A cold-rolled steel plate (1) and a manufacturing method therefor. The chemical composition of the steel plate (1) in percentage by weight is: C 0.15-0.25%, Si 1.50-2.50%, Mn 2.00-3.00%, P≤0.02%, S≤0.01%, Al 0.03-0.06%, N≤0.01%, with the balance being Fe and impurities. The surface layer has an inner oxide layer (2) with a thickness of 1-5 μm, and there is no enrichment of Si or Mn on the surface. The steel plate (1) has good phosphating performance and formability, with a tensile strength of ≥1180 MPa and an elongation of ≥14%, and has a complex-phase structure of ferrite, martensite, and retained austenite, the content of the retained austenite being not lower than 5%. A dew point is at −25° C. to 10° C. in continuous annealing, such that external oxidation transitions to internal oxidation.

Provided is a hot rolled steel sheet having excellent formability and fatigue properties comprising, in percentage by weight: 0.3-0.8% of C; 13-25% of Mn; 0.1-1.0% of V; 0.005-2.0% of Si; 0.01-2.5% of Al; 0.03% or less of P; 0.03% or less of S; 0.04% or less (excluding 0%) of N; and the balance being Fe and inevitable impurities, wherein, when viewed in a cross section in the thickness direction, the hot rolled steel sheet comprises, by area fraction, 20-70% of a non-recrystallized structure and 30-80% of a recrystallized structure.

Provided is a hot rolled steel sheet having excellent formability and fatigue properties comprising, in percentage by weight: 0.3-0.8% of C; 13-25% of Mn; 0.1-1.0% of V; 0.005-2.0% of Si; 0.01-2.5% of Al; 0.03% or less of P; 0.03% or less of S; 0.04% or less (excluding 0%) of N; and the balance being Fe and inevitable impurities, wherein, when viewed in a cross section in the thickness direction, the hot rolled steel sheet comprises, by area fraction, 20-70% of a non-recrystallized structure and 30-80% of a recrystallized structure.

Steel sheet low in cost and improved in fatigue characteristics without causing a drop in the cold formability, characterized in that it comprises an inner layer and a hard layer on one or both surfaces of the inner layer, a thickness of the hard layer is 20 μm or more and 40% or less of the thickness of the steel sheet, an average micro-Vickers hardness of the hard layer is 240 HV or more and less than 400 HV, an amount of C of the hard layer is 0.4 mass % or less, an amount of N is 0.02 mass % or less, a variation of hardness measured by a nanoindenter at a depth of 10 from the surface of the hard layer is a standard deviation of 2.0 or less, an average micro-Vickers hardness of the inner layer is 80 HV or more and less than 400 HV, a volume rate of carbides contained in the inner layer is less than 2.00%, and the average micro-Vickers hardness of the hard layer is 1.05 times or more the average micro-Vickers hardness of the inner layer.

[Object] What is provided is a manufacturing method of a galvannealed steel sheet capable of further promoting alloying of zinc plating with the steel sheet. [Resolution Means] A manufacturing method of a galvannealed steel sheet, including: forming on a surface of a steel sheet after hot rolling and pickling which contains, by mass %, C: 0.001% to 0.350%, Si: 0.001% to 2.500% or P: 0.001% to 0.100%, or combination thereof, Mn: 0.10% to 3.00%, S: 0.001% to 0.010%, N: 0.0010% to 0.0065%, and sol. Al: 0.001% to 0.800% with a remainder being Fe and impurities, grooves having an opening surface width of 10 μm to 25 μm and a depth of 10 μm to 30 μm at intervals of 20 μm to 500 μm; cold rolling the steel sheet at a rolling reduction of 30% or more; reduction annealing the steel sheet after the cold rolling; immersing the steel sheet in a hot-dip galvanizing bath containing 0.10 mass % to 0.20 mass % of Al with a remainder consisting of Zn and optional components, and adhering a hot-dip galvanized layer to the surface of the steel sheet; and heating the steel sheet to which the hot-dip galvanized layer is adhered, and alloying the steel sheet with the hot-dip galvanized layer.

[Object] What is provided is a manufacturing method of a galvannealed steel sheet capable of further promoting alloying of zinc plating with the steel sheet. [Resolution Means] A manufacturing method of a galvannealed steel sheet, including: forming on a surface of a steel sheet after hot rolling and pickling which contains, by mass %, C: 0.001% to 0.350%, Si: 0.001% to 2.500% or P: 0.001% to 0.100%, or combination thereof, Mn: 0.10% to 3.00%, S: 0.001% to 0.010%, N: 0.0010% to 0.0065%, and sol. Al: 0.001% to 0.800% with a remainder being Fe and impurities, grooves having an opening surface width of 10 μm to 25 μm and a depth of 10 μm to 30 μm at intervals of 20 μm to 500 μm; cold rolling the steel sheet at a rolling reduction of 30% or more; reduction annealing the steel sheet after the cold rolling; immersing the steel sheet in a hot-dip galvanizing bath containing 0.10 mass % to 0.20 mass % of Al with a remainder consisting of Zn and optional components, and adhering a hot-dip galvanized layer to the surface of the steel sheet; and heating the steel sheet to which the hot-dip galvanized layer is adhered, and alloying the steel sheet with the hot-dip galvanized layer.

The present invention relates to a method for manufacturing a high strength and high toughness steel material which is mainly used at an extremely low temperature and used in various parts of ships for LNG transport and LNG fuel vehicles.

A soft magnetic alloy or the like combining high saturated magnetic flux density, low coercive force and high magnetic permeability μ′ having the composition formula (Fe.sub.(1−(α+β))X1.sub.αX2.sub.β).sub.(1−(a+b+c+d+e))B.sub.aSi.sub.bC.sub.cCu.sub.dM.sub.e. X1 is one more elements selected from the group consisting of Co and Ni, X2 is one or more elements selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Bi, N, O and rare earth elements, and M is one or more elements selected from the group consisting of Nb, Hf, Zr, Ta, Ti, Mo, W and V. 0.140<a≤0.240, 0≤b≤0.030, 0<c<0.080, 0<d≤0.020, 0≤e≤0.030, α≥0, β≥0, and 0≤α+β≤0.50 are satisfied.

A soft magnetic alloy or the like combining high saturated magnetic flux density, low coercive force and high magnetic permeability μ′ having the composition formula (Fe.sub.(1−(α+β))X1.sub.αX2.sub.β).sub.(1−(a+b+c+d+e))B.sub.aSi.sub.bC.sub.cCu.sub.dM.sub.e. X1 is one more elements selected from the group consisting of Co and Ni, X2 is one or more elements selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Bi, N, O and rare earth elements, and M is one or more elements selected from the group consisting of Nb, Hf, Zr, Ta, Ti, Mo, W and V. 0.140<a≤0.240, 0≤b≤0.030, 0<c<0.080, 0<d≤0.020, 0≤e≤0.030, α≥0, β≥0, and 0≤α+β≤0.50 are satisfied.

Provided herein is a low-alloy high-strength seamless steel pipe. The steel pipe of the present invention has a composition that contains, in mass %, C: 0.20 to 0.50%, Si: 0.01 to 0.35%, Mn: 0.45 to 1.5%, P: 0.020% or less, S: 0.002% or less, 0: 0.003% or less, Al: 0.01 to 0.08%, Cu: 0.02 to 0.09%, Cr: 0.35 to 1.1%, Mo: 0.05 to 0.35%, B: 0.0010 to 0.0030%, Ca: 0.0010 to 0.0030%, Mg: 0.001% or less, and N: 0.005% or less, and in which the balance is Fe and incidental impurities. The steel pipe has a microstructure in which the number of oxide-base nonmetallic inclusions satisfying the composition ratios represented by predefined formulae is 20 or less per 100 mm.sup.2, and in which the number of oxide-base nonmetallic inclusions satisfying the composition ratios represented by other predefined formulae is 50 or less per 100 mm.sup.2.