Patent classifications
C22C38/02
Method for manufacturing high-carbon bearing steel and high-carbon bearing steel manufactured therefrom
Disclosed is a method for manufacturing high-carbon bearing steel, which include: heating a billet at a temperature of about 950 to 1,050° C. for about 70 to 120 minutes, rolling the billet to manufacture a wire rod, winding the wire rod to manufacture a wire rod coil, cooling the wire rod coil, and subsequently heat treating the wire rod coil for spheroidizing and carbonitriding, respectively. The bearing steel may include an amount of about 0.9 to 1.3 wt % of carbon (C), an amount of about 1.1 to 1.6 wt % of silicon (Si), an amount of about 1.0 to 1.5 wt % of manganese (Mn), an amount of about 1.5 to 1.9 wt % of chromium (Cr), an amount of about 0.2 to 0.6 wt % of nickel (Ni), an amount of about 0.1 to 0.3 wt % of molybdenum (Mo), and the balance iron (Fe) based on the total weight thereof.
High-strength high-toughness hot-rolled steel sheet and manufacturing method therefor
A preferable aspect of the present invention provides a high-strength high-toughness hot-rolled steel sheet and a manufacturing method therefor, wherein the hot-rolled steel sheet contains, by weight, 0.07-0.13% C, 0.20-0.50% Si, 0.5-0.9% Mn, 0.03% or less P, 0.02% or less S, 0.005-0.03% Nb, 0.3-0.6% Cr, 0.005-0.03% Ti, 0.1-0.35% Cu, 0.05-0.3% Ni, 0.01-0.15% Mo, 0.007% or less N, 0.001-0.006% Ca, 0.01-0.05% Al, and the balance Fe and other unavoidable impurities, the alloy elements satisfying the following relational formulas [Relational formula 1] 1.6≤(Mo/96)/(P/31)≤6, [Relational formula 2] 1.6≤(Ca/S)≤3, and [Relational formula 3] 3.5≤(3*C/12+Mn/55)*100≤5; wherein a microstructure comprises, by area fraction, 85% or more of polygonal ferrite and 15% or less of pearlite, the crystal grain size of the polygonal ferrite being 10 μm or less; and wherein a variation in yield strength in a width direction is 35 MPa or lower.
High-strength high-toughness hot-rolled steel sheet and manufacturing method therefor
A preferable aspect of the present invention provides a high-strength high-toughness hot-rolled steel sheet and a manufacturing method therefor, wherein the hot-rolled steel sheet contains, by weight, 0.07-0.13% C, 0.20-0.50% Si, 0.5-0.9% Mn, 0.03% or less P, 0.02% or less S, 0.005-0.03% Nb, 0.3-0.6% Cr, 0.005-0.03% Ti, 0.1-0.35% Cu, 0.05-0.3% Ni, 0.01-0.15% Mo, 0.007% or less N, 0.001-0.006% Ca, 0.01-0.05% Al, and the balance Fe and other unavoidable impurities, the alloy elements satisfying the following relational formulas [Relational formula 1] 1.6≤(Mo/96)/(P/31)≤6, [Relational formula 2] 1.6≤(Ca/S)≤3, and [Relational formula 3] 3.5≤(3*C/12+Mn/55)*100≤5; wherein a microstructure comprises, by area fraction, 85% or more of polygonal ferrite and 15% or less of pearlite, the crystal grain size of the polygonal ferrite being 10 μm or less; and wherein a variation in yield strength in a width direction is 35 MPa or lower.
COLD-ROLLED AND ANNEALED STEEL SHEET AND MANUFACTURING METHOD
A steel sheet has a composition comprising 0.060%≤C≤0.085%, 1.8%≤Mn≤2.0%, 0.4%≤Cr≤0.6%, 0.1%≤Si≤0.5%, 0.010%≤Nb≤0.025%, 3.42N≤Ti≤0.035%, 0≤Mo≤0.030%, 0.020%≤Al≤0.060%, 0.0012%≤B≤0.0030%, S≤0.005%, P≤0.050%, 0.002%≤N≤0.007% and optionally 0.0005%≤Ca≤0.005%, the remainder of the composition being iron and unavoidable impurities. The microstructure consists of 34% to 80% bainite, 10% to 16% martensite, and 10% to 50% of ferrite. The surface fraction of unrecrystallized ferrite, with respect to the whole structure, is of less than 30%. The martensite consists of self-tempered martensite and fresh martensite, the surface fraction of self-tempered martensite being comprised between 4% and 10%.
COLD-ROLLED AND ANNEALED STEEL SHEET AND MANUFACTURING METHOD
A steel sheet has a composition comprising 0.060%≤C≤0.085%, 1.8%≤Mn≤2.0%, 0.4%≤Cr≤0.6%, 0.1%≤Si≤0.5%, 0.010%≤Nb≤0.025%, 3.42N≤Ti≤0.035%, 0≤Mo≤0.030%, 0.020%≤Al≤0.060%, 0.0012%≤B≤0.0030%, S≤0.005%, P≤0.050%, 0.002%≤N≤0.007% and optionally 0.0005%≤Ca≤0.005%, the remainder of the composition being iron and unavoidable impurities. The microstructure consists of 34% to 80% bainite, 10% to 16% martensite, and 10% to 50% of ferrite. The surface fraction of unrecrystallized ferrite, with respect to the whole structure, is of less than 30%. The martensite consists of self-tempered martensite and fresh martensite, the surface fraction of self-tempered martensite being comprised between 4% and 10%.
STEEL WIRE ROD HAVING EXCELLENT SPHEROIDIZING HEAT TREATMENT PROPERTIES, AND METHOD FOR PRODUCING SAME
An embodiment of the present invention provides a steel wire rod and a method for producing same, the steel wire rod comprising 0.3-0.5 wt % of C, 0.02-0.4 wt % of Si, 1.0-1.5 wt % of Mn, 0.3-0.7 wt % of Cr, 0.003 wt % or less of B, 0.03 wt % or less of Ti, 0.03 wt % or less of P, 0.01 wt % or less of S, 0.02-0.05 wt % of Al, and 0.001-0.01 wt % of N, with the balance being Fe and inevitable impurities, and having a microstructure in which the main phase thereof is a complex structure of ferrite+pearlite, and contains at most 5 area % (including 0 area %) of at least one of bainite or martensite, wherein the average pearlite colony size in a region extending from the ⅖ point to the ⅗ point of the diameter is at most 7 μm.
STEEL WIRE ROD HAVING EXCELLENT SPHEROIDIZING HEAT TREATMENT PROPERTIES, AND METHOD FOR PRODUCING SAME
An embodiment of the present invention provides a steel wire rod and a method for producing same, the steel wire rod comprising 0.3-0.5 wt % of C, 0.02-0.4 wt % of Si, 1.0-1.5 wt % of Mn, 0.3-0.7 wt % of Cr, 0.003 wt % or less of B, 0.03 wt % or less of Ti, 0.03 wt % or less of P, 0.01 wt % or less of S, 0.02-0.05 wt % of Al, and 0.001-0.01 wt % of N, with the balance being Fe and inevitable impurities, and having a microstructure in which the main phase thereof is a complex structure of ferrite+pearlite, and contains at most 5 area % (including 0 area %) of at least one of bainite or martensite, wherein the average pearlite colony size in a region extending from the ⅖ point to the ⅗ point of the diameter is at most 7 μm.
STAINLESS STEEL HAVING EXCELLENT SURFACE ELECTRICAL CONDUCTIVITY FOR FUEL CELL SEPARATOR AND MANUFACTURING METHOD THEREFOR
Disclosed is a stainless steel having excellent surface electrical conductivity for a fuel cell separator. According to an embodiment of the disclosed stainless steel having excellent surface electrical conductivity for a fuel cell separator, a value of the following surface oxide atomic ratio (1) may be 0.5 or less, as measured on the surface of a stainless steel containing 15 wt % or more of Cr by X-ray angle-resolved photoemission spectroscopy using an Al-Kα X-ray source under the condition where a take-off angle of photoelectrons is from 12° to 85°.
The metal oxide (MO) includes a mixed oxide: M represents an alloying element other than Cr and Fe or a combination thereof in the matrix; and O represents oxygen. The total oxides and hydroxides include a Cr oxide, a Cr hydroxide, an Fe oxide, an Fe hydroxide, and the metal oxide (MO).
ALLOY
An alloy including an amorphous phase, and the alloy includes: an average Fe concentration in an entire alloy of 82.0 at. % or more and 88.0 at. % or less; an average Cu concentration in the entire alloy of 0.4 at. % or more and 1.0 at. % or less; an average P concentration in the entire alloy of 5.0 at. % or more and 9.0 at. % or less; an average B concentration in the entire alloy of 6.0 at. % or more and 10.0 at. % or less; an average Si concentration in the entire alloy of 0.4 at. % or more and 1.9 at. % or less; an average C concentration in the entire alloy of 0 at. % or more and 2.0 at. % or less; an average impurity concentration of an impurity other than Fe, Cu, P, B, Si, and C in the entire alloy of 0 at. % or more and 0.3 at. % or less; and a total of the average Fe concentration, the average Cu concentration, the average P concentration, the average B concentration, the average Si concentration, the average C concentration, and the average impurity concentration of 100.0 at. %.
ALLOY
An alloy including an amorphous phase, and the alloy includes: an average Fe concentration in an entire alloy of 82.0 at. % or more and 88.0 at. % or less; an average Cu concentration in the entire alloy of 0.4 at. % or more and 1.0 at. % or less; an average P concentration in the entire alloy of 5.0 at. % or more and 9.0 at. % or less; an average B concentration in the entire alloy of 6.0 at. % or more and 10.0 at. % or less; an average Si concentration in the entire alloy of 0.4 at. % or more and 1.9 at. % or less; an average C concentration in the entire alloy of 0 at. % or more and 2.0 at. % or less; an average impurity concentration of an impurity other than Fe, Cu, P, B, Si, and C in the entire alloy of 0 at. % or more and 0.3 at. % or less; and a total of the average Fe concentration, the average Cu concentration, the average P concentration, the average B concentration, the average Si concentration, the average C concentration, and the average impurity concentration of 100.0 at. %.