The disclosure provides for a layered metal with resistance to hydrogen induced cracking and method of production thereof, comprising a core metal alloy and a skin metal alloy. The core metal alloy comprises twinned boundaries. The core metal alloy has undergone plastic deformation and a heat treatment. The core metal alloy comprises nickel and cobalt. The skin metal alloy is disposed on the core metal alloy, wherein the skin metal alloy comprises an entropy greater than the core metal alloy. The core metal alloy comprises a greater density of twinned boundaries than the skin metal alloy. The skin metal alloy comprises a stacking fault energy of at least about 50 mJ/m.sup.2, and the skin metal alloy comprises iron, aluminum, and boron.

Provided is a method for producing a Ni- or Ti-based alloy product, the method capable of locally increasing the cooling rate and effectively cooling. The method includes the steps: preliminarily processing a hot working material of a Ni- or Ti-based alloy after hot working into a predetermined shape; heating and holding the material at a solution treatment temperature to obtain a material held in a heated state; and cooling the material held in a heated state to obtain a solution-treated material. The cooling step includes placing a flow path-forming member having a space for forming a flow path for a fluid on a surface of the material held in a heated state to form a fluid flow path defined by the surface of the material held in a heated state and an inner surface of the space of the flow path-forming member; and allowing a fluid to flow in the fluid flow path so that the fluid in the flow path locally cools a part of the surface of the material held in a heated state.

Provided are a Ni-based heat resistant superalloy for aircraft engine cases excellent in high-temperature characteristic such as tensile characteristics and low-cycle fatigue characteristics in a high-temperature range and also excellent in workability, and an aircraft engine case formed of the same. The Ni-based heat resistant superalloy has composition containing, by mass, Co: 4.0 to 11.0%, Cr: 12.0 to 17.0%, Al: 2.0 to 4.0%, Ti: 2.0 to 4.0%, Al+Ti: 4.6 to 6.7%, Mo: more than 5.5 to 10.0%, W: more than 0 to 4.0%, B: 0.001 to 0.040%, C: 0.02 to 0.06%, Zr: 0 to 0.05%, Mg: 0 to 0.005%, P: 0 to 0.01%, Nb: 0 to 1.0%, Ta: 0 to 1.0%, and Fe: 0 to 2.0%, and the balance of Ni with inevitable impurities, and is suitable for aircraft engine cases.

Provided are a Ni-based heat resistant superalloy for aircraft engine cases excellent in high-temperature characteristic such as tensile characteristics and low-cycle fatigue characteristics in a high-temperature range and also excellent in workability, and an aircraft engine case formed of the same. The Ni-based heat resistant superalloy has composition containing, by mass, Co: 4.0 to 11.0%, Cr: 12.0 to 17.0%, Al: 2.0 to 4.0%, Ti: 2.0 to 4.0%, Al+Ti: 4.6 to 6.7%, Mo: more than 5.5 to 10.0%, W: more than 0 to 4.0%, B: 0.001 to 0.040%, C: 0.02 to 0.06%, Zr: 0 to 0.05%, Mg: 0 to 0.005%, P: 0 to 0.01%, Nb: 0 to 1.0%, Ta: 0 to 1.0%, and Fe: 0 to 2.0%, and the balance of Ni with inevitable impurities, and is suitable for aircraft engine cases.

A nickel alloy sputtering target comprises: a nickel alloy containing an element capable of decreasing the Curie temperature of nickel, wherein an area ratio of a Ni phase having a Ni content of 99.0 mass % or more is 13% or less and an average crystal grain diameter is 100 gm or less. It is preferred that an area ratio of a high-purity Ni phase having a Ni content of 99.5 mass % or more be 5% or less.

Provided are a Ni-based heat resistant superalloy for aircraft engine cases excellent in high-temperature characteristic such as tensile characteristics and low-cycle fatigue characteristics in a high-temperature range and also excellent in workability, and an aircraft engine case formed of the same. The Ni-based heat resistant superalloy has composition containing, by mass, Co: 4.0 to 11.0%, Cr: 12.0 to 17.0%, Al: 2.0 to 4.0%, Ti: 2.0 to 4.0%, Al+Ti: 4.6 to 6.7%, Mo: more than 5.5 to 10.0%, W: more than 0 to 4.0%, B: 0.001 to 0.040%, C: 0.02 to 0.06%, Zr: 0 to 0.05%, Mg: 0 to 0.005%, P: 0 to 0.01%, Nb: 0 to 1.0%, Ta: 0 to 1.0%, and Fe: 0 to 2.0%, and the balance of Ni with inevitable impurities, and is suitable for aircraft engine cases.

Provided are a Ni-based heat resistant superalloy for aircraft engine cases excellent in high-temperature characteristic such as tensile characteristics and low-cycle fatigue characteristics in a high-temperature range and also excellent in workability, and an aircraft engine case formed of the same. The Ni-based heat resistant superalloy has composition containing, by mass, Co: 4.0 to 11.0%, Cr: 12.0 to 17.0%, Al: 2.0 to 4.0%, Ti: 2.0 to 4.0%, Al+Ti: 4.6 to 6.7%, Mo: more than 5.5 to 10.0%, W: more than 0 to 4.0%, B: 0.001 to 0.040%, C: 0.02 to 0.06%, Zr: 0 to 0.05%, Mg: 0 to 0.005%, P: 0 to 0.01%, Nb: 0 to 1.0%, Ta: 0 to 1.0%, and Fe: 0 to 2.0%, and the balance of Ni with inevitable impurities, and is suitable for aircraft engine cases.

An austenitic alloy based on nickel and having a high chromium content, intended to be used at a given operating temperature between 900° C. and 1150° C., comprises the following elements by mass percentage: chromium between 40% and 45%; iron between 10% and 14%; carbon between 0.4% and 0.6%; titanium between 0.05% and 0.2%; niobium between 0.5% and 1.5%; at least one reactive element, selected from rare earths or hafnium, between 0.002% and 0.1%; silicon between 0% and 1%; manganese between 0% and 0.5%; nickel to balance the alloy elements. In addition, the alloy has a molar fraction of more than 0.1% of secondary carbo-nitrides rich in niobium and/or titanium, after the operating temperature has been applied thereto. The disclosure also relates to a method for designing such an alloy and to a method for validating such an alloy.

An austenitic alloy based on nickel and having a high chromium content, intended to be used at a given operating temperature between 900° C. and 1150° C., comprises the following elements by mass percentage: chromium between 40% and 45%; iron between 10% and 14%; carbon between 0.4% and 0.6%; titanium between 0.05% and 0.2%; niobium between 0.5% and 1.5%; at least one reactive element, selected from rare earths or hafnium, between 0.002% and 0.1%; silicon between 0% and 1%; manganese between 0% and 0.5%; nickel to balance the alloy elements. In addition, the alloy has a molar fraction of more than 0.1% of secondary carbo-nitrides rich in niobium and/or titanium, after the operating temperature has been applied thereto. The disclosure also relates to a method for designing such an alloy and to a method for validating such an alloy.

There is provided a cobalt-based alloy product comprising: in mass %, 0.08-0.25% C; 0.1% or less B; 10-30% Cr; 5% or less Fe and 30% or less Ni, the total amount of Fe and Ni being 30% or less; W and/or Mo, the total amount of W and Mo being 5-12%; 0.5% or less Si; 0.5% or less Mn; 0.003-0.04% N; 0.5 to 2 mass % of an M component being a transition metal other than W and Mo and having an atomic radius of more than 130 pm; and the balance being Co and impurities. The impurities include 0.5% or less Al and 0.04% or less O. The product is a polycrystalline body of matrix phase crystal grains. In the matrix phase crystal grains, segregation cells with an average size of 0.13-2 μm are formed, in which the M component is segregated in boundary regions of the segregation cells.