the first lead-tin based metal composition, thereby forming a first dilute copper metal composition and a first solder refining slag, followed by separating the slag from the metal composition, and partially oxidizing a second liquid bath having the first dilute copper metal composition, thereby forming a first high-copper metal composition and a third solder refining slag, followed by separating the third solder refining slag from the first high-copper metal composition,
whereby the solder product is derived from the first solder refining slag.

A disclosed process produces at least one concentrated copper product together with at least one crude solder product, starting from a black copper composition with at least 50% of copper together with at least 1.0% wt of tin and at least 1.0% wt of lead The process includes the step of partially oxidizing the black copper thereby forming a first copper refining slag, followed by partially reducing the first copper refining slag to form a first lead-tin based metal composition and a first spent slag. The total feed to the reducing step includes an amount of copper that is at least 1.5 times as high as the sum of the amounts of Sn plus Pb present, and the first spent slag includes at most 20% wt total of copper, tin and lead together.

A disclosed process produces at least one concentrated copper product together with at least one crude solder product, starting from a black copper composition with at least 50% of copper together with at least 1.0% wt of tin and at least 1.0% wt of lead The process includes the step of partially oxidizing the black copper thereby forming a first copper refining slag, followed by partially reducing the first copper refining slag to form a first lead-tin based metal composition and a first spent slag. The total feed to the reducing step includes an amount of copper that is at least 1.5 times as high as the sum of the amounts of Sn plus Pb present, and the first spent slag includes at most 20% wt total of copper, tin and lead together.