The present inventive concept is related to metal nanoparticles, such as silver (Ag) nanoparticles, including a metal core and a surface to the metal core functionalized with a positively charged molecule/polymer coating the surface such as amino (—NH.sub.2), amide ([C═O]—N), polyethyleneimine/branched polyethyleneimine (PEI/BPEI), pesticidal compositions including the metal nanoparticle, and methods of using the pesticidal compositions including the metal nanoparticle.

The present inventive concept is related to metal nanoparticles, such as silver (Ag) nanoparticles, including a metal core and a surface to the metal core functionalized with a positively charged molecule/polymer coating the surface such as amino (—NH.sub.2), amide ([C═O]—N), polyethyleneimine/branched polyethyleneimine (PEI/BPEI), pesticidal compositions including the metal nanoparticle, and methods of using the pesticidal compositions including the metal nanoparticle.

A multilayer film containing up to 15 wt % of a blend of cis-13-docosenamide and at least one primary antimicrobial material on or in an exterior layer of the film. The blend of cis-13-docosenamide and at least one primary antimicrobial material is either extruded as part of the surface layer of the film or coated onto the surface of the film.

A multilayer film containing up to 15 wt % of a blend of cis-13-docosenamide and at least one primary antimicrobial material on or in an exterior layer of the film. The blend of cis-13-docosenamide and at least one primary antimicrobial material is either extruded as part of the surface layer of the film or coated onto the surface of the film.

A reloadable microcapsule contains a microcapsule core and a microcapsule wall encapsulating the microcapsule core. The microcapsule core contains a hydrophobic core solvent and a hydrophilic core solvent, and the microcapsule wall, formed of an encapsulating polymer, is permeable to the hydrophilic core solvent. Also disclosed are methods of preparing the reloadable microcapsule and consumer products having the microcapsules.

A reloadable microcapsule contains a microcapsule core and a microcapsule wall encapsulating the microcapsule core. The microcapsule core contains a hydrophobic core solvent and a hydrophilic core solvent, and the microcapsule wall, formed of an encapsulating polymer, is permeable to the hydrophilic core solvent. Also disclosed are methods of preparing the reloadable microcapsule and consumer products having the microcapsules.

A reloadable microcapsule contains a microcapsule core and a microcapsule wall encapsulating the microcapsule core. The microcapsule core contains a hydrophobic core solvent and a hydrophilic core solvent, and the microcapsule wall, formed of an encapsulating polymer, is permeable to the hydrophilic core solvent. Also disclosed are methods of preparing the reloadable microcapsule and consumer products having the microcapsules.

A reloadable microcapsule contains a microcapsule core and a microcapsule wall encapsulating the microcapsule core. The microcapsule core contains a hydrophobic core solvent and a hydrophilic core solvent, and the microcapsule wall, formed of an encapsulating polymer, is permeable to the hydrophilic core solvent. Also disclosed are methods of preparing the reloadable microcapsule and consumer products having the microcapsules.

A method of controlling phytopathogenic diseases on useful plants or on propagation material thereof, which comprises applying to the useful plants, the locus thereof or propagation material thereof a combination of components (A) and (B) in a synergistically effective amount, wherein component (A) is a compound of formula I compound of formula I ##STR00001## wherein R is hydrogen or methoxy; Q is ##STR00002## R.sub.1 is hydrogen, halogen or C.sub.1-C.sub.6alkyl; R.sub.2 is hydrogen, halogen, C.sub.1-C.sub.6alkyl, C.sub.2-C.sub.6alkenyl, C.sub.3-C.sub.6alkinyl, C.sub.3-C.sub.6cycloalkyl-C.sub.3-C.sub.6alkinyl, halophenoxy, halophenyl-C.sub.3-C.sub.6alkinyl, C(C.sub.1-C.sub.4alkyl)=NO—C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.6haloalkyl, C.sub.1-C.sub.6haloalkoxy, C.sub.2-C.sub.6haloalkenyl, or C.sub.2-C.sub.6haloalkenyloxy; R.sub.3 is hydrogen, halogen, C.sub.1-C.sub.6alkyl; R.sub.4, R.sub.5 and R.sub.6, independently from each other, are hydrogen, halogen or —≡—R.sub.7; with the proviso that at least one of R.sub.4, R.sub.5 and R.sub.6 is different from hydrogen; R.sub.7 is hydrogen, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6haloalkyl or C.sub.1-C.sub.4alkoxyalkyl; and R.sub.8 is hydrogen or methoxy; and agrochemically acceptable salts/isomers/structural isomers/stereoisomers/diastereoisomers/enantiomers/tautomers and N-oxides of those compounds; and component (B) is a compound selected from compounds known for their fungicidal and/or insecticidal activity, is particularly effective in controlling or preventing fungal diseases of useful plants.

A method of controlling phytopathogenic diseases on useful plants or on propagation material thereof, which comprises applying to the useful plants, the locus thereof or propagation material thereof a combination of components (A) and (B) in a synergistically effective amount, wherein component (A) is a compound of formula I compound of formula I ##STR00001## wherein R is hydrogen or methoxy; Q is ##STR00002## R.sub.1 is hydrogen, halogen or C.sub.1-C.sub.6alkyl; R.sub.2 is hydrogen, halogen, C.sub.1-C.sub.6alkyl, C.sub.2-C.sub.6alkenyl, C.sub.3-C.sub.6alkinyl, C.sub.3-C.sub.6cycloalkyl-C.sub.3-C.sub.6alkinyl, halophenoxy, halophenyl-C.sub.3-C.sub.6alkinyl, C(C.sub.1-C.sub.4alkyl)=NO—C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.6haloalkyl, C.sub.1-C.sub.6haloalkoxy, C.sub.2-C.sub.6haloalkenyl, or C.sub.2-C.sub.6haloalkenyloxy; R.sub.3 is hydrogen, halogen, C.sub.1-C.sub.6alkyl; R.sub.4, R.sub.5 and R.sub.6, independently from each other, are hydrogen, halogen or —≡—R.sub.7; with the proviso that at least one of R.sub.4, R.sub.5 and R.sub.6 is different from hydrogen; R.sub.7 is hydrogen, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6haloalkyl or C.sub.1-C.sub.4alkoxyalkyl; and R.sub.8 is hydrogen or methoxy; and agrochemically acceptable salts/isomers/structural isomers/stereoisomers/diastereoisomers/enantiomers/tautomers and N-oxides of those compounds; and component (B) is a compound selected from compounds known for their fungicidal and/or insecticidal activity, is particularly effective in controlling or preventing fungal diseases of useful plants.