A high-strength steel sheet with excellent delayed fracture resistance, having a tensile strength of 1700 MPa or larger, including a predetermined component composition, having a martensite structure whose ratio accounts for 95 area % or more of the entire metallographic structure, and having a transition metal carbide whose ratio accounts for 0.8 volume % or more of the entire metallographic structure.

A high-strength steel sheet with excellent delayed fracture resistance, having a tensile strength of 1700 MPa or larger, including a predetermined component composition, having a martensite structure whose ratio accounts for 95 area % or more of the entire metallographic structure, and having a transition metal carbide whose ratio accounts for 0.8 volume % or more of the entire metallographic structure.

A hot-rolled steel sheet has, as a chemical composition, by mass %: C: 0.01% to 0.30%; Si: 0.01% to 3.00%; Mn: 0.20% to 3.00%; P: 0.030% or less; S: 0.030% or less; Al: 0.001% to 2.000%; N: 0.0100% or less; and Ni: 0.02% to 0.50%, in which among measurement points at which elemental analysis is performed at a measurement pitch of 1 μm using an EPMA in a region of 250 μm×250 μm on a surface, the percentage of measurement points having a Ni content of 0.5 mass % or more is 10% to 70%.

A steel sheet includes a predetermined composition, in which a microstructure at a ¼ thickness position from a surface in a sheet thickness direction includes, by vol %, ferrite: 80% or more, martensite: 2% or less, and residual austenite: 2% or less, a proportion of unrecrystallized ferrite in the ferrite of 5% or less, and in the microstructure of the steel sheet stretched by 10% at the ¼ thickness position from the surface in the sheet thickness direction, a number density of voids having a maximum diameter of 1.0 μm or more is 1.0×10.sup.9 pieces/m.sup.2 or less.

A metal powder having a composition including the following elements, expressed in content by weight: 6.5%≤Si≤10%, 4.5%≤Nb≤10%, 0.2%≤B≤2.0%, 0.2%≤Cu≤2.0%, C≤2% and optionally containing Ni≤10 wt % and/or Co≤10 wt % and/or Cr≤7 wt % and/or Zr as a substitute for any part of Nb on a one-to-one basis and/or Mo as a substitute for any part of Nb on a one-to-one basis and/or P as a substitute for any part of Si on a one-to-one basis, the balance being Fe and unavoidable impurities resulting from the elaboration, the metal powder having a microstructure including at least 5% in area fraction of an amorphous phase, the balance being made of crystalline ferritic phases with a grain size below 20 μm and possible precipitates, the metal powder having a mean sphericity SPHT of at least 0.80.

A high-strength structural steel material having excellent fatigue crack propagation inhibitory characteristics according to an aspect of the present invention contains, by weight, 0.02-0.12% of C, 1.7-2.5% of Mn, 0.01-0.8% of Si, 0.005-0.5% of Al, and the balance Fe and unavoidable impurities, wherein a microstructure of the structural steel sheet material is divided into a surface layer portion outside and a central portion inside along a thickness direction; the surface layer portion comprises tempered bainite as a matrix structure, fresh martensite as a second structure, and austenite as a residual structure; and the central portion comprises lath bainite.

A high-strength structural steel material having excellent fatigue crack propagation inhibitory characteristics according to an aspect of the present invention contains, by weight, 0.02-0.12% of C, 1.7-2.5% of Mn, 0.01-0.8% of Si, 0.005-0.5% of Al, and the balance Fe and unavoidable impurities, wherein a microstructure of the structural steel sheet material is divided into a surface layer portion outside and a central portion inside along a thickness direction; the surface layer portion comprises tempered bainite as a matrix structure, fresh martensite as a second structure, and austenite as a residual structure; and the central portion comprises lath bainite.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PMg.sub.2SiO.sub.4 of Mg.sub.2SiO.sub.4 in the form of forsterite, observed in a range of 35°<2θ<36° of both more than 0 and satisfying a relationship PTiN≧PMg.sub.2SiO.sub.4, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

Provided are a high-strength steel sheet and a method for manufacturing the steel sheet. The high-strength steel sheet has a specified chemical composition with the balance being Fe and inevitable impurities, a microstructure including, in terms of area ratio, 30% or more of a ferrite phase, 40% to 65% of a bainite phase and/or a martensite phase, and 5% or less of cementite, in which, in a surface layer that is a region within 50 μm from the surface in the thickness direction, the area ratio of a ferrite phase is 40% to 55% and the total area ratio of a bainite phase having a grain diameter of more than 5 μm and/or a martensite phase having a grain diameter of more than 5 μm is 20% or less, and a tensile strength is 980 MPa or more.

Provided are a high-strength steel sheet and a method for manufacturing the steel sheet. The high-strength steel sheet has a specified chemical composition with the balance being Fe and inevitable impurities, a microstructure including, in terms of area ratio, 30% or more of a ferrite phase, 40% to 65% of a bainite phase and/or a martensite phase, and 5% or less of cementite, in which, in a surface layer that is a region within 50 μm from the surface in the thickness direction, the area ratio of a ferrite phase is 40% to 55% and the total area ratio of a bainite phase having a grain diameter of more than 5 μm and/or a martensite phase having a grain diameter of more than 5 μm is 20% or less, and a tensile strength is 980 MPa or more.