An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

The black heart malleable cast iron according to the present embodiment comprises a matrix of ferrite and lump graphite included in the matrix, the black heart malleable cast iron comprising 50 ppm or more and 100 ppm or less of boron, and 65 ppm or more and 200 ppm or less of nitrogen in a mass ratio, wherein a grain size of the matrix is 8.0 or more and 10.0 or less in terms of grain size number, numerically determined by comparison between a metallographic photograph and a standard grain size chart.

The black heart malleable cast iron according to the present embodiment comprises a matrix of ferrite and lump graphite included in the matrix, the black heart malleable cast iron comprising 50 ppm or more and 100 ppm or less of boron, and 65 ppm or more and 200 ppm or less of nitrogen in a mass ratio, wherein a grain size of the matrix is 8.0 or more and 10.0 or less in terms of grain size number, numerically determined by comparison between a metallographic photograph and a standard grain size chart.

A centrifugally cast composite roll for hot rolling comprising an outer layer made of an Fe-based alloy having a chemical composition comprising by mass 2.6-3.6% of C, 0.1-3% of Si, 0.3-2% of Mn, 2.3-5.5% of Ni, 0.5-3.2% of Cr, 0.3-1.6% of Mo, 1.8-3.4% of V, and 0.7-2.4% of Nb, 1.4 ≤V/Nb ≤2.7, a V equivalent (Veq=V+0.55 Nb) being 2.60-4% by mass, and the balance being Fe and impurities, and an inner layer made of an iron-based alloy and integrally fused to the outer layer.

A centrifugally cast composite roll for hot rolling comprising an outer layer made of an Fe-based alloy having a chemical composition comprising by mass 2.6-3.6% of C, 0.1-3% of Si, 0.3-2% of Mn, 2.3-5.5% of Ni, 0.5-3.2% of Cr, 0.3-1.6% of Mo, 1.8-3.4% of V, and 0.7-2.4% of Nb, 1.4 ≤V/Nb ≤2.7, a V equivalent (Veq=V+0.55 Nb) being 2.60-4% by mass, and the balance being Fe and impurities, and an inner layer made of an iron-based alloy and integrally fused to the outer layer.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

An inoculant for the manufacture of cast iron with spheroidal graphite is disclosed, the inoculant has a particulate ferrosilicon alloy having between 40 and 80% by weight of Si; 0.02-8% by weight of Ca; 0-5% by weight of Sr; 0-12% by weight of Ba; 0-15% by weight of rare earth metal; 0-5% by weight of Mg; 0.05-5% by weight of Al; 0-10% by weight of Mn; 0-10% by weight of Ti; 0-10 by weight of Zr; the balance being Fe and incidental impurities in the ordinary amount, wherein the inoculant additionally contains, by weight, based on the total weight of inoculant: 0.1 to 15% of particulate Sb.sub.2S.sub.3, and optionally between 0.1 and 15% of particulate Bi.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Sb.sub.2O.sub.3, and/or between 0.1 and 15% of particulate Bi.sub.2S.sub.3, and/or between 0.1 and 5% of one or more of particulate Fe.sub.3O.sub.4, Fe.sub.2O.sub.3, FeO, or a mixture thereof, and/or between 0.1 and 5% of one or more of particulate FeS, FeS.sub.2, Fe.sub.3S.sub.4, or a mixture thereof, a method for producing such inoculant and use of such inoculant.

This ferritic spheroidal graphite cast iron contains 3.0% to 3.6% by mass of C, 4.0% to 5.0% by mass of Si, 0.020% to 0.10% by mass of Mg, 1.0% or less of Mn, 0.10% by mass or less of P, and 0.015% by mass or less of S, with the balance being Fe and inevitable impurities.

A spheroidal graphite cast iron having an excellent impact strength at low temperature and a method for producing the same are provided. The present disclosure relates to the spheroidal graphite cast iron comprising: C: 3.5 mass % to 4.2 mass %; Si: 2.0 mass % to 2.8 mass %; Mn: 0.2 mass % to 0.4 mass %; Cu: 0.1 mass % to 0.7 mass %; Mg: 0.02 mass % to 0.06 mass %; Cr: 0.01 mass % to 0.15 mass %; and the balance: Fe and inevitable impurities, wherein Mn+Cr+Cu is 0.431 mass % to 1.090 mass %, a graphite nodule count is 230/mm.sup.2 or less, and a pearlite fraction is 30% to 85%.