A press hardening method including the following steps: A. the provision of a steel sheet for heat treatment being optionally coated with a zinc- or aluminum-based pre-coating, B. the flexible rolling of the steel sheet in the rolling direction so as to obtain a steel sheet having a variable thickness, C. the cutting of the rolled steel sheet to obtain a tailored rolled blank, D. the deposition of a hydrogen barrier pre-coating over a thickness from 10 to 550 nm, E. the heat treatment of the tailored rolled blank to obtain a fully austenitic microstructure in the steel, F. the transfer of the tailored rolled blank into a press tool, G. the hot-forming of the tailored rolled blank to obtain a part having a variable thickness,H. the cooling of the part having a variable thickness obtained at step G).

A zinc spraying material comprises a zinc material containing zinc; and a sulfate salt whose solubility in water is 1/8 or more of the solubility of calcium sulfate. The content of the sulfate salt in the zinc spraying material can be 0.006 to 0.14 mol based on 100 g of the content of the zinc material. Note that the sulfate salt can be at least one of potassium sulfate, sodium sulfate, magnesium sulfate, calcium sulfate, ferric sulfate, ferrous sulfate, lithium sulfate, calcium sulfate, and aluminum sulfate. Also, the zinc material is zinc. Alternatively, the zinc material can also be a zinc alloy containing zinc as the main component and at least one metal selected from aluminum and magnesium.

A zinc spraying material comprises a zinc material containing zinc; and a sulfate salt whose solubility in water is 1/8 or more of the solubility of calcium sulfate. The content of the sulfate salt in the zinc spraying material can be 0.006 to 0.14 mol based on 100 g of the content of the zinc material. Note that the sulfate salt can be at least one of potassium sulfate, sodium sulfate, magnesium sulfate, calcium sulfate, ferric sulfate, ferrous sulfate, lithium sulfate, calcium sulfate, and aluminum sulfate. Also, the zinc material is zinc. Alternatively, the zinc material can also be a zinc alloy containing zinc as the main component and at least one metal selected from aluminum and magnesium.

The invention relates to a method for producing a hot-rolled strip composed of a bainitic multi-phase steel and having a Zn—Mg—Al coating, comprising the following steps: melting a steel melt containing (in weight percent): C: 0.04-0.11, Si: <=0.7, Mn: 1.4-2.2, Mo: 0.05-0.5, Al: 0.015-0.1, P: up to 0.02, S: up to 0.01, B: up to 0.006, and at least one element from the group Nb, V, Ti in accordance with the following condition: 0.02<=Nb+V+Ti<=0.20, the remainder being iron including unavoidable steel-accompanying elements resulting from the melting process, casting the steel melt into a preliminary material, in particular a slab or a block or a thin slab, hot rolling the preliminary material into a hot-rolled strip having a final rolling temperature in the range of 800 to 950° C., cooling the hot-rolled strip to a winding temperature less than 650° C., winding the hot-rolled strip at a winding temperature less than 650° C., cooling the wound hot-rolled strip to room temperature in still air, wherein the microstructure of the wound hot-rolled strip then has a bainite fraction greater than 50% after the hot rolling, heating the hot-rolled strip to a temperature greater than 650° C. and less than Ac3, in particular less than Ac1+50° C., cooling the hot-rolled strip to zinc bath temperature, hot-dip coating the heated hot-rolled strip in a zinc alloy molten bath containing (in weight percent): Al: 1.0-2.0, Mg: 1.0-2.0, the remainder being zinc and unavoidable impurities. The invention further relates to the hot-rolled strip produced in accordance with the method above and to shaped, dynamically highly loadable components, in particular motor vehicle parts, that are produced from said hot-roiled strip and that are resistant to corrosive and abrasive influences.

The invention relates to a method for producing a hot-rolled strip composed of a bainitic multi-phase steel and having a Zn—Mg—Al coating, comprising the following steps: melting a steel melt containing (in weight percent): C: 0.04-0.11, Si: <=0.7, Mn: 1.4-2.2, Mo: 0.05-0.5, Al: 0.015-0.1, P: up to 0.02, S: up to 0.01, B: up to 0.006, and at least one element from the group Nb, V, Ti in accordance with the following condition: 0.02<=Nb+V+Ti<=0.20, the remainder being iron including unavoidable steel-accompanying elements resulting from the melting process, casting the steel melt into a preliminary material, in particular a slab or a block or a thin slab, hot rolling the preliminary material into a hot-rolled strip having a final rolling temperature in the range of 800 to 950° C., cooling the hot-rolled strip to a winding temperature less than 650° C., winding the hot-rolled strip at a winding temperature less than 650° C., cooling the wound hot-rolled strip to room temperature in still air, wherein the microstructure of the wound hot-rolled strip then has a bainite fraction greater than 50% after the hot rolling, heating the hot-rolled strip to a temperature greater than 650° C. and less than Ac3, in particular less than Ac1+50° C., cooling the hot-rolled strip to zinc bath temperature, hot-dip coating the heated hot-rolled strip in a zinc alloy molten bath containing (in weight percent): Al: 1.0-2.0, Mg: 1.0-2.0, the remainder being zinc and unavoidable impurities. The invention further relates to the hot-rolled strip produced in accordance with the method above and to shaped, dynamically highly loadable components, in particular motor vehicle parts, that are produced from said hot-roiled strip and that are resistant to corrosive and abrasive influences.

The present invention provides a method for manufacturing more beautiful black coated steel sheets by uniformly blackening the coating layer. Specifically, the present invention provides a method for manufacturing black coated steel sheets, which brings Zn—Al—Mg alloy coated steel sheets (1) into contact with steam in a closed container (10), wherein said closed container (10) can maintain a predefined internal pressure through variable control of the amount of steam flowing into said closed container (10) and/or the amount of steam flowing out of said closed container (10), and in said closed container (10) that can maintain said predefined pressure, said Zn—Al—Mg alloy coated steel sheets (1) have contact with the steam introduced into said closed container (10).

The present invention provides a method for manufacturing more beautiful black coated steel sheets by uniformly blackening the coating layer. Specifically, the present invention provides a method for manufacturing black coated steel sheets, which brings Zn—Al—Mg alloy coated steel sheets (1) into contact with steam in a closed container (10), wherein said closed container (10) can maintain a predefined internal pressure through variable control of the amount of steam flowing into said closed container (10) and/or the amount of steam flowing out of said closed container (10), and in said closed container (10) that can maintain said predefined pressure, said Zn—Al—Mg alloy coated steel sheets (1) have contact with the steam introduced into said closed container (10).

The present invention relates to a surface treatment composition comprising, on the basis of 100 wt % of the solid part of the composition, 20-40 wt % of a water-soluble polyurethane resin, 40-60 wt % of a silane-based sol-gel resin in which three types of silane compounds are cross-linked, 5-15 wt % of a curing agent, 0.5-1.5 wt % of a corrosion inhibitor, 0.1-1.0 wt % of a molybdenum-based compound, 1.0-3.0 wt % of a silane coupling agent; 1.0-2.0 wt % of an organometallic complex, 1.0-2.0 wt % of an acid scavenger, 0.1-1.0 wt % of an aluminum-based compound, and 1.0-2.0 wt % of a lubricant. A ternary hot-dip galvannealed steel sheet treated with a chromium-free surface treatment coating agent, according to an exemplary embodiment in the present invention, has excellent resistance to blackening, alkali and corrosion, and provides excellent effects without concern for problems, in chromium treatment, of additional equipment installation, an increase in manufacturing costs and environmental pollution.

A coated steel material including: a base steel, and a coating layer containing a Zn—Al—Mg alloy layer disposed on a surface of the base steel, wherein the coating layer has a predetermined chemical composition, and, in a backscattered electron image of the Zn—Al—Mg alloy layer that is obtained at a time of observing the surface of the Zn—Al—Mg alloy layer after polishing to ½ of the layer thickness, under a scanning electron microscope at a magnification of 100×, Al crystals are present, and the average value of the cumulative circumferential length of the Al crystals is 88 to 195 mm/mm.sup.2.

A coated steel material including: a base steel, and a coating layer containing a Zn—Al—Mg alloy layer disposed on a surface of the base steel, wherein the coating layer has a predetermined chemical composition, and, in a backscattered electron image of the Zn—Al—Mg alloy layer that is obtained at a time of observing the surface of the Zn—Al—Mg alloy layer after polishing to ½ of the layer thickness, under a scanning electron microscope at a magnification of 100×, Al crystals are present, and the average value of the cumulative circumferential length of the Al crystals is 88 to 195 mm/mm.sup.2.