A method of hydrogenating carbon dioxide comprises forming a tunable catalyst comprising at least one metal comprising a size within a range of from a single atom to about 999 nanometers and formulated to produce one or more carbon-containing compound. An electrochemical cell comprising a positive electrode, a negative electrode comprising the tunable catalyst, and an electrolyte between the positive electrode and the negative electrode is formed. Carbon dioxide is introduced to the negative electrode of the electrochemical cell and a potential difference is applied between the positive electrode and the negative electrode to selectively hydrogenate the carbon dioxide. The hydrogen ions are diffused through the electrochemical cell. The carbon dioxide at the negative electrode is hydrogenated to selectively form carbon monoxide, methane, or a desired ratio of carbon monoxide and methane. An electrochemical cell and a carbon dioxide hydrogenation system are also disclosed.

What is proposed is an apparatus for conducting an electrolysis with an oxygen depolarized cathode, comprising: (a) an electrolyzer 1 which (b) is connected on the reactant side via an inlet control valve 2 to an oxygen source 3, and (c) on the product side has at least one off gas line 4, (d) which has at least one pressure regulator (PT) 5, at least one gas analyzer (QI) 6, at least one flow regulator (FT) 7 and at least one outlet control valve 8, wherein (e) the pressure regulator 5 controls the inlet control valve 2, (f) the gas analyzer 6 controls the flow regulator 7 or the outlet control valve 8 and/or (g) the flow regulator 7 controls the outlet control valve 8.

An electrolytic system and method of manufacturing white phosphorus.

An electrolytic system and method of manufacturing white phosphorus.

A method of producing graphite may include beneficiating an amount of coal to form a coal char, grinding the coal char to produce a crushed char and placing the crushed char in a porous container. Then, the method includes immersing the porous container in a molten salt bath. The molten salt bath includes a graphite anode. The method further includes applying an electrical potential across the porous container and the graphite anode such that a graphite deposit forms on the graphite anode. The graphite anode is removed from the molten salt bath and the graphite deposit is separated from the graphite anode to produce graphite fragments.

A method of producing graphite may include beneficiating an amount of coal to form a coal char, grinding the coal char to produce a crushed char and placing the crushed char in a porous container. Then, the method includes immersing the porous container in a molten salt bath. The molten salt bath includes a graphite anode. The method further includes applying an electrical potential across the porous container and the graphite anode such that a graphite deposit forms on the graphite anode. The graphite anode is removed from the molten salt bath and the graphite deposit is separated from the graphite anode to produce graphite fragments.

The invention relates to an integrated process for continuous production of liquid hydrogen, comprising (a) producing gaseous hydrogen by electrolysis; and (b) liquefying said gaseous hydrogen in a hydrogen liquefaction unit, which liquefaction unit is powered by energy essentially from renewable sources; and, (c) when additional power is needed, using electrical energy generated in a process in which electrical energy and hydrogen are co-generated by an integrated electrolysis process comprising: (d) electrolysing a metal salt or mixture of metal salts and water into the corresponding metal or metals, acid or acids, and oxygen (electricity storage phase), and (e) producing gaseous hydrogen and recovering electricity in a regeneration reaction of the metal (s) and acid(s) of step (d) (regeneration phase); wherein at least part of the gaseous hydrogen generated in step (e) is used in step (b) of the process.

The present disclosure relates to the field of new materials, and aims at providing an A-site high-entropy nanometer metal oxide with high conductivity, and a preparation method thereof. The metal oxide has molecular formula of Gd.sub.0.4Er.sub.0.3La.sub.0.4Nd.sub.0.5Y.sub.0.4)(Zr.sub.0.7, Sn.sub.0.8, V.sub.0.5)O.sub.7 and is a powder, and has microstructure of the metal oxide as a square namometer sheet with a side length of 4-12 nm and a thickness of 1-3 nm. Compared with an existing high-entropy oxide, the product in the present disclosure has high conductivity, and can be well applied to a conductive alloy, an electrical contact composite material, a conductive composite material, a multifunctional bio-based composite material, a conductive/antistatic composite coating and the like.

The present disclosure relates to the field of new materials, and aims at providing an A-site high-entropy nanometer metal oxide with high conductivity, and a preparation method thereof. The metal oxide has molecular formula of Gd.sub.0.4Er.sub.0.3La.sub.0.4Nd.sub.0.5Y.sub.0.4)(Zr.sub.0.7, Sn.sub.0.8, V.sub.0.5)O.sub.7 and is a powder, and has microstructure of the metal oxide as a square namometer sheet with a side length of 4-12 nm and a thickness of 1-3 nm. Compared with an existing high-entropy oxide, the product in the present disclosure has high conductivity, and can be well applied to a conductive alloy, an electrical contact composite material, a conductive composite material, a multifunctional bio-based composite material, a conductive/antistatic composite coating and the like.

Large scale exploitation of Solar energy is proposed by using floating devices which use solar energy to produce compressed hydrogen by electrolysis of deep sea water. Natural ocean currents are used to allow the devices to gather solar energy in the form of compressed hydrogen from over a large area with minimum energy transportation cost. The proposal uses a combination of well understood technologies, and a preliminary cost analysis shows that the hydrogen produced in this manner would satisfy the ultimate cost targets for hydrogen production and pave the way for carbon free energy economy.