A method for providing phosphate conversion crystal coating, the method including the steps of: pre-treating a substrate by depositing metal oxide particles on the substrate; treating the substrate with a phosphate coating solution, resulting in the phosphate conversion crystal coating forming (crystallizing) on the substrate.

A method and system for marking a workpiece at a marking location by infusing colorant into targeted surface material within a region of the workpiece via laser-induced chemical etching are disclosed. The system includes a laser subsystem for generating a pulsed laser output and a transport subsystem including a medium containing the colorant mounted immediately adjacent the marking location to transfer the colorant to the targeted surface material upon impact by the pulsed laser output. The system also includes a delivery subsystem for irradiating the medium and the targeted surface material with the pulsed laser output to melt the targeted surface material to obtain molten material and to transfer the colorant from the medium to the molten material. The molten material allows the transferred colorant to thermally diffuse into and chemically bond to the molten material. Each laser pulse creates a microtextured colorized spot of material on the workpiece.

A method and system for marking a workpiece at a marking location by infusing colorant into targeted surface material within a region of the workpiece via laser-induced chemical etching are disclosed. The system includes a laser subsystem for generating a pulsed laser output and a transport subsystem including a medium containing the colorant mounted immediately adjacent the marking location to transfer the colorant to the targeted surface material upon impact by the pulsed laser output. The system also includes a delivery subsystem for irradiating the medium and the targeted surface material with the pulsed laser output to melt the targeted surface material to obtain molten material and to transfer the colorant from the medium to the molten material. The molten material allows the transferred colorant to thermally diffuse into and chemically bond to the molten material. Each laser pulse creates a microtextured colorized spot of material on the workpiece.

The invention relates to a multi-component composite sulfide solid lubricating film prepared by sulfurizing the surface of a high-entropy alloy. The high-entropy alloy is composed of five metal elements of Co, Cr, Fe, Ni and Mo or six metal elements of Co, Cr, Fe, Ni, Mo and W. The multi-component composite sulfide solid lubricating film of the invention is mainly applied to the friction pair surface of mechanical equipment, the lubricating film and the sulfurized base have high bonding strength, and multi-component composite sulfide solid lubricating films containing different sulfide lubricating phases can be chose and prepared according to the service environment of equipment.

Apparatuses and methods of manufacturing of thermally formed composite structures, such as a projectile firing structure, are provided. One simplified exemplary method includes: determining material properties of a projectile firing structure comprising a rifled barrel including thermal conductivity, wear, and tensile strength; wrapping a plurality of thermally reactive layers onto a cylindrical press form structure, the cylindrical press form structure comprising a plurality of spiraled grooves and lands, the thermally reactive layers comprising metal or metal oxides that when heated produce thermal diffusion byproducts in a composite structure forming the rifled barrel having the plurality of material properties; disposing an enclosing structure around the thermally reactive layers wrapped around the cylindrical press form structure; and heating the plurality of thermally reactive layers at a temperature and time so that the plurality of thermally reactive layers thermally react via thermal diffusion forming the rifled barrel having the plurality of material properties.

Apparatuses and methods of manufacturing of thermally formed composite structures, such as a projectile firing structure, are provided. One simplified exemplary method includes: determining material properties of a projectile firing structure comprising a rifled barrel including thermal conductivity, wear, and tensile strength; wrapping a plurality of thermally reactive layers onto a cylindrical press form structure, the cylindrical press form structure comprising a plurality of spiraled grooves and lands, the thermally reactive layers comprising metal or metal oxides that when heated produce thermal diffusion byproducts in a composite structure forming the rifled barrel having the plurality of material properties; disposing an enclosing structure around the thermally reactive layers wrapped around the cylindrical press form structure; and heating the plurality of thermally reactive layers at a temperature and time so that the plurality of thermally reactive layers thermally react via thermal diffusion forming the rifled barrel having the plurality of material properties.

The invention relates to a multi-component composite sulfide solid lubricating film prepared by sulfurizing the surface of a high-entropy alloy. The high-entropy alloy is composed of five metal elements of Co, Cr, Fe, Ni and Mo or six metal elements of Co, Cr, Fe, Ni, Mo and W. The multi-component composite sulfide solid lubricating film of the invention is mainly applied to the friction pair surface of mechanical equipment, the lubricating film and the sulfurized base have high bonding strength, and multi-component composite sulfide solid lubricating films containing different sulfide lubricating phases can be chose and prepared according to the service environment of equipment.

A method for treating a metal material to make a surface portion hydrophobic. The method includes oxidizing an untreated surface portion of the metal material to form an oxidized surface portion. The untreated surface portion has metal atoms. The oxidizing step forming bonds between the metal atoms and oxygen atoms. The method further includes doping the oxidized surface portion with a liquid containing a fluorine-containing salt to form a fluorinated surface portion. The doping step forming bonds between fluorine atoms and at least a portion of the metal atoms and the oxygen atoms. The fluorinated surface portion is hydrophobic.

An apparatus and process are presented for continuous production of metal-based micro-porous structures of pore sizes from 0.3 nm to 5.0 m from a green part of characteristic diffusion mass transfer dimension less than 1 mm through chemical reactions in a continuous flow of gas substantially free of oxygen. The produced micro-porous structures include i) thin porous metal sheets of thickness less than 200 m and pore sizes in the range of 0.1 to 5.0 m, ii) porous ceramic coating of thickness less than 40 m and ceramic particle sizes of 200 nm or less on a porous metal-based support structures of pore sizes in the range of 0.1 to 5 m.

Apparatuses and methods of manufacturing of thermally formed composite structures, such as a projectile firing structure, are provided. One simplified exemplary method includes: determining material properties of a projectile firing structure comprising a rifled barrel including thermal conductivity, wear, and tensile strength; wrapping a plurality of thermally reactive layers onto a cylindrical press form structure, the cylindrical press form structure comprising a plurality of spiraled grooves and lands, the thermally reactive layers comprising metal or metal oxides that when heated produce thermal diffusion byproducts in a composite structure forming the rifled barrel having the plurality of material properties; disposing an enclosing structure around the thermally reactive layers wrapped around the cylindrical press form structure; and heating the plurality of thermally reactive layers at a temperature and time so that the plurality of thermally reactive layers thermally react via thermal diffusion forming the rifled barrel having the plurality of material properties.