A Ni steel has a chemical composition within a predetermined range, in which a metallographic structure of a thickness middle portion contains 2.0 vol % to 20.0 vol % of an austenite phase, an average grain size of prior austenite grains is 3.0 μm to 12.0 μm, an average aspect ratio of the prior austenite grains is 2.6 to 10.0, a plate thickness is 4.5 mm to 20 mm, a yield stress at room temperature is 590 MPa to 710 MPa, and a tensile strength at the room temperature is 690 MPa to 810 MPa, when the plate thickness is more than 16 mm, the Ni steel contains Ni: 11.5% or more, and when the plate thickness is 16 mm or less and the Ni steel contains Ni: less than 11.5%, the average grain size of the prior austenite grains is 6.0 μm or less.

The present invention relates to a hot stamped component, a precoated steel sheet used for hot stamping, and a hot stamping process. The hot stamped component of the present invention is provided with a coating of aluminium or an aluminium alloy on at least one surface of the base steel, the coating is produced by interdiffusion between the base steel and a precoating of aluminium or aluminium alloy, and the coating has a thickness of 6 to 26 μm.

A grain-oriented electrical steel sheet having excellent iron loss property is produced from a steel slab containing, by mass %, C: 0.002-0.15%, Si: 2.5-6.0%, Mn: 0.01-0.80%, Al: 0.010-0.050% and N: 0.003-0.020%, when: a heating rate between 500-700° C. in decarburization annealing is not less than 80° C./s, a surface roughness Ra of a work roll in final cold rolling is 0.01-3.0 μm, a total content of alkaline earth metals to MgO in annealing separator is 0-5 mass %, an average length L in rolling direction of passed crystal grains is not more than 25 mm, a ratio of crystal grains having a length in rolling direction of not more than 5 mm is 40-90%, and an existence ratio of alkaline earth metal sulfides having a size corresponding to circle of not less than 0.5 μm in a cross section of forsterite film is not more than 0.2/μm per unit length in sheet width direction.

A grain-oriented electrical steel sheet having excellent iron loss property is produced from a steel slab containing, by mass %, C: 0.002-0.15%, Si: 2.5-6.0%, Mn: 0.01-0.80%, Al: 0.010-0.050% and N: 0.003-0.020%, when: a heating rate between 500-700° C. in decarburization annealing is not less than 80° C./s, a surface roughness Ra of a work roll in final cold rolling is 0.01-3.0 μm, a total content of alkaline earth metals to MgO in annealing separator is 0-5 mass %, an average length L in rolling direction of passed crystal grains is not more than 25 mm, a ratio of crystal grains having a length in rolling direction of not more than 5 mm is 40-90%, and an existence ratio of alkaline earth metal sulfides having a size corresponding to circle of not less than 0.5 μm in a cross section of forsterite film is not more than 0.2/μm per unit length in sheet width direction.

Method for the manufacture of a galvannealed steel sheet includes the following steps: A) the provision of a pre-coated steel sheet coated with a first coating comprising iron and nickel, such steel sheet having the following chemical composition in weight percent 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<2.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0% and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.005%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B) the thermal treatment of such pre-coated steel sheet at a temperature between 600 to 1000° C., C) the hot-dip coating of the steel sheet obtained in step B) with a second coating based on zinc and D) an alloying treatment to form a galvannealed steel sheet.

Method for the manufacture of a galvannealed steel sheet includes the following steps: A) the provision of a pre-coated steel sheet coated with a first coating comprising iron and nickel, such steel sheet having the following chemical composition in weight percent 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<2.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0% and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.005%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B) the thermal treatment of such pre-coated steel sheet at a temperature between 600 to 1000° C., C) the hot-dip coating of the steel sheet obtained in step B) with a second coating based on zinc and D) an alloying treatment to form a galvannealed steel sheet.

A hot-stamping formed body has a predetermined chemical composition and includes microstructure which includes residual austenite of which an area ratio is in a range of 20% to 30%. Among grain boundaries of crystal grains of bainite and tempered martensite in the microstructure, a ratio of a length of a grain boundary having a rotation angle in a range of 55° to 75° to a total length of a grain boundary having a rotation angle in a range of 4° to 12°, a grain boundary having a rotation angle in a range of 49° to 54°, and a grain boundary having a rotation angle in a range of 55° to 75° to the <011> direction as a rotation axis is 30% or more.

A high-strength steel sheet with excellent delayed fracture resistance, having a tensile strength of 1700 MPa or larger, including a predetermined component composition, having a martensite structure whose ratio accounts for 95 area % or more of the entire metallographic structure, and having a transition metal carbide whose ratio accounts for 0.8 volume % or more of the entire metallographic structure.

A high-strength steel sheet with excellent delayed fracture resistance, having a tensile strength of 1700 MPa or larger, including a predetermined component composition, having a martensite structure whose ratio accounts for 95 area % or more of the entire metallographic structure, and having a transition metal carbide whose ratio accounts for 0.8 volume % or more of the entire metallographic structure.

A hot-rolled steel sheet has, as a chemical composition, by mass %: C: 0.01% to 0.30%; Si: 0.01% to 3.00%; Mn: 0.20% to 3.00%; P: 0.030% or less; S: 0.030% or less; Al: 0.001% to 2.000%; N: 0.0100% or less; and Ni: 0.02% to 0.50%, in which among measurement points at which elemental analysis is performed at a measurement pitch of 1 μm using an EPMA in a region of 250 μm×250 μm on a surface, the percentage of measurement points having a Ni content of 0.5 mass % or more is 10% to 70%.