The embodiments of the present disclosure relate to a method and apparatus for producing a CNM product that may comprise carbon nanotubes (CNTs). The method and apparatus employ carbon dioxide (CO.sub.2) and a carbonate electrolyte that is lithium-free as reactants in an electrolysis reaction in order to make CNTs. In some embodiments of the present disclosure, a graphene-defect agent may be introduced into the electrolysis reaction.

An electrolytic liquid generation device includes stacked body in which conductive membrane is stacked and interposed between cathode and anode adjacent to each other, electrolytic part that electrolyzes liquid, and housing in which electrolytic part is disposed and flow path is formed. Electrolytic part includes slot that is open in flow path, and in the slot, a part of interface between conductive membrane and cathode and anode is exposed. Either one of the electrodes of cathode and anode has an outer periphery smaller in width than slot of electrolytic part. This can provide an electrolytic liquid generation device capable of improving the concentration of an electrolytic product dissolved in liquid.

An electrolytic liquid generation device includes stacked body in which conductive membrane is stacked and interposed between cathode and anode adjacent to each other, electrolytic part that electrolyzes liquid, and housing in which electrolytic part is disposed and flow path is formed. Electrolytic part includes slot that is open in flow path, and in the slot, a part of interface between conductive membrane and cathode and anode is exposed. Either one of the electrodes of cathode and anode has an outer periphery smaller in width than slot of electrolytic part. This can provide an electrolytic liquid generation device capable of improving the concentration of an electrolytic product dissolved in liquid.

Hydrogen peroxide water and, if necessary, sulfuric acid and/or water, are added to a sulfuric acid solution in a storage tank of an electrolytic sulfuric acid solution manufacturing system to enhance the oxidizing power of the sulfuric acid solution supplied to an electrolytic cell to perform electrolysis. The manufacturing system starts up during an initial operation after completion of the system, or after replacement of a sulfuric acid-containing solution in the system, or during an operation after the concentration of a persulfuric acid component in the sulfuric acid solution stored in the system decreases due to shutdown of the system, or other similar situations. By starting up the manufacturing system in this manner, the startup of the system, which manufactures an electrolytic sulfuric acid solution containing a persulfuric acid component generated by electrolyzing sulfuric acid, can be completed in a short time, and the energy consumption can be reduced.

Hydrogen peroxide water and, if necessary, sulfuric acid and/or water, are added to a sulfuric acid solution in a storage tank of an electrolytic sulfuric acid solution manufacturing system to enhance the oxidizing power of the sulfuric acid solution supplied to an electrolytic cell to perform electrolysis. The manufacturing system starts up during an initial operation after completion of the system, or after replacement of a sulfuric acid-containing solution in the system, or during an operation after the concentration of a persulfuric acid component in the sulfuric acid solution stored in the system decreases due to shutdown of the system, or other similar situations. By starting up the manufacturing system in this manner, the startup of the system, which manufactures an electrolytic sulfuric acid solution containing a persulfuric acid component generated by electrolyzing sulfuric acid, can be completed in a short time, and the energy consumption can be reduced.

A system for alkaline water electrolysis includes electrolysis cells, a hydrogen separator tank, a first piping from the electrolysis cells to the hydrogen separator tank, an oxygen separator tank, a second piping from the electrolysis cells to the oxygen separator tank, and a third piping for conducting liquid electrolyte from the hydrogen separator tank and from the oxygen separator tank back to the electrolysis cells. The system includes an ultrasound source for applying ultrasound on the liquid electrolyte contained by the first piping. The ultrasound enhances the separation of dissolved hydrogen gas from the liquid electrolyte contained by the first piping, and thus energy efficiency of the alkaline water electrolysis is improved. Furthermore, a safe control range of the alkaline water electrolysis is broadened because crossover of hydrogen gas to an oxygen side of the system is reduced.

A system for alkaline water electrolysis includes electrolysis cells, a hydrogen separator tank, a first piping from the electrolysis cells to the hydrogen separator tank, an oxygen separator tank, a second piping from the electrolysis cells to the oxygen separator tank, and a third piping for conducting liquid electrolyte from the hydrogen separator tank and from the oxygen separator tank back to the electrolysis cells. The system includes an ultrasound source for applying ultrasound on the liquid electrolyte contained by the first piping. The ultrasound enhances the separation of dissolved hydrogen gas from the liquid electrolyte contained by the first piping, and thus energy efficiency of the alkaline water electrolysis is improved. Furthermore, a safe control range of the alkaline water electrolysis is broadened because crossover of hydrogen gas to an oxygen side of the system is reduced.

A fluid electrolysis apparatus includes: a body part which includes an inlet port and an outlet port formed thereon and is provided with an inner space through which a fluid introduced through the inlet port passes to be discharged through the outlet port; an electrode part mounted in the inner space and including a first electrode plate and a second electrode plate, to which external powers of opposite polarity are applied, respectively, wherein the first electrode plate and the second electrode plate are alternately arranged while being spaced apart from each other, to form a plurality of fluid channels between the first electrode plate and the second electrode plate; and a conductive connection terminal part integrally formed with the body part so that at least a portion of a body thereof is embedded in the body part to apply external power to the electrode.

Provided herein are anode and/or cathode pan assemblies comprising unique manifold, outlet tube, and/or baffle plate configurations; electrochemical cell and/or electrolyzer containing the anode and/or the cathode pan assemblies; and methods to use and manufacture the same.

Provided herein are anode and/or cathode pan assemblies comprising unique manifold, outlet tube, and/or baffle plate configurations; electrochemical cell and/or electrolyzer containing the anode and/or the cathode pan assemblies; and methods to use and manufacture the same.