Corrosion inhibitor compositions are provided that can include a mixture of one or more alkaline earth metals, one or more organic phosphates, one or more inorganic phosphates, optionally a dispersant, and hydroxyphosphono acetic acid and/or salts thereof and/or derivatives of hydroxyphosphono acetic acid and/or salts thereof. Methods of mitigating or inhibiting corrosion of metal surfaces are also disclosed. The methods can include the steps of adding a corrosion inhibitor composition as described in the present disclosure to a medium in contact with the metal surface and optionally to the metal surface before it is contacted by the medium.

A system and method for delivering volatile corrosion inhibitor (VCI) for protecting against external corrosion to the bottom, soil-side, surface of a storage tank is disclosed. The VCI delivery system can include a transport material buried underneath the tank and a carrier structure for containing the transport material. VCI can be supplied to the transport material from an external VCI storage tank and the supply regulated by a control valve. The transport material is configured to adaptively and controllably release VCI into the soil in response an external stimulus. The transport material can passively adjust the VCI release rate as a function of a stimulus including pH or soil potential. Additionally, a control system can monitor soil conditions and generate the stimulus that triggers the release of the VCI. Also disclosed are systems and methods for deploying the VCI delivery system under the tank using horizontal drilling techniques.

A system and method for delivering volatile corrosion inhibitor (VCI) for protecting against external corrosion to the bottom, soil-side, surface of a storage tank is disclosed. The VCI delivery system can include a transport material buried underneath the tank and a carrier structure for containing the transport material. VCI can be supplied to the transport material from an external VCI storage tank and the supply regulated by a control valve. The transport material is configured to adaptively and controllably release VCI into the soil in response an external stimulus. The transport material can passively adjust the VCI release rate as a function of a stimulus including pH or soil potential. Additionally, a control system can monitor soil conditions and generate the stimulus that triggers the release of the VCI. Also disclosed are systems and methods for deploying the VCI delivery system under the tank using horizontal drilling techniques.

A method of inhibiting corrosion of a metal surface in contact with geothermal system is provided. The method may include contacting the metal surface with a corrosion inhibitor composition by adding the composition to geothermal process water. The corrosion inhibitor composition may include an organic phosphonate, an ortho phosphate, and zinc or a salt thereof.

A method of inhibiting corrosion of a metal surface in contact with geothermal system is provided. The method may include contacting the metal surface with a corrosion inhibitor composition by adding the composition to geothermal process water. The corrosion inhibitor composition may include an organic phosphonate, an ortho phosphate, and zinc or a salt thereof.

Methods and compositions for inhibiting corrosion of a corrodible metal surface that contact a nitrogen-containing solution. The method comprises adding a chemical treatment composition to the nitrogen-containing solution that includes an organic filmer and a passivator. The organic filmer may be a hydroxycarboxylic acid. The chemical treatment composition may further include a surface-active compound.

A method for inhibiting corrosion of pipelines and other metal surfaces, particularly those used in the oil-and-gas industry, is disclosed. The method comprises treating a brine-exposed metal surface with a film-forming composition. The composition comprises a quaternary surfactant, which is made by reacting a polyalkylene glycol (PAG), a haloalkanoic acid, and a tertiary fatty amine that optionally incorporates amide or ester functionality. The surfactant comprises a PAG monoester quat and a PAG diester diquat and may have other components. The quaternary surfactants provide good corrosion protection and can partition effectively from an oily phase into a brine phase in the absence of agitation. The surfactants are easy to synthesize economically and have structures that can be tailored to meet local HLB requirements.

The present invention relates to glycol based heat-transfer fluids exhibiting corrosion inhibition and comprising more than 5 wt. % (by total weight of the composition) of a glycol selected from the group consisting of monoethylene glycol, monopropylene glycol, 1,3-propanediol, glycerol or combinations thereof; and more than 1 wt. % (by total weight of the composition) of a short-chain organic carboxylic acid or salt thereof selected from the group consisting of C.sub.2 organic carboxylic acids or salts thereof, C.sub.3 organic carboxylic acids or salts thereof and combinations thereof; wherein the combined amount of the glycol and the short-chain organic carboxylic acid or salt thereof is more than 15 wt. % (by total weight of the composition). The invention further relates to concentrates for the preparation of said heat-transfer fluids, to methods for the preparation of said heat-transfer fluids, and to the methods and uses employing said heat-transfer fluids.

With the present invention, sustainable systems for corrosion, inhibition in the processing of metals (in particular iron, aluminum and magnesium) are made available. These systems being in full accordance with the principles of green chemistry comprise an amino acid as neutralizing component for an acidic corrosion inhibitor, whereby the amino acid is used in deprotonated form. The resulting metalworking fluids may be water- or oil-based or semi synthetic formulations. The neutralization of acidic corrosion inhibitors with the claimed system comprising an amino acid consistently achieves convincing results and, together with acidic corrosion inhibitors from corresponding sources, completely renewable systems for corrosion inhibition are provided.

An organic blend chemical additive comprising more than 50 wt. % organic solvent (e.g. methanol and/or ethylene glycol), less than 10 wt. % water, a nitrate salt, a maleic acid copolymer, and optionally an imidazoline may be delivered to a production well through a conduit having a stainless steel and corrosion resistant metal alloy surface, such as a capillary string or an umbilical tubing, the organic blend chemical additive being shown to be useful in inhibiting localized corrosion of and improving the repassivation of the equipment or conduit.