The disclosure provides Fe—Cr—Ni—Mo—P—C—B metallic glass-forming alloys and metallic glasses that have a high glass forming ability along with a high thermal stability of the supercooled liquid against crystallization.

A method for producing a soft magnetic material having both high saturation magnetization and low coercive force, including: preparing an alloy having a composition represented by Compositional Formula 1 or 2 and having an amorphous phase, and heating the alloy at a rate of temperature rise of 10° C./sec or more and holding for 0 to 80 seconds at a temperature equal to or higher than the crystallization starting temperature and lower than the temperature at which Fe—B compounds start to form wherein, Compositional Formula 1 is Fe.sub.100-x-yB.sub.xM.sub.y, M represents at least one element selected from Nb, Mo, Ta, W, Ni, Co and Sn, and x and y are in atomic percent (at %) and satisfy the relational expressions of 10≤x≤16 and 0≥y≤8, and Compositional Formula 2 is Fe.sub.100-a-b-cB.sub.aCu.sub.bM′.sub.c, M′ represents at least one element selected from Nb, Mo, Ta, W, Ni and Co, and a, b and c are in atomic percent (at %) and satisfy the relational expressions 10≤a≤16, 0<b≤2 and 0≤c≤8.

A method for producing a soft magnetic material having both high saturation magnetization and low coercive force, including: preparing an alloy having a composition represented by Compositional Formula 1 or 2 and having an amorphous phase, and heating the alloy at a rate of temperature rise of 10° C./sec or more and holding for 0 to 80 seconds at a temperature equal to or higher than the crystallization starting temperature and lower than the temperature at which Fe—B compounds start to form wherein, Compositional Formula 1 is Fe.sub.100-x-yB.sub.xM.sub.y, M represents at least one element selected from Nb, Mo, Ta, W, Ni, Co and Sn, and x and y are in atomic percent (at %) and satisfy the relational expressions of 10≤x≤16 and 0≥y≤8, and Compositional Formula 2 is Fe.sub.100-a-b-cB.sub.aCu.sub.bM′.sub.c, M′ represents at least one element selected from Nb, Mo, Ta, W, Ni and Co, and a, b and c are in atomic percent (at %) and satisfy the relational expressions 10≤a≤16, 0<b≤2 and 0≤c≤8.

A method of producing a laminated amorphous alloy ribbon holding spool. The method includes providing amorphous alloy ribbon holding spools, each of which is wound with a single layer amorphous alloy ribbon, unwinding the single layer amorphous alloy ribbon from each of the amorphous alloy ribbon holding spools, making the single layer amorphous alloy ribbon travel with a laser being radiated thereto, to thereby simultaneously prepare single layer amorphous alloy ribbons having laser irradiation mark formed thereon, laminating the single layer amorphous alloy ribbons having the laser irradiation mark formed thereon to, thereby prepare a laminated amorphous alloy ribbon, and winding up the laminated amorphous alloy ribbon on a spool.

A method of producing a laminated amorphous alloy ribbon holding spool. The method includes providing amorphous alloy ribbon holding spools, each of which is wound with a single layer amorphous alloy ribbon, unwinding the single layer amorphous alloy ribbon from each of the amorphous alloy ribbon holding spools, making the single layer amorphous alloy ribbon travel with a laser being radiated thereto, to thereby simultaneously prepare single layer amorphous alloy ribbons having laser irradiation mark formed thereon, laminating the single layer amorphous alloy ribbons having the laser irradiation mark formed thereon to, thereby prepare a laminated amorphous alloy ribbon, and winding up the laminated amorphous alloy ribbon on a spool.

There is provided a soft magnetic alloy comprising a composition expressed by a formula of (Fe.sub.(1-α)A.sub.α).sub.(1-m-x-y)M.sub.mX.sub.xY.sub.y, in which M represents at least one selected from the group consisting of Zr and Hf, X represents at least one selected from the group consisting of Ni, Mn, Cu, Co, Al, and Ge, Y represents at least one selected from the group consisting of B, P, and Si, A represents at least one selected from the group consisting of Ti, V, Cr, Zn, Mg, Sn, Bi, O, N, S, and a rare earth element, m, x, y, and α satisfy relationships of 0.070≤m≤0.120, 0.001≤x≤0.030, 0≤y≤0.010, and 0≤α≤0.100, and the alloy contains Fe-based nanocrystals having an average crystal grain size of 30 nm or less.

There is provided a soft magnetic alloy comprising a composition expressed by a formula of (Fe.sub.(1-α)A.sub.α).sub.(1-m-x-y)M.sub.mX.sub.xY.sub.y, in which M represents at least one selected from the group consisting of Zr and Hf, X represents at least one selected from the group consisting of Ni, Mn, Cu, Co, Al, and Ge, Y represents at least one selected from the group consisting of B, P, and Si, A represents at least one selected from the group consisting of Ti, V, Cr, Zn, Mg, Sn, Bi, O, N, S, and a rare earth element, m, x, y, and α satisfy relationships of 0.070≤m≤0.120, 0.001≤x≤0.030, 0≤y≤0.010, and 0≤α≤0.100, and the alloy contains Fe-based nanocrystals having an average crystal grain size of 30 nm or less.

A soft magnetic alloy including a compositional formula of ((Fe.sub.(1−(α+β))X1.sub.αX2.sub.β).sub.(1−(a+b+c+e))M.sub.aB.sub.bP.sub.cCu.sub.e).sub.1−fC.sub.f, wherein X1 is one or more selected from the group consisting Co and Ni, X2 is one or more selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Bi, N, O, and rare earth elements, “M” is one or more selected from the group consisting of Nb, Hf, Zr, Ta, Ti, Mo, W, and V, 0.030<a≤0.14, 0.028≤b≤0.20, 0≤c≤0.030, 0<e≤0.030, 0<f≤0.040, α≥0, β≥0, and 0≤α+β≤0.50 are satisfied.

A soft magnetic alloy including a compositional formula of ((Fe.sub.(1−(α+β))X1.sub.αX2.sub.β).sub.(1−(a+b+c+e))M.sub.aB.sub.bP.sub.cCu.sub.e).sub.1−fC.sub.f, wherein X1 is one or more selected from the group consisting Co and Ni, X2 is one or more selected from the group consisting of Al, Mn, Ag, Zn, Sn, As, Sb, Bi, N, O, and rare earth elements, “M” is one or more selected from the group consisting of Nb, Hf, Zr, Ta, Ti, Mo, W, and V, 0.030<a≤0.14, 0.028≤b≤0.20, 0≤c≤0.030, 0<e≤0.030, 0<f≤0.040, α≥0, β≥0, and 0≤α+β≤0.50 are satisfied.

There is provided a metal sheet producing method that can avoid a decrease in magnetic properties. The metal sheet producing method is a method for producing metal sheets by applying heat treatment to metal sheets made of amorphous soft magnetic material while conveying the metal sheets along a bar and thus crystallizing the amorphous soft magnetic material into nano-crystal soft magnetic material. The method includes attaching the plurality of metal sheets in a laminated state to an upstream portion of the bar, separating the plurality of metal sheets from each other using magnetic force and moving the metal sheets while applying heat treatment thereto so as to allow them to pass by a midstream portion of the bar, and sequentially laminating the metal sheets that have passed by the midstream portion on a downstream portion of the bar.