Disclosed is a method of treating a substrate, comprising contacting at least a portion of the substrate surface with a first composition comprising a lanthanide source and an oxidizing agent. A substrate obtainable by the methods also is disclosed.

Disclosed is a method of treating a substrate, comprising contacting at least a portion of the substrate surface with a first composition comprising a lanthanide source and an oxidizing agent. A substrate obtainable by the methods also is disclosed.

Described herein is a method for treatment of at least one surface of a metal containing substrate including contacting the surface with an aqueous acidic Ni-free composition (A) including at least zinc cations, manganese cations, and phosphate anions to form a conversion coating on the surface, and contacting the formed coating with an aqueous Ni-free composition (B) including one or more linear polymers (P) containing vinyl phosphonic acid and (meth)acrylic acid in form of their polymerized monomeric units. Also described herein is a composition (B) as such, a master batch to produce the composition (B), a kit-of-parts including both compositions (A) and (B), a kit-of-parts including respective master batches to produce both compositions (A) and (B), and a coated substrate obtainable by the method described herein.

Described herein is a method for treatment of at least one surface of a metal containing substrate including contacting the surface with an aqueous acidic Ni-free composition (A) including at least zinc cations, manganese cations, and phosphate anions to form a conversion coating on the surface, and contacting the formed coating with an aqueous Ni-free composition (B) including one or more linear polymers (P) containing vinyl phosphonic acid and (meth)acrylic acid in form of their polymerized monomeric units. Also described herein is a composition (B) as such, a master batch to produce the composition (B), a kit-of-parts including both compositions (A) and (B), a kit-of-parts including respective master batches to produce both compositions (A) and (B), and a coated substrate obtainable by the method described herein.

A method for the preliminary treatment against corrosion of a plurality of metallic components, in which dragging of water-soluble phosphates from an acid passivation process using water-dissolved phosphates as the active components, e.g. a phosphating process, into the dip coating treatment stage, is effectively prevented.

A method for the preliminary treatment against corrosion of a plurality of metallic components, in which dragging of water-soluble phosphates from an acid passivation process using water-dissolved phosphates as the active components, e.g. a phosphating process, into the dip coating treatment stage, is effectively prevented.

The present invention discloses a durable super-hydrophobic manganese dioxide coating and a preparation method thereof, belonging to the field of metallic material surface treatment. In the method, by using manganese sulfate as a raw material, based on the property of interface reaction, a manganese dioxide coating is synthesized on the metallic material surface by simple and convenient solution impregnation, and then processed by hydrophobization with stearic acid to obtain a super-hydrophobic manganese dioxide coating. This coating has excellent chemical stability to organic solvents such as n-hexane, isooctane, dodecane, tetradecane, and acids, alkali and salt solutions at different pH values, and exhibits great resistance against dynamic water shear and good durability, with broad application prospect.

A process for anticorrosion treatment of a metallic surface, including bringing the surface into successive contact with the an alkaline or acidic cleaner composition, a first rinsing composition, optionally a second rinsing composition, an acidic conversion composition, optionally a third rinsing composition, and a composition including a (meth)acrylate- and/or epoxide-based cathodic electrophoretic coating. At least one of the compositions includes at least one compound of the formula R.sup.1O—(CH.sub.2).sub.x—Z—(CH.sub.2).sub.y—OR.sup.2. R.sup.1 and R.sup.2 are each, independently of one another, H or an HO—(CH.sub.2).sub.w— group with w≥2. X and y are each, independently of one another, from 1 to 4 and Z is an S atom or a C—C triple bond. An aqueous composition for reducing corrosive removal of material in anticorrosion treatment of metallic surfaces is disclosed.

A process for anticorrosion treatment of a metallic surface, including bringing the surface into successive contact with the an alkaline or acidic cleaner composition, a first rinsing composition, optionally a second rinsing composition, an acidic conversion composition, optionally a third rinsing composition, and a composition including a (meth)acrylate- and/or epoxide-based cathodic electrophoretic coating. At least one of the compositions includes at least one compound of the formula R.sup.1O—(CH.sub.2).sub.x—Z—(CH.sub.2).sub.y—OR.sup.2. R.sup.1 and R.sup.2 are each, independently of one another, H or an HO—(CH.sub.2).sub.w— group with w≥2. X and y are each, independently of one another, from 1 to 4 and Z is an S atom or a C—C triple bond. An aqueous composition for reducing corrosive removal of material in anticorrosion treatment of metallic surfaces is disclosed.

Described herein is a method for treatment of at least one surface of a substrate at least partially made of aluminum and/or an aluminum alloy, including at least a step of contacting said surface with an acidic aqueous composition (A) including one or more metal compounds (M) selected from the group of titanium compounds, zirconium compounds, and hafnium compounds and one or more linear polymers (P) containing (m1) N,N-dimethyl (meth)acryl amide, (m2) vinylphosphonic acid, and (m3) (meth)acrylic acid in form of their polymerized monomeric units, the one or more linear polymers (P) being included in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm. Also described herein is an acidic aqueous composition (A), a master batch to produce the acidic aqueous composition (A), a method of using the acidic aqueous composition (A) for treating surfaces, and substrates comprising the treated surfaces.