One embodiment provides a composition, comprising: a powder composition comprising alloy that is at least partially amorphous, the alloy comprising chromium, molybdenum, carbon, boron, and iron. One embodiment provides a method of forming a coating, comprising: providing a substrate; and disposing onto the substrate a coating, comprising: powder composition comprising an alloy that is at least partially amorphous, the alloy comprising chromium, molybdenum, carbon, boron, and iron.

Provided in one embodiment is a method of forming a connection mechanism in or on a bulk-solidifying amorphous alloy by casting in or on, or forming with the bulk-solidifying amorphous alloy, a machinable metal. The connection mechanism can be formed by machining the machinable metal.

A method of making an aluminum alloy containing zirconium includes heating a first composition comprising aluminum to a first temperature of greater than or equal to about 580 C. to less than or equal to about 800 C. The method further includes adding a second composition including a copper-zirconium compound to the first composition to form a third composition. The copper-zirconium compound of the second composition has a molar composition of greater than or equal to about 41% zirconium to less than or equal to about 67% zirconium and a balance of copper. The method also includes solidifying the third composition at a cooling rate of greater than or equal to about 0.1 C./second to less than or equal to about 100 C./second to a second temperature less than or equal to a solidus temperature and decomposing the copper-zirconium compound at a third temperature of less than or equal to about 715 C.

A method of making an aluminum alloy containing zirconium includes heating a first composition including aluminum to a first temperature. The first temperature is greater than or equal to a liquidus temperature of the first composition. The method further includes adding a second composition including a copper-zirconium compound to the first composition. The method further includes decomposing at least a portion of the copper-zirconium compound into copper and zirconium. The method further includes forming a third composition by dissolving at least some of the copper from the decomposing in the aluminum of the first composition. The method further includes cooling the third composition to a second temperature to form a first solid material. The second temperature is less than or equal to a solidus temperature of the third composition. The method further includes heat treating the first solid material to form the aluminum alloy containing zirconium.

Disclosed are a metal alloy composition including an amorphous or crystalline metal matrix and metal particles having hyperelasticity by a phase transition dispersed in the metal matrix, wherein the metal alloy composition includes at least one early transition metal (ETM), at least one late transition metal (LTM), and silicon (Si) in an amount of greater than about 0 atomic % and less than about 2 atomic %, a fabricating method thereof, and a product including the same.

Provided in one embodiment is a method of making use of foams as a processing aid or to improve the properties of bulk-solidifying amorphous alloy materials. Other embodiments include the bulk-solidifying amorphous alloy/foam composite materials made in accordance with the methods.

Systems and alloying methods for forming metals are described. Waste materials from various industrial processes and botched master alloy production heats result in numerous byproducts that can form constituent components for the formation of bulk alloys with higher value and more diverse applications. Reusing and upcycling industrial byproducts into material with specific structure and properties result in additional commercial and industrial applications and value.

An embodiment relates to a method comprising overmolding a bulk-solidifying amorphous alloy on a preform of another material than the bulk-solidifying amorphous alloy to form a bulk-solidifying amorphous alloy overmolded preform. Another embodiment relates to an article comprising an overmolded shell comprising the bulk-solidifying amorphous alloy on a preform of another material than the bulk-solidifying amorphous alloy. The preform could be made of a crystalline or amorphous metal or alloy such as aluminum, stainless steel, copper or beryllium.

Nanostructured materials that contain amorphous intergranular films (AlFs) are described herein. Amorphous intergranular films are structurally disordered (lacking the ordered pattern of a crystal) films that are up to a few nanometers thick. Nanostructured materials containing these films exhibit increased ductility, strength, and thermal stability simultaneously. A nanocrystalline material system that has two or more elements can be designed to contain AlFs at the grain boundaries, provided that the dopants segregate to the interface and certain materials science design rules are followed. An example of AlFs in a nanostructured CuZr alloy is provided to illustrate the benefits of integrating AlFs into nanostructured materials.

Embodiments herein relate to forming nano- and/or micro-replication directly embossed in a bulk solidifying amorphous alloy comprising a metal alloy by superplastic forming of the bulk solidifying amorphous alloy at a temperature greater than a glass transition temperature (Tg) of the metal alloy.