Forming a lithium lanthanum zirconate thin film includes disposing zirconium oxide on a substrate to yield a zirconium oxide coating, contacting the zirconium oxide coating with a solution including a lithium salt and a lanthanum salt, heating the substrate to yield a dried salt coating on the zirconium oxide coating, melting the dried salt coating to yield a molten salt mixture, reacting the molten salt mixture with the zirconium oxide coating to yield lithium lanthanum zirconate, and cooling the lithium lanthanum zirconate to yield a lithium lanthanum zirconate coating on the substrate. In some cases, the zirconium oxide coating is contacted with an aqueous molten salt mixture including a lithium salt and a lanthanum salt, the molten salt mixture is reacted with the zirconium oxide coating to yield lithium lanthanum zirconate, and the lithium lanthanum zirconate is cooled to yield a lithium lanthanum zirconate coating on the substrate.

Forming a lithium lanthanum zirconate thin film includes disposing zirconium oxide on a substrate to yield a zirconium oxide coating, contacting the zirconium oxide coating with a solution including a lithium salt and a lanthanum salt, heating the substrate to yield a dried salt coating on the zirconium oxide coating, melting the dried salt coating to yield a molten salt mixture, reacting the molten salt mixture with the zirconium oxide coating to yield lithium lanthanum zirconate, and cooling the lithium lanthanum zirconate to yield a lithium lanthanum zirconate coating on the substrate. In some cases, the zirconium oxide coating is contacted with an aqueous molten salt mixture including a lithium salt and a lanthanum salt, the molten salt mixture is reacted with the zirconium oxide coating to yield lithium lanthanum zirconate, and the lithium lanthanum zirconate is cooled to yield a lithium lanthanum zirconate coating on the substrate.

An article and method for forming a coated metal pipe for use as an automotive fluid transport tube including a copper plated carbon steel tubing formed into a circular cross sectional profile. At least one intermediate layer including any of a corrosion inhibiting zinc/aluminum alloy, electroplated zinc or hot dip aluminum is applied over said tubing. One or more outer polymer or copolymer layers are applied over the intermediate layer, with the outer layer or multi-layers compounded with a graphene or graphene oxide powder.

A method of disposing a corrosion resistant system to a substrate may comprise applying a plating material to the substrate; forming a chemical conversion coating solution by combining a solvent, at least one corrosion inhibitive cation comprising at least one of zinc, calcium, strontium, magnesium, or aluminum, at least one corrosion inhibitive anion comprising at least one of phosphate, molybdate, or silicate, and a complexing agent; and applying the chemical conversion coating solution to the plating material on the substrate.

A method of disposing a corrosion resistant system to a substrate may comprise applying a plating material to the substrate; forming a chemical conversion coating solution by combining a solvent, at least one corrosion inhibitive cation comprising at least one of zinc, calcium, strontium, magnesium, or aluminum, at least one corrosion inhibitive anion comprising at least one of phosphate, molybdate, or silicate, and a complexing agent; and applying the chemical conversion coating solution to the plating material on the substrate.

A method for anti-corrosion pre-treatment of metal substrates using zirconium-based aqueous anti-corrosion agents comprising polycyclic hydrocarbons that have at least one anellated benzene ring, each having at least two ring-substituted hydroxyl groups in ortho position to each other. The aqueous anti-corrosion agent can be substantially free both of passivating chromium-containing compounds and of fluoride-containing compounds that pickle the metal substrate. Pre-treatment by drying (dry-in-place method) is especially advantageous. Accordingly, the method according to the invention is suitable in particular for the pre-treatment of metal strip, wherein excellent anti-corrosion results are achieved on surfaces of aluminum or steel. The invention further relates to a method for producing coated can lids from aluminum strip by using the previously mentioned zirconium-based anti-corrosion agent. A further aspect comprises an aqueous concentrate for providing the ready-to-use anti-corrosion agents.

Disclosed is a copper alloy article including: a substrate 10 made of a copper alloy; a polyester-based resin body 40; and a compound layer 20 for bonding the substrate 10 and the polyester-based resin body 40, wherein the compound layer 20 contains; a compound having a nitrogen-containing functional group and a silanol group, and an alkane type amine-based silane coupling agent.

Disclosed is a copper alloy article including: a substrate 10 made of a copper alloy; a polyester-based resin body 40; and a compound layer 20 for bonding the substrate 10 and the polyester-based resin body 40, wherein the compound layer 20 contains; a compound having a nitrogen-containing functional group and a silanol group, and an alkane type amine-based silane coupling agent.

The invention relates to a method for preparing a metal sheet (1) comprising at least the steps of: providing a steel substrate (3) having two faces (5), for which at least one is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.

The invention relates to a method for preparing a metal sheet (1) comprising at least the steps of: providing a steel substrate (3) having two faces (5), for which at least one is coated with a metal coating (7) comprising at least 40% by weight of zinc, applying on the outer surface (15) of the metal coating (7) an aqueous solution comprising an amino acid, and the metal sheet which may be obtained.