An exemplary embodiment of the present invention relates to a magnesium alloy sheet and a manufacturing method thereof. The exemplary embodiment of the present invention provides a magnesium alloy sheet including 0.5 to 2.1 wt % of Al, 0.5 to 1.5 wt % of Zn, 0.1 to 1.0 wt % of Ca, and a balance of Mg and inevitable impurities, with respect to a total of 100 wt % of the magnesium alloy sheet.

An exemplary embodiment of the present invention relates to a magnesium alloy sheet and a manufacturing method thereof. The exemplary embodiment of the present invention provides a magnesium alloy sheet including 0.5 to 2.1 wt % of Al, 0.5 to 1.5 wt % of Zn, 0.1 to 1.0 wt % of Ca, and a balance of Mg and inevitable impurities, with respect to a total of 100 wt % of the magnesium alloy sheet.

A magnesium alloy containing Al, Sr, Ca, and Mn, with the balance being Mg and inevitable impurities, the magnesium alloy having: a structure having an α-Mg phase, and a precipitate dispersed in at least one of a grain boundary of the α-Mg phase and a cell boundary, the precipitate including: at least one phase selected from a group A consisting of an Al.sub.2Sr phase, an Al.sub.4Sr phase, a (Mg, Al).sub.2Sr phase, and a (Mg, Al).sub.4Sr phase; and at least one phase selected from a group B consisting of an Al.sub.2Ca phase and a (Mg, Al).sub.2Ca phase, the magnesium alloy having, in a cross section, a total area rate of a group A precipitate and a group B precipitate of greater than or equal to 2.5% and less than or equal to 30%.

A magnesium alloy containing Al, Sr, Ca, and Mn, with the balance being Mg and inevitable impurities, the magnesium alloy having: a structure having an α-Mg phase, and a precipitate dispersed in at least one of a grain boundary of the α-Mg phase and a cell boundary, the precipitate including: at least one phase selected from a group A consisting of an Al.sub.2Sr phase, an Al.sub.4Sr phase, a (Mg, Al).sub.2Sr phase, and a (Mg, Al).sub.4Sr phase; and at least one phase selected from a group B consisting of an Al.sub.2Ca phase and a (Mg, Al).sub.2Ca phase, the magnesium alloy having, in a cross section, a total area rate of a group A precipitate and a group B precipitate of greater than or equal to 2.5% and less than or equal to 30%.

A dissolvable magnesium alloy can be used for components of a downhole tool. The dissolvable magnesium alloy can be dissolved completely and controlled at a dissolving rate so as to be compatible with downhole operations, including hydraulic fracturing operations. The alloy includes nickel at 0.04-0.4% by weight and the balance of magnesium. The alloy is dissolvable in KCl at 2.1% by weight and 95 QC with a dissolving rate in a range of 10-100 mg/cm2/hr, yield strength in a range of 18-37 ksi, ultimate tensile strength in a range of 29-47 ksi, and elongation in a range of 8-40%.

A dissolvable magnesium alloy can be used for components of a downhole tool. The dissolvable magnesium alloy can be dissolved completely and controlled at a dissolving rate so as to be compatible with downhole operations, including hydraulic fracturing operations. The alloy includes nickel at 0.04-0.4% by weight and the balance of magnesium. The alloy is dissolvable in KCl at 2.1% by weight and 95 QC with a dissolving rate in a range of 10-100 mg/cm2/hr, yield strength in a range of 18-37 ksi, ultimate tensile strength in a range of 29-47 ksi, and elongation in a range of 8-40%.

According to an exemplary embodiment of the present invention, a manufacturing method of a magnesium alloy plate includes: (a) solution-treating a magnesium casting material containing 0.5 to 10 wt % of zinc (Zn), 1 to 15 wt % of aluminum (Al), and a balance of magnesium (Mg) and inevitable impurities at 300 to 500° C. for 1 to 48 hours; (b) pre-heating the solution-treated magnesium casting material at 300 to 500° C.; and (c) of rolling the pre-heated magnesium casting material together with a constraint member selected by following Relational Expression 1 to satisfy Relational Expressions 2 and 3; and (d) solution-treating a thus-rolled magnesium alloy plate at 300 to 500° C. for 0.5 to 5 hours. Relational Expressions 1 to 3 are as described in the specification.

According to an exemplary embodiment of the present invention, a manufacturing method of a magnesium alloy plate includes: (a) solution-treating a magnesium casting material containing 0.5 to 10 wt % of zinc (Zn), 1 to 15 wt % of aluminum (Al), and a balance of magnesium (Mg) and inevitable impurities at 300 to 500° C. for 1 to 48 hours; (b) pre-heating the solution-treated magnesium casting material at 300 to 500° C.; and (c) of rolling the pre-heated magnesium casting material together with a constraint member selected by following Relational Expression 1 to satisfy Relational Expressions 2 and 3; and (d) solution-treating a thus-rolled magnesium alloy plate at 300 to 500° C. for 0.5 to 5 hours. Relational Expressions 1 to 3 are as described in the specification.

The present invention, in some embodiments, is a method of forming an O temper or T temper product that includes obtaining a coil of a non-ferrous alloy strip as feedstock; uncoiling the coil of the feedstock; heating the feedstock to a temperature between a recrystallization temperature of the non-ferrous alloy and 10 degrees Fahrenheit below a solidus temperature of the non-ferrous alloy; and quenching the feedstock to form a heat-treated product having am O temper or T temper. The non-ferrous alloy strip used in the method excludes aluminum alloys having 0.4 weight percent silicon, less than 0.2 weight percent iron, 0.35 to 0.40 weight percent copper, 0.9 weight percent manganese, and 1 weight percent magnesium.

The present invention, in some embodiments, is a method of forming an O temper or T temper product that includes obtaining a coil of a non-ferrous alloy strip as feedstock; uncoiling the coil of the feedstock; heating the feedstock to a temperature between a recrystallization temperature of the non-ferrous alloy and 10 degrees Fahrenheit below a solidus temperature of the non-ferrous alloy; and quenching the feedstock to form a heat-treated product having am O temper or T temper. The non-ferrous alloy strip used in the method excludes aluminum alloys having 0.4 weight percent silicon, less than 0.2 weight percent iron, 0.35 to 0.40 weight percent copper, 0.9 weight percent manganese, and 1 weight percent magnesium.