A redox ion exchange membrane may include an electrically-conductive material; and redox-active materials associated with that material, the redox-active materials having reversible oxidation and reduction properties. The redox-active materials may be inorganic nanostructures on the electrically-conductive material. A hydrogen production device and a fuel cell device may include such a redox ion exchange membrane positioned between the cathode and anode. A method of producing hydrogen gas may include providing a cathode, an anode, and a redox ion exchange membrane positioned between the cathode and the anode, and applying electrical power to the cathode and the anode; where that applying causes simultaneous reciprocal reduction and oxidation reactions on opposite sides of the redox ion exchange membrane, such that H+ is released on one side of the redox ion exchange membrane

To provide a membrane electrode assembly, a solid polymer electrolyte membrane, a water electrolysis apparatus, and an electrolytic hydrogenation apparatus, that can reduce the range of increase in electrolysis voltage even when the current density increases when applied to a water electrolysis apparatus or an electrolytic hydrogenation apparatus. The membrane electrode assembly of the present invention comprises an anode having a catalyst layer, a cathode having a catalyst layer, and a solid polymer electrolyte membrane disposed between the anode and the cathode, wherein the solid polymer electrolyte membrane comprises a fluorinated polymer having ion-exchange groups and a woven fabric, wherein the aperture ratio of the woven fabric is at least 50%, and the ratio TA.sub.AVE/TB.sub.AVE calculated from the average maximum membrane thickness TA.sub.AVE and the average minimum membrane thickness TB.sub.AVE of the solid polymer electrolyte membrane is at least 1.20.

To provide a membrane electrode assembly, a solid polymer electrolyte membrane, a water electrolysis apparatus, and an electrolytic hydrogenation apparatus, that can reduce the range of increase in electrolysis voltage even when the current density increases when applied to a water electrolysis apparatus or an electrolytic hydrogenation apparatus. The membrane electrode assembly of the present invention comprises an anode having a catalyst layer, a cathode having a catalyst layer, and a solid polymer electrolyte membrane disposed between the anode and the cathode, wherein the solid polymer electrolyte membrane comprises a fluorinated polymer having ion-exchange groups and a woven fabric, wherein the aperture ratio of the woven fabric is at least 50%, and the ratio TA.sub.AVE/TB.sub.AVE calculated from the average maximum membrane thickness TA.sub.AVE and the average minimum membrane thickness TB.sub.AVE of the solid polymer electrolyte membrane is at least 1.20.

A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a CO.sub.x reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.

A platform technology that uses a novel membrane electrode assembly, including a cathode layer, an anode layer, a membrane layer arranged between the cathode layer and the anode layer, the membrane conductively connecting the cathode layer and the anode layer, in a CO.sub.x reduction reactor has been developed. The reactor can be used to synthesize a broad range of carbon-based compounds from carbon dioxide and other gases containing carbon.

Provided herein are membrane electrode assemblies (MEAs) for CO.sub.x reduction. According to various embodiments, the MEAs are configured to address challenges particular to CO.sub.x including managing water in the MEA. Bipolar and anion-exchange membrane (AEM)-only MEAs are described along with components thereof and related methods of fabrication.

Provided herein are membrane electrode assemblies (MEAs) for CO.sub.x reduction. According to various embodiments, the MEAs are configured to address challenges particular to CO.sub.x including managing water in the MEA. Bipolar and anion-exchange membrane (AEM)-only MEAs are described along with components thereof and related methods of fabrication.

Methods, apparatuses, and systems related to the electrochemical separation of target gases from gas mixtures are provided. In some cases, a target gas such as carbon dioxide is captured and optionally released using an electrochemical cell (e.g., by bonding to an electroactive species in a reduced state). Some embodiments are particularly useful for selectively capturing the target gas while reacting with little to no oxygen gas that may be present in the gas mixture. Some such embodiments may be useful in applications involving separations from gas mixtures having relatively low concentrations of the target gas, such as direct air capture and ventilated air treatment.

A pressure releasing method in a water electrolysis system including a water electrolyzer, the pressure releasing method includes operating the water electrolyzer to electrolyze water to produce oxygen with a first pressure on an anode side and hydrogen with a second pressure higher than the first pressure on the cathode side. It is determined whether the water electrolyzer is in a frozen environment when the water electrolysis system stops operating. The cathode side is depressurized without suppling a depressurizing current to the water electrolyzer if it is determined that the water electrolyzer is in the frozen environment, or with suppling the depressurizing current to the water electrolyzer if it is determined that the water electrolyzer is not in the frozen environment.

A pressure releasing method in a water electrolysis system including a water electrolyzer, the pressure releasing method includes operating the water electrolyzer to electrolyze water to produce oxygen with a first pressure on an anode side and hydrogen with a second pressure higher than the first pressure on the cathode side. It is determined whether the water electrolyzer is in a frozen environment when the water electrolysis system stops operating. The cathode side is depressurized without suppling a depressurizing current to the water electrolyzer if it is determined that the water electrolyzer is in the frozen environment, or with suppling the depressurizing current to the water electrolyzer if it is determined that the water electrolyzer is not in the frozen environment.