A composite structure with an aluminum-based alloy layer containing boron carbide and a manufacturing method thereof are provided. The composite structure includes a substrate with an open hole in that surface and the aluminum-based alloy layer containing boron carbide. The aluminum-based alloy layer is disposed in the open hole and contains aluminum, boron, carbon, and oxygen, wherein the content of aluminum is between 4 at. % and 55 at. %, the content of boron is between 9 at. % and 32 at. %, the content of carbon is between 13 at. % and 32 at. %, the content of oxygen is between 2 at. % and 38 at. %, and the ratio of the content of boron to carbon is between 0.3 and 2.7.

A composite structure with an aluminum-based alloy layer containing boron carbide and a manufacturing method thereof are provided. The composite structure includes a substrate with an open hole in that surface and the aluminum-based alloy layer containing boron carbide. The aluminum-based alloy layer is disposed in the open hole and contains aluminum, boron, carbon, and oxygen, wherein the content of aluminum is between 4 at. % and 55 at. %, the content of boron is between 9 at. % and 32 at. %, the content of carbon is between 13 at. % and 32 at. %, the content of oxygen is between 2 at. % and 38 at. %, and the ratio of the content of boron to carbon is between 0.3 and 2.7.

A cermet contains hard phase particles containing Ti and a binding phase containing at least one of Ni and Co, and 70% or more (by number) of the hard phase particles have a cored structure containing a core and a peripheral portion around the core. The core is composed mainly of at least one of Ti carbide, Ti nitride, and Ti carbonitride, and the peripheral portion is composed mainly of a Ti composite compound containing Ti and at least one selected from W, Mo, Ta, Nb, and Cr. The core has an average particle size α, the peripheral portion has an average particle size β, and α and β satisfy 1.1≦β/α≦1.7.

A cermet contains hard phase particles containing Ti and a binding phase containing at least one of Ni and Co, and 70% or more (by number) of the hard phase particles have a cored structure containing a core and a peripheral portion around the core. The core is composed mainly of at least one of Ti carbide, Ti nitride, and Ti carbonitride, and the peripheral portion is composed mainly of a Ti composite compound containing Ti and at least one selected from W, Mo, Ta, Nb, and Cr. The core has an average particle size α, the peripheral portion has an average particle size β, and α and β satisfy 1.1≦β/α≦1.7.

A cermet contains hard phase particles containing Ti and a binding phase containing at least one of Ni and Co. 70% or more of the hard phase particles have a cored structure containing a core and a peripheral portion around the core. The core is composed mainly of at least one of Ti carbide, Ti nitride, and Ti carbonitride. The peripheral portion is composed mainly of a Ti composite compound containing Ti and at least one selected from W, Mo, Ta, Nb, and Cr. The core has an average particle size α, the peripheral portion has an average particle size β, and α and β satisfy 1.1≦β/α≦1.7. The hard phase particles in the cermet have an average particle size of more than 1.0 μm.

A cermet contains hard phase particles containing Ti and a binding phase containing at least one of Ni and Co. 70% or more of the hard phase particles have a cored structure containing a core and a peripheral portion around the core. The core is composed mainly of at least one of Ti carbide, Ti nitride, and Ti carbonitride. The peripheral portion is composed mainly of a Ti composite compound containing Ti and at least one selected from W, Mo, Ta, Nb, and Cr. The core has an average particle size α, the peripheral portion has an average particle size β, and α and β satisfy 1.1≦β/α≦1.7. The hard phase particles in the cermet have an average particle size of more than 1.0 μm.

A sintered friction material comprises a metallic matrix and granular constituents embedded in the matrix. The metallic matrix comprises a copper base alloy. The friction material is characterized in that the granular constituents comprise at least one sintered cemented carbide in a proportion of up to 9 weight percent, based on the total weight of the friction material. Furthermore, a friction body, in particular for clutches and brakes, that comprises a friction lining with at least one layer made of the sintered friction material, and a method for the production of a friction lining with the sintered friction material are described.

A sintered friction material comprises a metallic matrix and granular constituents embedded in the matrix. The metallic matrix comprises a copper base alloy. The friction material is characterized in that the granular constituents comprise at least one sintered cemented carbide in a proportion of up to 9 weight percent, based on the total weight of the friction material. Furthermore, a friction body, in particular for clutches and brakes, that comprises a friction lining with at least one layer made of the sintered friction material, and a method for the production of a friction lining with the sintered friction material are described.

The present invention relates to a method of making a cemented carbide comprising mixing in a slurry a first powder fraction and a second powder fraction, subjecting the slurry to milling, drying, pressing and sintering. The first powder fraction is made from cemented carbide scrap recycled using the Zn recovery process, comprising the elements W, C, Co, and at least one or more of Ta, Ti, Nb, Cr, Zr, Hf and Mo, and the second powder fraction comprising virgin raw materials of WC and possibly carbides and/or carbonitrides of one or more of Cr, Zr, W, Ta, Ti, Hf and Nb. The first powder fraction is subjected to a pre-milling step, prior to the step of forming the slurry, to obtain an average grain size of between 0.2 to 1.5 μm.

The present invention relates to a method of making a cemented carbide comprising mixing in a slurry a first powder fraction and a second powder fraction, subjecting the slurry to milling, drying, pressing and sintering. The first powder fraction is made from cemented carbide scrap recycled using the Zn recovery process, comprising the elements W, C, Co, and at least one or more of Ta, Ti, Nb, Cr, Zr, Hf and Mo, and the second powder fraction comprising virgin raw materials of WC and possibly carbides and/or carbonitrides of one or more of Cr, Zr, W, Ta, Ti, Hf and Nb. The first powder fraction is subjected to a pre-milling step, prior to the step of forming the slurry, to obtain an average grain size of between 0.2 to 1.5 μm.