Extreme ultraviolet (EUV) mask blanks, methods for their manufacture and production systems therefor are disclosed. The EUV mask blanks comprise a substrate; a multilayer stack of reflective layers on the substrate; a capping layer on the multilayer stack of reflecting layers; and an absorber layer on the capping layer, the absorber layer comprising an alloy selected from an alloy of ruthenium (Ru) and silicon (Si); an alloy tantalum (Ta) and platinum (Pt); and an alloy of ruthenium (Ru) and molybdenum (Mo).

To provide Ti—Cu alloy formulations and additive manufacturing process configurations for fabrication of a bulk metallic glass (BMG) product that is biocompatible and antimicrobial, compositions of Ti-based metal alloy powder, comprising: Ti; Cu within a range of 5-30 atomic percent; transition metal within a range of 0-50 atomic percent, wherein such transition metal is one or a plurality of Zr, Nb, Ta, Pd, and Co, are disclosed. Moreover, additive manufacturing processes disclosed herein are capable of fabricating a bulk metallic glass of one or a combination of following phasic structures: fully amorphous microstructure; amorphous beta titanium phase; amorphous copper phase; and amorphous (Ti,M).sub.2Cu phase. The resulting biocompatible metal alloy product may be a medical device, particularly but not limited to a medical implant.

Disclosed is a gear including a resettable metallic glass. The gear of the present disclosure includes, as a base material, a resettable metallic glass, wherein the resettable metallic glass includes at least one metal element selected from each of (a) the group consisting of Ti, Zr, and Hf and (b) the group consisting of Fe, Co, Ni, Cu, and Zn, and further includes at least one metal element to maximize the complexity in the thermodynamic enthalpy of mixing among constituent elements, thereby including multiple resetting cores in various atomic-scale cluster forms in an amorphous matrix, leading to a structure with maximized structural complexity.

Disclosed is a gear including a resettable metallic glass. The gear of the present disclosure includes, as a base material, a resettable metallic glass, wherein the resettable metallic glass includes at least one metal element selected from each of (a) the group consisting of Ti, Zr, and Hf and (b) the group consisting of Fe, Co, Ni, Cu, and Zn, and further includes at least one metal element to maximize the complexity in the thermodynamic enthalpy of mixing among constituent elements, thereby including multiple resetting cores in various atomic-scale cluster forms in an amorphous matrix, leading to a structure with maximized structural complexity.

Disclosed are a resettable metallic glass and a manufacturing method therefor. The resettable metallic glass may include: (1) an element group TM consisting of group IV transition elements; (2) an element group E having a negative (−) enthalpy of mixing with group IV transition elements and including a eutectic reaction of a large temperature difference; (3) an element group PN having a positive (+) enthalpy of mixing with the element group TM and a negative (−) enthalpy of mixing with the element group E to form both a TM-E cluster resetting core and an E-PN cluster resetting core or, on the contrary, an element group NP having a negative (−) enthalpy of mixing with the element group TM and a positive (+) enthalpy of mixing with the element group E to form both a TM-E cluster resetting core and a TM-NP cluster resetting core.

Disclosed are a resettable metallic glass and a manufacturing method therefor. The resettable metallic glass may include: (1) an element group TM consisting of group IV transition elements; (2) an element group E having a negative (−) enthalpy of mixing with group IV transition elements and including a eutectic reaction of a large temperature difference; (3) an element group PN having a positive (+) enthalpy of mixing with the element group TM and a negative (−) enthalpy of mixing with the element group E to form both a TM-E cluster resetting core and an E-PN cluster resetting core or, on the contrary, an element group NP having a negative (−) enthalpy of mixing with the element group TM and a positive (+) enthalpy of mixing with the element group E to form both a TM-E cluster resetting core and a TM-NP cluster resetting core.

Munitions structures comprising one or more high strength reactive alloys, in particular reactive bulk metallic glasses, have significant amounts of inherent chemical energy. This energy may be discharged by subjection of the munitions structure to rapid impulsive loading and fragmentation in the presence of oxygen and/or nitrogen. A munitions structure can be configured in both large and small penetrators, e.g. warheads and bullets, with increased lethality. The lethality of these munitions structures is augmented by means of rapidly and simultaneously imparting both mechanical energy (kinetic energy through impact and fragmentation) and chemical energy (blast and/or fireball) to a target. A high-strength reactive alloy can substitute at least in part one or both of explosives and inert structural materials in conventional munitions systems to improve performance and reduce parasitic weight of structural casing.

Munitions structures comprising one or more high strength reactive alloys, in particular reactive bulk metallic glasses, have significant amounts of inherent chemical energy. This energy may be discharged by subjection of the munitions structure to rapid impulsive loading and fragmentation in the presence of oxygen and/or nitrogen. A munitions structure can be configured in both large and small penetrators, e.g. warheads and bullets, with increased lethality. The lethality of these munitions structures is augmented by means of rapidly and simultaneously imparting both mechanical energy (kinetic energy through impact and fragmentation) and chemical energy (blast and/or fireball) to a target. A high-strength reactive alloy can substitute at least in part one or both of explosives and inert structural materials in conventional munitions systems to improve performance and reduce parasitic weight of structural casing.

Systems and methods in accordance with embodiments of the invention advantageously shape sheet materials that include metallic glass-based materials. In one embodiment, a method of shaping a sheet of material including a metallic glass-based material includes: heating a metallic glass-based material within a first region within a sheet of material to a temperature greater than the glass transition temperature of the metallic glass-based material; where the sheet of material has a thickness of between 0.1 mm and 10 mm; where at least some portion of the sheet of material does not include metallic glass-based material that is heated above its respective glass transition temperature when the metallic glass-based material within the first region is heated above its respective glass transition temperature; and deforming the metallic glass-based material within the first region while the temperature of the metallic glass-based material within the first region is greater than its respective glass transition temperature.

Systems and methods in accordance with embodiments of the invention advantageously shape sheet materials that include metallic glass-based materials. In one embodiment, a method of shaping a sheet of material including a metallic glass-based material includes: heating a metallic glass-based material within a first region within a sheet of material to a temperature greater than the glass transition temperature of the metallic glass-based material; where the sheet of material has a thickness of between 0.1 mm and 10 mm; where at least some portion of the sheet of material does not include metallic glass-based material that is heated above its respective glass transition temperature when the metallic glass-based material within the first region is heated above its respective glass transition temperature; and deforming the metallic glass-based material within the first region while the temperature of the metallic glass-based material within the first region is greater than its respective glass transition temperature.