Provided is a steel sheet which can be used for automobile parts and the like, and relates to a steel sheet having a superior balance of strength and ductility and strength and hole expansion ratio and superior bending formability, and a method for manufacturing same.

A steel sheet has a predetermined chemical composition containing, in mass %, C: more than 0.18% and less than 0.30%, Mn: more than 2.50% and 4.00% or less, and other elements. The steel micro-structure at a position at a depth of ¼ of the sheet thickness from the surface in an L cross section of the steel sheet is, in area %, tempered martensite: 25 to 90%, ferrite: 5% or less, retained austenite: 10 to 50%, and bainite: 5% or less. At a position at a depth of ¼ of the sheet thickness from the surface of the L cross section, the proportion of a total area of retained austenite grains having an area of 1 μm.sup.2 or more and having a grain shape circularity of 0.1 or more is less than 50% with respect to the entire area of retained austenite. The steel sheet satisfies the formula C.sub.Mnγ/C.sub.Mnα≥1.2.

Disclosed in the present disclosure is an ultrahigh-strength dual-phase steel. The matrix structure of the ultrahigh-strength dual-phase steel is ferrite and martensite, wherein the ferrite and the martensite are evenly distributed in an island shape. The ultrahigh-strength dual-phase steel contains the following chemical elements in percentage by mass: 0.12-0.2% of C, 0.5-1.0% of Si, 2.5-3.0% of Mn, 0.02-0.05% of Al, 0.02-0.05% of Nb, 0.02-0.05% of Ti, and 0.001-0.003% of B. Further disclosed in the present disclosure is a manufacturing method for the ultrahigh-strength dual-phase steel, comprising the steps of smelting and continuous casting, hot rolling, cold rolling, annealing, tempering, and leveling. The ultrahigh-strength dual-phase steel in the present disclosure has not only good mechanical properties but also excellent delayed cracking resistance and low initial hydrogen content, and can be suitable for manufacturing of vehicle safety structural parts.

Disclosed in the present disclosure is an ultrahigh-strength dual-phase steel. The matrix structure of the ultrahigh-strength dual-phase steel is ferrite and martensite, wherein the ferrite and the martensite are evenly distributed in an island shape. The ultrahigh-strength dual-phase steel contains the following chemical elements in percentage by mass: 0.12-0.2% of C, 0.5-1.0% of Si, 2.5-3.0% of Mn, 0.02-0.05% of Al, 0.02-0.05% of Nb, 0.02-0.05% of Ti, and 0.001-0.003% of B. Further disclosed in the present disclosure is a manufacturing method for the ultrahigh-strength dual-phase steel, comprising the steps of smelting and continuous casting, hot rolling, cold rolling, annealing, tempering, and leveling. The ultrahigh-strength dual-phase steel in the present disclosure has not only good mechanical properties but also excellent delayed cracking resistance and low initial hydrogen content, and can be suitable for manufacturing of vehicle safety structural parts.

A supersaturated solid solution soft magnetic material and a preparation method thereof are provided, belonging to the field of metal soft magnetic technologies. The supersaturated solid solution soft magnetic material is soft magnetic alloy with proportions of 72.0˜78.0 at % Fe, 12.0˜18.0 at % Si, 4.0˜12.0 at % Co and 1.0˜3.0 at % Ti. The preparation method uses molten glass purification or electromagnetic levitation melting to an alloy melt with a target supercooling degree, increases the solid solubility of the Ti element in α-Fe (Si, Co), and promotes the formation of supersaturated solid solution of Ti, thereby achieving the goal that the magnetocrystalline anisotropy constant and the magnetostriction coefficient tend to be zero. Ti element is uniformly distributed in the α-Fe (Si, Co) after supercooled solidification analyzed by X-ray energy spectrometer, a supersaturated solid solution alloy without Ti precipitation is obtained, and the soft magnetic alloy has low coercivity and high permeability.

A supersaturated solid solution soft magnetic material and a preparation method thereof are provided, belonging to the field of metal soft magnetic technologies. The supersaturated solid solution soft magnetic material is soft magnetic alloy with proportions of 72.0˜78.0 at % Fe, 12.0˜18.0 at % Si, 4.0˜12.0 at % Co and 1.0˜3.0 at % Ti. The preparation method uses molten glass purification or electromagnetic levitation melting to an alloy melt with a target supercooling degree, increases the solid solubility of the Ti element in α-Fe (Si, Co), and promotes the formation of supersaturated solid solution of Ti, thereby achieving the goal that the magnetocrystalline anisotropy constant and the magnetostriction coefficient tend to be zero. Ti element is uniformly distributed in the α-Fe (Si, Co) after supercooled solidification analyzed by X-ray energy spectrometer, a supersaturated solid solution alloy without Ti precipitation is obtained, and the soft magnetic alloy has low coercivity and high permeability.

Provided is a grain-oriented electrical steel sheet that has excellent magnetic properties and can be manufactured by secondary recrystallization orientation control using coil annealing with high productivity. A grain-oriented electrical steel sheet comprises a specific chemical composition, wherein an average value of a deviation angle (α.sup.2+β.sup.2).sup.1/2 calculated from a deviation angle α from ideal Goss orientation around an ND rotation axis and a deviation angle β from ideal Goss orientation around a TD rotation axis is 5.0° or less, and an area ratio R.sub.β of crystal grains with β≤0.50° is 20% or less.

Provided is a grain-oriented electrical steel sheet that has excellent magnetic properties and can be manufactured by secondary recrystallization orientation control using coil annealing with high productivity. A grain-oriented electrical steel sheet comprises a specific chemical composition, wherein an average value of a deviation angle (α.sup.2+β.sup.2).sup.1/2 calculated from a deviation angle α from ideal Goss orientation around an ND rotation axis and a deviation angle β from ideal Goss orientation around a TD rotation axis is 5.0° or less, and an area ratio R.sub.β of crystal grains with β≤0.50° is 20% or less.

A high-strength galvanized steel sheet includes a steel sheet having a chemical composition containing a predetermined component element, a mass ratio of a content of Si to a content of Mn in the steel (Si/Mn) being 0.1 or more and less than 0.2, and the balance: Fe and incidental impurities, and a steel structure in which an average grain size of inclusions containing at least one of Al, Si, Mg, and Ca and existing in an area extending from a surface to a position of ⅓ of a sheet thickness is 50 μm or less, and an average nearest distance between ones of the inclusions is 20 μm or more; and a galvanized layer provided on a surface of the steel sheet, in which an amount of diffusible hydrogen contained in the steel is less than 0.25 mass ppm, and a tensile strength is 1100 MPa or more.

A method of forming a shaped steel object is provided. The method includes cutting a blank from an alloy composition including 0.05-0.5 wt. % carbon, 4-12 wt. % manganese, 1-8 wt. % aluminum, 0-0.4 wt. % vanadium, and a remainder balance of iron. The method also includes heating the blank until the blank is austenitized to form a heated blank, transferring the heated blank to a press, forming the heating blank into a predetermined shape to form a stamped object, and decreasing the temperature of the stamped object to a temperature between a martensite start (Ms) temperature of the alloy composition and a martensite final (Mf) temperature of the alloy composition to form a shaped steel object comprising martensite and retained austenite.