Various examples are directed to a solar power electrolyzer system comprising a first electrolyzer stack, a second electrolyzer stack, a first converter and a first converter controller. The first electrolyzer stack may be electrically coupled in series with a photovoltaic array. The first converter may be electrically coupled in series with the first electrolyzer stack and electrically coupled in series with the photovoltaic array. The second electrolyzer stack electrically may be coupled at an output of the first converter. The first converter controller may be configured to control a current gain of the first converter.

Various examples are directed to a solar power electrolyzer system comprising a first electrolyzer stack, a second electrolyzer stack, a first converter and a first converter controller. The first electrolyzer stack may be electrically coupled in series with a photovoltaic array. The first converter may be electrically coupled in series with the first electrolyzer stack and electrically coupled in series with the photovoltaic array. The second electrolyzer stack electrically may be coupled at an output of the first converter. The first converter controller may be configured to control a current gain of the first converter.

The invention provides a method of storing varying or intermittent electrical energy and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) with an energy apparatus, the method comprising: providing the first cell aqueous liquid, the second cell aqueous liquid, and electrical power from an external power source to the functional unit thereby providing an electrically charged functional battery unit and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) stored in said storage system, wherein during at least part of a charging time the functional unit is charged at a potential difference between the first cell electrode and the second cell electrode of more than 1.37 V.

The invention provides a method of storing varying or intermittent electrical energy and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) with an energy apparatus, the method comprising: providing the first cell aqueous liquid, the second cell aqueous liquid, and electrical power from an external power source to the functional unit thereby providing an electrically charged functional battery unit and one or more of hydrogen (H.sub.2) and oxygen (O.sub.2) stored in said storage system, wherein during at least part of a charging time the functional unit is charged at a potential difference between the first cell electrode and the second cell electrode of more than 1.37 V.

An electrochemical process implements, in a decoupled manner, a first step of electrolysis of an electrolyte to produce gaseous oxygen in a chamber and a second step of electrochemical conversion of H+ ions into gaseous hydrogen in a chamber which contains a liquid phase and a gas phase not dissolved in the liquid phase. Gaseous hydrogen produced in the conversion step is partly present in the gaseous headspace of chamber and as bubbles in the electrolyte, and partly dissolved in the electrolyte which is saturated with hydrogen. The electrolyte has at least one redox pair (A/B) forming at least one intermediate vector enabling the decoupling of the first and second steps. The interface between the gas and liquid phases is increased during the second step to accelerate the diffusion, from liquid phase to gas phase, of the dissolved hydrogen able to supersaturate the electrolyte. Pressurized gaseous hydrogen is then collected.

An electrochemical process implements, in a decoupled manner, a first step of electrolysis of an electrolyte to produce gaseous oxygen in a chamber and a second step of electrochemical conversion of H+ ions into gaseous hydrogen in a chamber which contains a liquid phase and a gas phase not dissolved in the liquid phase. Gaseous hydrogen produced in the conversion step is partly present in the gaseous headspace of chamber and as bubbles in the electrolyte, and partly dissolved in the electrolyte which is saturated with hydrogen. The electrolyte has at least one redox pair (A/B) forming at least one intermediate vector enabling the decoupling of the first and second steps. The interface between the gas and liquid phases is increased during the second step to accelerate the diffusion, from liquid phase to gas phase, of the dissolved hydrogen able to supersaturate the electrolyte. Pressurized gaseous hydrogen is then collected.

The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H.sub.2S and CO.sub.2. In an exemplary process of this disclosure H.sub.2S is supplied to anode side of an electrochemical cell, while CO.sub.2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO.sub.2 is harvested from the anode side, while synthesis gas, CO+H.sub.2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H.sub.2S and CO.sub.2. In an exemplary process of this disclosure H.sub.2S is supplied to anode side of an electrochemical cell, while CO.sub.2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO.sub.2 is harvested from the anode side, while synthesis gas, CO+H.sub.2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

An electrolyzer stack is configured for high-speed manufacturing and assembly of a plurality of scalable electrolysis cells. Each cell comprises a plurality of water windows configured to maintain a pressure loss, temperature rise and/or oxygen outlet volume fraction below predetermined thresholds. Repeating components of the cells are configured based on a desired roll web width for production and a stack compression system is configured to enable a variable quantity and variable area of said repeating cells in a single stack. A high-speed manufacturing system is configured to produce scalable cells and assemble scalable stacks at rates in excess of 1,000 MW-class stacks per year.

An electrolyzer stack is configured for high-speed manufacturing and assembly of a plurality of scalable electrolysis cells. Each cell comprises a plurality of water windows configured to maintain a pressure loss, temperature rise and/or oxygen outlet volume fraction below predetermined thresholds. Repeating components of the cells are configured based on a desired roll web width for production and a stack compression system is configured to enable a variable quantity and variable area of said repeating cells in a single stack. A high-speed manufacturing system is configured to produce scalable cells and assemble scalable stacks at rates in excess of 1,000 MW-class stacks per year.