A method and system is provided to separate calcium carbonate inorganic eggshell from the inner lining of organic protein-based membrane in eggshell by-product. The method involves three phases: mechanical agitation/separation, functional chemical digestion and refining chemical digestion. In the mechanical stage, agitation and sieving are used to remove large pieces, and the majority of, membrane material. In the functional chemical digestion stage, the by-product is processed through at least one basic solution to remove additional organic membrane and impurities. In the refining chemical digestion stage, the remaining organic membrane and impurities are removed. The purified calcium carbonate is then rinsed and dried, in preparation for further refinement and processing to finished goods specifications.

The main purpose of the invention is to provide a method for recovery of cathode materials, cathode materials and electric vehicles. The method for recovery of cathode materials comprises the following steps: step 1, adding cathode materials and a metal reducing agent (MRA) to a molten salt (MS), the cathode materials and the MRA performing a reduction reaction in MS to obtain precipitates and MS solutions. By using the method for recovery of cathode materials of the present invention, main metal elements in cathode materials of a secondary battery are effectively recovered, and compared with pyrometallurgical or hydrometallurgical methods in the prior art, the recovery rate of a metal mixture can reach unexpected 90% or more. Furthermore, the method of the present invention is environmentally friendly, all raw materials can be recycled and reused and no exhaust gases or waste liquids contaminating the environment are discharged.

The main purpose of the invention is to provide a method for recovery of cathode materials, cathode materials and electric vehicles. The method for recovery of cathode materials comprises the following steps: step 1, adding cathode materials and a metal reducing agent (MRA) to a molten salt (MS), the cathode materials and the MRA performing a reduction reaction in MS to obtain precipitates and MS solutions. By using the method for recovery of cathode materials of the present invention, main metal elements in cathode materials of a secondary battery are effectively recovered, and compared with pyrometallurgical or hydrometallurgical methods in the prior art, the recovery rate of a metal mixture can reach unexpected 90% or more. Furthermore, the method of the present invention is environmentally friendly, all raw materials can be recycled and reused and no exhaust gases or waste liquids contaminating the environment are discharged.

In a method of recovering a transition metal from a lithium secondary battery, a an acidic solution is added to a recovery target material containing a transition metal to form a leachate. A basic compound is added to the leachate in an amount of 0.5 wt % to 1.9 wt % based on a total weight of the leachate to form a first transition metal solution. A fluorine compound is added to the first transition metal solution to form a second transition metal solution.

In a method of recovering a transition metal from a lithium secondary battery, a an acidic solution is added to a recovery target material containing a transition metal to form a leachate. A basic compound is added to the leachate in an amount of 0.5 wt % to 1.9 wt % based on a total weight of the leachate to form a first transition metal solution. A fluorine compound is added to the first transition metal solution to form a second transition metal solution.

The present relates to a method for producing calcium sulfate solid crystals and hydrochloric acid (HCl) from a calcium chloride solution comprising the steps of feeding a continuous stirred-tank reactor with a calcium chloride solution, sulfuric acid and water; mixing the calcium chloride solution, sulfuric acid and water in the reactor; and maintaining the reactor a temperature of less than about 70 C., converting the calcium chloride solution, sulfuric acid and water into HCl and calcium sulfate solid crystals. The method described herein can be incorporated as a means for regenerating HCl from CaCl.sub.2 solutions which are generated in the metallurgical industry when processing calcium-bearing ores for recovering metals like rare earth elements.

Submersible media filters and submersible columns for use in removing radioactive isotopes and other contaminants from a fluid stream, such as a fluid stream from the primary coolant loop of a nuclear reactor system or a fluid stream from a spent-fuel pool. Generally, these submersible media filters and submersible columns are adapted to be submersed in the fluid stream, and additionally the filters are adapted to be vitrified after use, resulting in a stabilized, non-leaching final waste product with a substantially reduced volume compared to the original filter. In several embodiments, the submersible media filters and submersible columns include isotope-specific media (ISM).

Submersible media filters and submersible columns for use in removing radioactive isotopes and other contaminants from a fluid stream, such as a fluid stream from the primary coolant loop of a nuclear reactor system or a fluid stream from a spent-fuel pool. Generally, these submersible media filters and submersible columns are adapted to be submersed in the fluid stream, and additionally the filters are adapted to be vitrified after use, resulting in a stabilized, non-leaching final waste product with a substantially reduced volume compared to the original filter. In several embodiments, the submersible media filters and submersible columns include isotope-specific media (ISM).

Hydrometallurgical systems, methods, and compositions are described in which organic amine-based lixiviants are utilized in the selective recovery of alkaline earth elements. The lixiviant can be regenerated and recycled for use in subsequent iterations of the process. Multiple alkaline earth elements can be recovered from a sample in parallel or in serial applications of the disclosed methods.

Hydrometallurgical systems, methods, and compositions are described in which organic amine-based lixiviants are utilized in the selective recovery of alkaline earth elements. The lixiviant can be regenerated and recycled for use in subsequent iterations of the process. Multiple alkaline earth elements can be recovered from a sample in parallel or in serial applications of the disclosed methods.