A galvannealed steel sheet includes a zinc coating layer containing 7 to 15% Fe on the surface of steel sheet including, C: 0.02% to 0.30%, Si: 0.01% to 2.5%, Mn: 0.1% to 3.0%, P: 0.003% to 0.08%, S: not more than 0.01%, Al: 0.001% to 0.20%, one or more selected from Ti: 0.03% to 0.40%, Nb: 0.001% to 0.2%, V: 0.001% to 0.2%, Mo: 0.01% to 0.5% and W: 0.001% to 0.2%. In the zinc coating layer, carbides with average particle size of 1 nm to 20 nm including one or more selected from titanium, niobium, vanadium, molybdenum and tungsten are present with a density of five or more particles per segment that is defined by the thickness of the coating layer and also by dividing a cross section of the coating layer at intervals of 1 μm in a direction perpendicular to the thickness of the coating layer.

A galvannealed steel sheet includes a zinc coating layer containing 7 to 15% Fe on the surface of steel sheet including, C: 0.02% to 0.30%, Si: 0.01% to 2.5%, Mn: 0.1% to 3.0%, P: 0.003% to 0.08%, S: not more than 0.01%, Al: 0.001% to 0.20%, one or more selected from Ti: 0.03% to 0.40%, Nb: 0.001% to 0.2%, V: 0.001% to 0.2%, Mo: 0.01% to 0.5% and W: 0.001% to 0.2%. In the zinc coating layer, carbides with average particle size of 1 nm to 20 nm including one or more selected from titanium, niobium, vanadium, molybdenum and tungsten are present with a density of five or more particles per segment that is defined by the thickness of the coating layer and also by dividing a cross section of the coating layer at intervals of 1 μm in a direction perpendicular to the thickness of the coating layer.

Provided is a high-strength hot-dip galvanized steel sheet having excellent plating adhesion, formability, and hole expandability with an ultimate tensile strength of 980 MPa or more, the hot-dip galvanized steel sheet comprising a hot-dip galvanized layer formed on a surface of a base steel sheet. The base steel sheet contains, by mass %, C: 0.05% to 0.4 %; Si: 0.01% to 3.0%; Mn: 0.1% to 3.0%; Al: 0.01 to 2.0%; in which Si+Al >0.5%, P: limited to 0.04% or less; S: limited to 0.05% or less; N: limited to 0.01% or less; and a balance including Fe and inevitable impurities, a microstructure of the base steel sheet contains 40% or more by total volume fraction of martensite and bainite, 8% or more by volume fraction of residual austenite, and a balance of the microstructure being ferrite or ferrite and 10% or less by volume fraction of pearlite. The martensite contains 10% or more by total volume fraction of two or more kinds of three kinds of martensites (1), (2), and (3), and the hot-dip galvanized layer contains less than 7 mass % of Fe.

Provided is a high-strength hot-dip galvanized steel sheet having excellent plating adhesion, formability, and hole expandability with an ultimate tensile strength of 980 MPa or more, the hot-dip galvanized steel sheet comprising a hot-dip galvanized layer formed on a surface of a base steel sheet. The base steel sheet contains, by mass %, C: 0.05% to 0.4 %; Si: 0.01% to 3.0%; Mn: 0.1% to 3.0%; Al: 0.01 to 2.0%; in which Si+Al >0.5%, P: limited to 0.04% or less; S: limited to 0.05% or less; N: limited to 0.01% or less; and a balance including Fe and inevitable impurities, a microstructure of the base steel sheet contains 40% or more by total volume fraction of martensite and bainite, 8% or more by volume fraction of residual austenite, and a balance of the microstructure being ferrite or ferrite and 10% or less by volume fraction of pearlite. The martensite contains 10% or more by total volume fraction of two or more kinds of three kinds of martensites (1), (2), and (3), and the hot-dip galvanized layer contains less than 7 mass % of Fe.

A high-strength hot-dip galvanized steel sheet and a method for manufacturing the steel sheet are provided. The high-strength hot-dip galvanized steel sheet has a specific composition including C, Si, Mn, etc. In this chemical composition, the content of Ti [Ti] and the content of N [N] satisfy [Ti]>4[N]. The high-strength hot-dip galvanized steel sheet has a microstructure including martensite at an area fraction of 60% or more and 90% or less, polygonal ferrite at an area fraction of more than 5% and 40% or less, and retained austenite at an area fraction of less than 3% (including 0%). The average hardness of the martensite is 450 or more and 600 or less in terms of Vickers hardness, and the average crystal grain diameter of the martensite is 10 μm or less. The standard deviation of the crystal grain diameters of the martensite is 4.0 μm or less.

A spot welded member includes a spot weld formed by holding a sheet stack of multiple steel sheets between a pair of electrodes and spot-welding the sheet stack, in which at least one of the multiple steel sheets is a high-strength zinc-based coated steel sheet having a tensile strength of 780 MPa or more, the high-strength zinc-based coated steel sheet having a coating with an Al content of 0.5% or more by mass, and in which the heat shock region of the spot weld outwardly extending from an edge of a corona bond area includes a coated layer including an FeAl alloy layer having an average thickness of 0.3 μm or more and a zinc-based coated layer having an average thickness of 2.0 μm or more on the FeAl alloy layer at the interface between the base steel sheet of the high-strength zinc-based coated steel sheet and the coating.

A spot welded member includes a spot weld formed by holding a sheet stack of multiple steel sheets between a pair of electrodes and spot-welding the sheet stack, in which at least one of the multiple steel sheets is a high-strength zinc-based coated steel sheet having a tensile strength of 780 MPa or more, the high-strength zinc-based coated steel sheet having a coating with an Al content of 0.5% or more by mass, and in which the heat shock region of the spot weld outwardly extending from an edge of a corona bond area includes a coated layer including an FeAl alloy layer having an average thickness of 0.3 μm or more and a zinc-based coated layer having an average thickness of 2.0 μm or more on the FeAl alloy layer at the interface between the base steel sheet of the high-strength zinc-based coated steel sheet and the coating.

A method for creating a bonded zinc-coated structure is provided. In another aspect, a sheet metal joining system includes a heated roller contacting a sheet metal workpiece to braze together zinc-based coatings. A further aspect employs a zinc coated metal sandwich including a core having peaks and valleys.

A method for creating a bonded zinc-coated structure is provided. In another aspect, a sheet metal joining system includes a heated roller contacting a sheet metal workpiece to braze together zinc-based coatings. A further aspect employs a zinc coated metal sandwich including a core having peaks and valleys.

A high-strength galvanized steel sheet comprising a cold-rolled steel sheet, an intermetallic compound formed on the cold-rolled steel sheet, and a galvanizing layer formed on the intermetallic compound, the cold-rolled steel sheet having a specific composition and a microstructure having a martensite area ratio of 7% or more and less than 25% and a ferrite area ratio of 50% or more and which includes a base metal surface portion in which the amount of internal oxides per single side is 0.05 g/m.sup.2 or less.