A method of applying a protective coating to an article comprises the steps of a) depositing aluminum in a surface region of an article, and b) depositing chromium is the surface region of the article subsequent to step a), whereby at least a portion of the chromium replaces at least a portion of the aluminum. Another method and an article are also disclosed.

A method of applying a protective coating to an article comprises the steps of a) depositing aluminum in a surface region of an article, and b) depositing chromium is the surface region of the article subsequent to step a), whereby at least a portion of the chromium replaces at least a portion of the aluminum. Another method and an article are also disclosed.

A steel sheet for a container includes: a steel sheet; a coated layer containing Ni provided as an upper layer of the steel sheet; and a chemical treatment layer as an upper layer of the coated layer, and containing a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal, and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal, in which the coated layer is one of: a Ni coated layer which contains Ni in amount of 10 to 1000 mg/m.sup.2 in terms of Ni metal, and a composite coated layer which contains Ni in an amount of 5 to 150 mg/m.sup.2 in terms of Ni metal and Sn in an amount of 300 to 3000 mg/m.sup.2 in terms of Sn metal, and has an island-shaped Sn coated layer formed on an FeNiSn alloy layer.

A steel sheet for a container includes: a steel sheet; a coated layer containing Ni provided as an upper layer of the steel sheet; and a chemical treatment layer as an upper layer of the coated layer, and containing a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal, and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal, in which the coated layer is one of: a Ni coated layer which contains Ni in amount of 10 to 1000 mg/m.sup.2 in terms of Ni metal, and a composite coated layer which contains Ni in an amount of 5 to 150 mg/m.sup.2 in terms of Ni metal and Sn in an amount of 300 to 3000 mg/m.sup.2 in terms of Sn metal, and has an island-shaped Sn coated layer formed on an FeNiSn alloy layer.

A steel sheet for a container includes a steel sheet, a Sn coated layer which is provided as an upper layer of the steel sheet and contains Sn in an amount of 560 to 5600 mg/m.sup.2 in terms of Sn metal, and a chemical treatment layer which is provided as an upper layer of the Sn coated layer and contains a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal.

A steel sheet for a container includes a steel sheet, a Sn coated layer which is provided as an upper layer of the steel sheet and contains Sn in an amount of 560 to 5600 mg/m.sup.2 in terms of Sn metal, and a chemical treatment layer which is provided as an upper layer of the Sn coated layer and contains a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal.

A coating system for a surface of a superalloy component is provided. The coating system includes a MCrAlY coating on the surface of the superalloy component, where M is Ni, Fe, Co, or a combination thereof. The MCrAlY coating generally has a higher chromium content than the superalloy component. The MCrAlY coating also includes a platinum-group metal aluminide diffusion layer. The MCrAlY coating includes Re, Ta, or a mixture thereof. Methods are also provided for forming a coating system on a surface of a superalloy component.

A coating system for a surface of a superalloy component is provided. The coating system includes a MCrAlY coating on the surface of the superalloy component, where M is Ni, Fe, Co, or a combination thereof. The MCrAlY coating generally has a higher chromium content than the superalloy component. The MCrAlY coating also includes a platinum-group metal aluminide diffusion layer. The MCrAlY coating includes Re, Ta, or a mixture thereof. Methods are also provided for forming a coating system on a surface of a superalloy component.

This method for producing a transparent optical film includes a film formation step of forming a silver layer and a high standard electrode potential metal layer so as to be laminated on a substrate, the film formation step including a silver deposition step of forming the silver layer, at a thickness of 6 nm or less by vacuum deposition, and a high standard electrode potential metal deposition step of forming the high standard electrode potential metal layer formed of a high standard electrode potential metal having a higher standard electrode potential than that of silver by vacuum deposition, and an alloying step of forming a silver alloy layer by diffusing the high standard electrode potential metal within the silver layer by performing a heating treatment at a temperature of 50 C. or higher and 400 C. or lower.

A method for converting an existing steam methane reformer (SMR) to produce hydrogen via ammonia cracking is provided. The method can include the steps of: providing the existing SMR, wherein the SMR was formerly used to produce hydrogen from a hydrocarbon feedstock; and improving the nitridation resistance of the inner surface of the equipment by adding a protective layer to an inner surface of equipment to be used in the existing SMR, wherein the equipment is selected from the group consisting of a catalyst tube, feed piping, a feed preheater, process gas heat exchangers, and combination thereof.