Disclosed is an AMS process using a water-leachable alloy that reacts with water and dissolves, and a porous metal manufactured using the same. An AMS precursor including element groups that are selected in consideration of the relationship of heat of mixing with the water-leachable alloy composition to be subjected to the AMS process is immersed in the alloy melt, thus manufacturing a bi-continuous structure alloy. The bi-continuous structure alloy is subjected to dealloying using water, thus manufacturing the porous metal. The water-leachable alloy is a Ca-based alloy having high reactivity to water and high oxidation resistance at high temperatures, and a dealloying process thereof is performed using only pure water, unlike a conventional dealloying process performed using a toxic etching solution of a strong acid/strong base. The metal porous body has high elongation, a large surface area, and low thermal conductivity.

Disclosed is an AMS process using a water-leachable alloy that reacts with water and dissolves, and a porous metal manufactured using the same. An AMS precursor including element groups that are selected in consideration of the relationship of heat of mixing with the water-leachable alloy composition to be subjected to the AMS process is immersed in the alloy melt, thus manufacturing a bi-continuous structure alloy. The bi-continuous structure alloy is subjected to dealloying using water, thus manufacturing the porous metal. The water-leachable alloy is a Ca-based alloy having high reactivity to water and high oxidation resistance at high temperatures, and a dealloying process thereof is performed using only pure water, unlike a conventional dealloying process performed using a toxic etching solution of a strong acid/strong base. The metal porous body has high elongation, a large surface area, and low thermal conductivity.

A method for forming a plurality of precision holes in a substrate by drilling, including affixing a sacrificial cover layer to a surface of the substrate, positioning a laser beam in a predetermined location relative to the substrate and corresponding to a desired location of one of the plurality of precision holes, forming a through hole in the sacrificial cover layer by repeatedly pulsing a laser beam at the predetermined location, and pulsing the laser beam into the through hole formed in the sacrificial cover layer. A work piece having precision holes including a substrate having the precision holes formed therein, wherein a longitudinal axis of each precision hole extends in a thickness direction of the substrate, and a sacrificial cover layer detachably affixed to a surface of the substrate, such that the sacrificial cover layer reduces irregularities of the precision holes.

A method for forming a plurality of precision holes in a substrate by drilling, including affixing a sacrificial cover layer to a surface of the substrate, positioning a laser beam in a predetermined location relative to the substrate and corresponding to a desired location of one of the plurality of precision holes, forming a through hole in the sacrificial cover layer by repeatedly pulsing a laser beam at the predetermined location, and pulsing the laser beam into the through hole formed in the sacrificial cover layer. A work piece having precision holes including a substrate having the precision holes formed therein, wherein a longitudinal axis of each precision hole extends in a thickness direction of the substrate, and a sacrificial cover layer detachably affixed to a surface of the substrate, such that the sacrificial cover layer reduces irregularities of the precision holes.

A method for preparing a three-dimensional porous graphene material, including: a) constructing a CAD model corresponding to a required three-dimensional porous structure, and designing an external shape and internal structure parameters of the model; b) based on the CAD model, preparing a three-dimensional porous metal structure using a metal powder as material; c) heating the three-dimensional porous metal structure and preparing a metal template of the required three-dimensional porous structure; d) placing the metal template in a tube furnace and heating the metal template to a temperature of between 800 and 1000 C.; standing for 0.5-1 hr, introducing a carbon source to the tube furnace for continued reaction, cooling resulting products to room temperature to yield a three-dimensional graphene grown on the metal template; and e) preparing a corrosive solution, and immersing the three-dimensional graphene in the corrosive solution.

A method for preparing a three-dimensional porous graphene material, including: a) constructing a CAD model corresponding to a required three-dimensional porous structure, and designing an external shape and internal structure parameters of the model; b) based on the CAD model, preparing a three-dimensional porous metal structure using a metal powder as material; c) heating the three-dimensional porous metal structure and preparing a metal template of the required three-dimensional porous structure; d) placing the metal template in a tube furnace and heating the metal template to a temperature of between 800 and 1000 C.; standing for 0.5-1 hr, introducing a carbon source to the tube furnace for continued reaction, cooling resulting products to room temperature to yield a three-dimensional graphene grown on the metal template; and e) preparing a corrosive solution, and immersing the three-dimensional graphene in the corrosive solution.

A metal member includes a metal substrate and a porous metal layer. A composite includes the metal member and a resin member. The metal substrate has one surface, is made of a metal material, and has a region formed as an uneven layer having an uneven shape with respect to the one surface. The porous metal layer has a mesh-like shape and is formed on the uneven layer. The uneven layer includes a plurality of protrusions protruding in a direction normal to the one surface.

A pressure vessel has a first end with a first boss, the first boss having a first outer surface. The vessel includes a liner having a second outer surface, a shell disposed over the second outer surface, and a first vent. The first vent is formed onto at least a portion of the first outer surface and at least a portion of the second outer surface. The first vent includes a texture that provides a higher rate of gas flow through the first vent than through a portion of an interface of the liner and shell lacking the texture. In another aspect, a pressure vessel has a first end and a second end, a plurality of first longitudinal vents and a plurality of second longitudinal vents. At least one of first longitudinal vents is circumferentially offset around the pressure vessel from at least one of the second longitudinal vents.

A pressure vessel has a first end with a first boss, the first boss having a first outer surface. The vessel includes a liner having a second outer surface, a shell disposed over the second outer surface, and a first vent. The first vent is formed onto at least a portion of the first outer surface and at least a portion of the second outer surface. The first vent includes a texture that provides a higher rate of gas flow through the first vent than through a portion of an interface of the liner and shell lacking the texture. In another aspect, a pressure vessel has a first end and a second end, a plurality of first longitudinal vents and a plurality of second longitudinal vents. At least one of first longitudinal vents is circumferentially offset around the pressure vessel from at least one of the second longitudinal vents.

The invention relates to three-dimensional crystalline foams with high surface areas, high lithium capacity, and high conductivity for use as electrode materials and methods for their fabrication. In additional embodiments, the invention also relates to the use of three-dimensional crystalline foams as supercapacitors for improved charge and energy storage.