A process for producing grain-oriented electrical steel strip by means of thin slab continuous casting, comprising the following process steps: a) smelting a steel, b) continuously casting the smelt by thin slab continuous casting, c) heating up the thin slabs and subjecting the slabs to homogenization annealing at a maximum temperature of 1250° C., d) heating to a temperature between 1250° C. and 1350° C., e) continuously hot rolling the thin slabs to form a hot-rolled strip, f) cooling and reeling the hot-rolled strip to form a coil, g) annealing the hot-rolled strip after reeling and prior to a subsequent cold rolling step, h) cold rolling the hot-rolled strip to the nominal usable thickness, i) subjecting the cold-rolled strip to recrystallization, decarburization and nitridation annealing, j) applying an annealing separator (non-stick layer) to the strip surface of the cold-rolled strip, k) subjecting the cold-rolled strip to secondary recrystallization annealing, forming a finished steel strip having a pronounced Goss texture, and l) stress-free annealing the finished steel strip, which has been coated with an insulating layer, provides an improved process for producing grain-oriented electrical steel strip by means of thin slab continuous casting. This is achieved in that the recrystallization, decarburization and nitridation annealing of the cold-rolled strip in process step h) comprises a decarburization annealing phase and a subsequent nitridation annealing phase, with an intermediate reduction annealing phase being interposed between the decarburization annealing phase and the nitridation annealing phase, and carried out at a temperature ranging from 820° C.-890° C., for a maximum period of 40 seconds, with a dry, gaseous annealing atmosphere, which contains nitrogen (N.sub.2) and hydrogen (H.sub.2) and acts on the cold-rolled strip, and which has a water vapor/hydrogen partial pressure ratio pH.sub.2O/pH.sub.2 of less than 0.10.

The present invention is steel for surface hardening for machine structural use which contains, by mass %, C: 0.3 to 0.6%, Si: 0.02 to 2.0%, Mn: 0.35 to less than 1.5%, and Al: 0.01 to 0.5%, is restricted to B: less than 0.0003%, S: 0.0001 to 0.021%, N: 0.003 to 0.0055%, P: 0.0001 to 0.03%, and O: 0.0001 to 0.0050%, has a ratio Mn/S of Mn and S satisfying 70 to 30,000, has a balance of Fe and unavoidable impurities, and, when nitrided, then induction hardened, has a surface hardenability of a Vicker's hardness when tempered at 300° C. of 650 or more.

A hot-rolled steel sheet for nitriding or a cold-rolled steel sheet for nitriding, in which a dislocation density within 50 μm in the sheet thickness direction from the surface is not less than 2.0 times nor more than 10.0 times as compared to a dislocation density at the position of ¼ in the sheet thickness direction; and a method of manufacturing the same. The manufacturing method comprises, on a hot-rolled steel sheet or a cold-rolled steel sheet, performing pickling, and then performing skin pass rolling under the condition that a reduction ratio is 0.5 to 5.0% and FIT, defined as a ratio of a line load F (kg/mm) of a rolling mill load divided by a sheet width of the steel sheet and a load T (kg/mm.sup.2) per unit area to be applied in the longitudinal direction of the steel sheet, is 8000 or more.

A hot-rolled steel sheet for nitriding or a cold-rolled steel sheet for nitriding, in which a dislocation density within 50 μm in the sheet thickness direction from the surface is not less than 2.0 times nor more than 10.0 times as compared to a dislocation density at the position of ¼ in the sheet thickness direction; and a method of manufacturing the same. The manufacturing method comprises, on a hot-rolled steel sheet or a cold-rolled steel sheet, performing pickling, and then performing skin pass rolling under the condition that a reduction ratio is 0.5 to 5.0% and FIT, defined as a ratio of a line load F (kg/mm) of a rolling mill load divided by a sheet width of the steel sheet and a load T (kg/mm.sup.2) per unit area to be applied in the longitudinal direction of the steel sheet, is 8000 or more.

Providing improved wear resistance to a metal material by hardening a surface layer and a surface layer hardening method. A base material is nitrided so that a metal material (40) has a surface layer hardened. The surface layer of the base material is formed with no nitrogen compound layer (40C), and the base material includes a region from a surface thereof to a depth of 78 μm, the region having a Vickers hardness higher than the base material by not less than 5%.

Providing improved wear resistance to a metal material by hardening a surface layer and a surface layer hardening method. A base material is nitrided so that a metal material (40) has a surface layer hardened. The surface layer of the base material is formed with no nitrogen compound layer (40C), and the base material includes a region from a surface thereof to a depth of 78 μm, the region having a Vickers hardness higher than the base material by not less than 5%.

A continuous nitriding treatment furnace includes a nitriding chamber, a heater, a first nitriding zone, and a second nitriding zone lower in atmosphere gas temperature than the first nitriding zone by 25° C. to 150° C., the continuous nitriding treatment furnace being configured such that an atmosphere gas in the first nitriding zone flows into the second nitriding zone and being configured to execute a nitriding treatment that forms an iron nitride compound layer composed of an ε phase or of the ε phase and a γ′ phase on a surface of the steel member in the first nitriding zone and precipitates the γ′ phase in the iron nitride compound layer in the second nitriding zone.

A continuous nitriding treatment furnace includes a nitriding chamber, a heater, a first nitriding zone, and a second nitriding zone lower in atmosphere gas temperature than the first nitriding zone by 25° C. to 150° C., the continuous nitriding treatment furnace being configured such that an atmosphere gas in the first nitriding zone flows into the second nitriding zone and being configured to execute a nitriding treatment that forms an iron nitride compound layer composed of an ε phase or of the ε phase and a γ′ phase on a surface of the steel member in the first nitriding zone and precipitates the γ′ phase in the iron nitride compound layer in the second nitriding zone.

A surface-treated metal plate including: a metal plate; and a nickel-cobalt binary alloy layer formed on the metal plate. When a part having a content ratio of oxygen atoms of 5 atomic % or more as measured by X-ray photoelectron spectroscopic analysis is an oxide coating film, the nickel-cobalt binary alloy layer contains the oxide coating film with a thickness of 0.5 to 30 nm on a surface thereof, and when a pressure cooker test including temperature increasing, retention for 72 hours under a water-vapor atmosphere at a temperature of 105° C. and a relative humidity of 100% RH, and temperature decreasing is performed, the amount of increase in the thickness of the oxide coating film is 28 nm or less.

A method for the low-pressure carbonitriding of steel parts, in particular parts used in the manufacture of automobiles comprises a heating step that includes a simple heating phase (M) followed by an initial nitridation phase (Ni) from a temperature between 700° C. to 750° C. to a temperature between 860° and 1000° C. and carried out using a reduced temperature gradient relative to the simple heating phase. Additionally, alternate cementing (C1-Cn) and nitridation (N1-Nn) steps are performed at constant temperature, wherein the final nitridation step is accompanied with a decrease in temperature immediately before quenching (T).