Provided is an oriented electrical steel sheet including: a forsterite film formed on one side or both sides of an oriented electrical steel sheet substrate; and a ceramic layer formed on an entire or partial region of the forsterite film. Provided is a manufacturing method for an oriented electrical steel sheet including: preparing an oriented electrical steel sheet having a forsterite film formed on one surface or both surfaces thereof; and forming a ceramic layer by spraying ceramic powder on the forsterite film.

A soft magnetic alloy or the like combining high saturated magnetic flux density, low coercive force and high magnetic permeability μ′ having the composition formula (Fe.sub.(1−(α+β))X1.sub.αX2.sub.β).sub.(1−(a+b+c+d+e))B.sub.aSi.sub.bC.sub.cCu.sub.dM.sub.e. X1 is one more elements selected from the group consisting of Co and Ni, X2 is one or more elements selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Bi, N, O and rare earth elements, and M is one or more elements selected from the group consisting of Nb, Hf, Zr, Ta, Ti, Mo, W and V. 0.140<a≤0.240, 0≤b≤0.030, 0<c<0.080, 0<d≤0.020, 0≤e≤0.030, α≥0, β≥0, and 0≤α+β≤0.50 are satisfied.

Grain-oriented electrical steel sheet excellent in magnetic properties and excellent in adhesion of a primary coating to the steel sheet is provided. The grain-oriented electrical steel sheet is provided with a base steel sheet having a chemical composition containing C: 0.005% or less, Si: 2.5 to 4.5%, Mn: 0.050 to 1.000%, a total of S and Se: 0.005% or less, sol. Al: 0.005% or less, and N: 0.005% or less and having a balance of Fe and impurities and a primary coating having Mg.sub.2 SiO.sub.4 as a main constituent formed on a surface of the base steel sheet. A peak position of Al emission intensity obtained when conducting elemental analysis by glow discharge spectrometry from a surface of the primary coating in a thickness direction is present in a range of 2.0 to 12.0 μm from a surface of the primary coating to the thickness direction. A sum of perimeters of the Al oxides at the peak position of Al emission intensity is 0.20 to 1.00 μm/μm.sup.2, and a number density of Al oxides is 0.02 to 0.20/μm.sup.2.

In the present invention, provided is a steel sheet having a predetermined chemical composition and a metallographic structure, in which A/B, which is a ratio of a length A of an interface between epitaxial ferrite and ferrite to a length B of an interface between the epitaxial ferrite and martensite in a cross section that is along a rolling direction and perpendicular to a surface of the steel sheet at a position of ¼ of a sheet thickness from the surface of the steel sheet is more than 1.5, a ratio of a major axis to a minor axis of the martensite is 5.0 or more, and a tensile strength is 980 MPa or more.

A method for controlling carbide network in a bearing steel wire rod by controlling cooling and rolling, comprises the following steps: rapidly rolling a bar to a wire rod and spinning it into a loose coil, controlling the rolling temperature at 780° C.-880° C.; and the spinning temperature at 750° C.-850° C.; carrying out on-line controlling cooling of continuous loose coils using EDC water bath austempering cooling process, controlling the cooling rate at 2.0° C./s-10° C./s, and controlling the final cooling temperature within 620-630° C.; after EDC water bath austempering cooling, using slow cooling under a cover, and the temperature is controlled to be 400° C.-500° C. when being removed out of the cover; after slow cooling, collecting coils, and cooling in air to the room temperature.

A seamless steel pipe of the present invention is a seamless steel pipe having a composition including, in mass %, C: 0.01 to 0.12%, Si: 0.01 to 0.8%, Mn: 0.10 to 2.00%, P: 0.050% or less, S: 0.040% or less, Al: 0.010 to 0.100%, Cu: 0.03 to 0.80%, Ni: 0.01 to 0.50%, Mo: 0.01 to 0.20%, Sb: 0.002 to 0.50%, Cr: 0.004% or less, W: 0.002% or less, and the balance Fe and incidental impurities, and a structure including a ferrite phase having an area percentage of 50 to 65%, a pearlite phase having an area percentage of 2% or less, and one or both of a bainite phase and a martensitic phase representing the remainder, the seamless steel pipe having a yield strength of 230 MPa or more, and a tensile strength of 380 MPa or more.

A stainless steel seamless pipe having high strength and excellent corrosion resistance. The stainless steel seamless pipe has a specified composition in which C, Si, Mn, Cr, Ni, Mo, Cu, and N satisfy a predetermined formula, a microstructure containing at least 25% martensitic phase, at most 65% ferrite phase, and at most 40% retained austenite phase by volume, and a yield strength of 758 MPa or more.

A preparation method of glassless grain-oriented silicon steel includes the following operations. During a decarburization annealing, a thickness of an oxide film on a surface of strip is 1.5-2.5 μm; an atomic weight ratio of Si element and Fe element in the oxide film satisfies: Si/(Si+Fe)≥0.76; during a high-temperature annealing, a cooling stage includes sequentially: cooling with an inner cover when a temperature drops from 1200° C. to 500° C.; wherein a protective gas is a mixed gas containing nitrogen and hydrogen, and a volume percentage of the hydrogen in the mixed gas is >3%; cooling with the inner cover when the temperature drops from 500° C. to 200° C.; wherein the protective gas is nitrogen; and cooling in air by removing the inner cover when the temperature is <200° C.

Provided is a high strength steel sheet that has a predetermined chemical composition and is manufactured under optimum conditions, the high strength steel sheet having a steel microstructure including, by area, ferrite: 30% or more and 80% or less, tempered martensite: 3.0% or more and 35% or less, and retained austenite: 8% or more, wherein the quotient of the area fraction of grains of the retained austenite, the grains having an aspect ratio of 2.0 or more and a minor axis length of 1 μm or less, divided by the total area fraction of the retained austenite is 0.3 or more, wherein the quotient of the average Mn content (mass %) in the retained austenite divided by the average Mn content (mass %) in the ferrite is 1.5 or more.

The steel sheet of the present invention has a steel microstructure containing, in area fraction, martensite: 20% to 100%, ferrite: 0% to 80%, and another metal phase: 5% or less, in which, on a surface of the steel sheet, a ratio of dislocation density in metal phases at a widthwise edge of the steel sheet to dislocation density in the metal phases at a widthwise center of the steel sheet is 100% to 140%, and, at a thicknesswise center of the steel sheet, a ratio of dislocation density in the metal phases at the widthwise edge of the steel sheet to dislocation density in the metal phases at the widthwise center of the steel sheet is 100% to 140%. The maximum amount of warpage of the steel sheet when the steel sheet is sheared to a length of 1 m in a rolling direction is 15 mm or less.