A method of both coating a substrate with aluminum oxide and infusing the substrate with elemental aluminum is disclosed. In one example, the method includes providing a metal powder/polymer binder slurry, the slurry having a solvent, an organic binder, metal granules and a seed element, wherein the metal granules include Al; dispersing the slurry upon a Cr-containing surface; after dispersing the slurry, exposing the slurry to air and maintaining the temperature of the slurry and substrate below 110 C. to remove at least a portion of the solvent from the slurry; and, in a combined step, both exposing the binder, metal granules and substrate to air and heating the remaining slurry and substrate at a temperature less than or equal to 1000 C. to both diffuse at least a portion of the metal of the metal granules into the substrate and coat the substrate with aluminum oxide.

A process for surface activation or depassivation of an article, in particular an alloy, by immersion of the alloy in an aqueous acid solution. The surface activation methods of the present invention can be performed during a relatively short period of time and achieve reductions in production costs and provide environmental friendliness as compared to prior art processes. In a further embodiment, after surface activation, the article is immersed in a second liquid that prevents re-formation of a passivating oxide layer on the surface of the article. In a further embodiment the surface-activated alloys are subjected to surface engineering by a process that infuses carbon or nitrogen through the surface at a temperature sufficiently low to suppress precipitation of carbides or nitrides.

A process for surface activation or depassivation of an article, in particular an alloy, by immersion of the alloy in an aqueous acid solution. The surface activation methods of the present invention can be performed during a relatively short period of time and achieve reductions in production costs and provide environmental friendliness as compared to prior art processes. In a further embodiment, after surface activation, the article is immersed in a second liquid that prevents re-formation of a passivating oxide layer on the surface of the article. In a further embodiment the surface-activated alloys are subjected to surface engineering by a process that infuses carbon or nitrogen through the surface at a temperature sufficiently low to suppress precipitation of carbides or nitrides.

A liquid composition comprising at least one bisphosphonic compound bearing at least one partially fluorinated, perfluorinated (PF) or perfluorpolether (PFPE) group. The bisphosphonic compound is dissolved in at least one non-flammable fluorinated solvent or in a mixture of non-flammable fluorinated solvents. A method for increasing the lipophobic or hydrophobic properties of a surface is also disclosed, wherein a liquid composition comprising at least one bisphosphonic compound bearing at least one partially fluorinated, perfluorinated (PF) or perfluorpolether (PFPE) group is applied to the surface. The method may include preliminary oxidation of the surface, if necessary; contacting the surface with the liquid composition until the bisphosphonic compound contained therein is assembled in a layer coating the surface; and drying the surface thus coated.

A liquid composition comprising at least one bisphosphonic compound bearing at least one partially fluorinated, perfluorinated (PF) or perfluorpolether (PFPE) group. The bisphosphonic compound is dissolved in at least one non-flammable fluorinated solvent or in a mixture of non-flammable fluorinated solvents. A method for increasing the lipophobic or hydrophobic properties of a surface is also disclosed, wherein a liquid composition comprising at least one bisphosphonic compound bearing at least one partially fluorinated, perfluorinated (PF) or perfluorpolether (PFPE) group is applied to the surface. The method may include preliminary oxidation of the surface, if necessary; contacting the surface with the liquid composition until the bisphosphonic compound contained therein is assembled in a layer coating the surface; and drying the surface thus coated.

The present disclosure concerns synthesis, anion binding features, liquid-liquid extraction of salts, and anti-corrosion character of aryl-triazole bicyclic macrocycles of Formula (I) and related compounds: ##STR00001##

Deposition of Pt nanoparticles on UiO metal organic frameworks via solvothermal reduction is achieved by reducing Pt acetylacetonate (Pt(acac).sub.2) in a UiO-66 and N,N-dimethylformamide (DMF) mixture at, for example, 130 C. for 18 hrs. Modification of reaction temperature and time can control the size of the Pt nanoparticles.

Deposition of Pt nanoparticles on UiO metal organic frameworks via solvothermal reduction is achieved by reducing Pt acetylacetonate (Pt(acac).sub.2) in a UiO-66 and N,N-dimethylformamide (DMF) mixture at, for example, 130 C. for 18 hrs. Modification of reaction temperature and time can control the size of the Pt nanoparticles.

A composite object with more complete and stronger adhesion between the constituent parts includes a substrate and a plastic member formed on a surface of the substrate. The substrate can be made of memory metal. Nano-holes are formed on the surface of the substrate. The composite further includes a combining layer. The combining layer is positioned between the substrate and the plastic member. The nano-holes are at least partially filled with the combining layer, unfilled holes being filled with the plastic constituent in the molten state. The disclosure further provides a method for manufacturing the composite.

A method for manufacturing a gas filling container is provided. The method includes performing a treatment of bringing an amine compound into contact with the inner surface of a gas filling container having at least the inner surface made of stainless steel, manganese steel, carbon steel, or chromium molybdenum steel, and, after the treatment, a treatment of volatilizing off the amine compound from the gas filling container.