Disclosed are combinations of substances for stimulus-dependent release of vapor phase corrosion inhibitors including: (1) a matrix; (2) at least one symmetrical or asymmetrical carboxylic acid anhydride of at least one first carboxylic acid, (3) at least one salt of at least one second, highly volatile corrosion-inhibiting carboxylic acid, wherein (2) is a non-volatile anhydride or an anhydride with low volatility with a vapor pressure of preferably lower than 1×10.sup.−3 Pa at 25° C. The combination is effective to release the first carboxylic acid(s) by hydrolysis of the anhydride and release the second carboxylic acid(s) of (3) from its salt by proton transfer from first carboxylic acid(s), so that the second carboxylic acid(s) is/are present as a corrosion inhibitor in the vapor phase. Also disclosed are methods for producing and using the combinations for corrosion protection of conventional industrially used metals, in, e.g., packing, storage and transport processes.

Disclosed are combinations of substances for stimulus-dependent release of vapor phase corrosion inhibitors including: (1) a matrix; (2) at least one symmetrical or asymmetrical carboxylic acid anhydride of at least one first carboxylic acid, (3) at least one salt of at least one second, highly volatile corrosion-inhibiting carboxylic acid, wherein (2) is a non-volatile anhydride or an anhydride with low volatility with a vapor pressure of preferably lower than 1×10.sup.−3 Pa at 25° C. The combination is effective to release the first carboxylic acid(s) by hydrolysis of the anhydride and release the second carboxylic acid(s) of (3) from its salt by proton transfer from first carboxylic acid(s), so that the second carboxylic acid(s) is/are present as a corrosion inhibitor in the vapor phase. Also disclosed are methods for producing and using the combinations for corrosion protection of conventional industrially used metals, in, e.g., packing, storage and transport processes.

The present disclosure describes methods of controlling corrosion in aqueous heat transfer systems, such as boiler systems. The methods add a morpholine generating agent to the aqueous heat transfer system. The methods form morpholine in situ by the partial decomposition of the morpholine generating agent in the aqueous heat transfer system.

The present disclosure describes methods of controlling corrosion in aqueous heat transfer systems, such as boiler systems. The methods add a morpholine generating agent to the aqueous heat transfer system. The methods form morpholine in situ by the partial decomposition of the morpholine generating agent in the aqueous heat transfer system.

A volatile corrosion inhibitor composition comprising about 1 wt. % to about 100 wt. % of a polyacrylamide is disclosed that prevents corrosion of metal materials. A volatile corrosion inhibitor composition may also include a second volatile corrosion inhibitor selected from the group consisting of: ammonium salt, triazole, nitrite, nitrate, an amine carboxylate, an amine, a carboxylic acid, aldehyde, anhydride and any combination thereof. An anticorrosion method of a metal material using the volatile corrosion inhibitor composition is also disclosed.

Substance combinations are disclosed which include urea, at least one chitosan biopolymer having a degree of deacetylation of from 70% to 95%, and at least one dicarboxylic acid in aqueous solution. The substance combinations are useful as primers for the pretreating substrate surfaces, in particular flat or sheet-form, non-metallic substrates, which are provided as carrier materials for vapor phase corrosion inhibitors, to enable subsequent fixing to those substrate surfaces of vapor phase corrosion inhibitors from an aqueous or aqueous-alcoholic solution containing them. Certain embodiments of the substance combination include 0.1-2% by weight chitosan biopolymer, 10-25% by weight urea, and 0.5-2.5% by weight of a dicarboxylic acid, completely dissolved in deionized water. Yet a further, related aspect of the invention relates to a carrier material for vapor phase corrosion inhibitors, wherein the vapor phase corrosion inhibitors are fixed to a substrate surface pretreated with the substance combination.

Substance combinations are disclosed which include urea, at least one chitosan biopolymer having a degree of deacetylation of from 70% to 95%, and at least one dicarboxylic acid in aqueous solution. The substance combinations are useful as primers for the pretreating substrate surfaces, in particular flat or sheet-form, non-metallic substrates, which are provided as carrier materials for vapor phase corrosion inhibitors, to enable subsequent fixing to those substrate surfaces of vapor phase corrosion inhibitors from an aqueous or aqueous-alcoholic solution containing them. Certain embodiments of the substance combination include 0.1-2% by weight chitosan biopolymer, 10-25% by weight urea, and 0.5-2.5% by weight of a dicarboxylic acid, completely dissolved in deionized water. Yet a further, related aspect of the invention relates to a carrier material for vapor phase corrosion inhibitors, wherein the vapor phase corrosion inhibitors are fixed to a substrate surface pretreated with the substance combination.

Corrosion preventative devices configured to be inserted within a storage container are disclosed. The exemplary corrosion preventative devices are made from or otherwise include a material configured to release corrosion protection molecules.

Corrosion preventative devices configured to be inserted within a storage container are disclosed. The exemplary corrosion preventative devices are made from or otherwise include a material configured to release corrosion protection molecules.

A corrosion risk reduction method includes introducing volatile corrosion inhibitor into a piping system, and distributing the volatile corrosion inhibitor inside the system. A corrosion risk reduction apparatus comprises at least one corrosion risk reduction module, which comprises a housing including inlet and outlet ports. The housing contains a volatile corrosion inhibitor. An outlet of the corrosion risk reduction apparatus is configured for fluid communication with a system, and is further configured to direct gas containing volatile corrosion inhibitor from the inside of the housing of the at least one corrosion risk reduction module into the system for distribution inside the system. A volatile corrosion inhibitor detection device comprises a coupling for coupling to a system configured to be closed, and a housing in fluid communication with the coupling and containing an indicator element configured to visually change upon contact with volatile corrosion inhibitor.