A holistic system for sustained capture, confinement and depuration of acid mist generated in nonferrous metal electrodeposition processes utilizing lead anodes, for precluding zero release of gaseous fluid pollutants in the atmospheric air surrounding electrodeposition processes, providing an assured solution to acid mist control and total abatement in an effective, efficient manner and sustainable in time by immediate recovery and recycling back in the source generating the contaminant effluents as there are produced, according to a cell by cell strategy, and directly connecting each cell to a system for depuration, recovery and recycling the contaminants gaseous fluid flow extracted from each cell reducing them to innocuous levels in the discharge to the open atmosphere; complying the condition of 100% Null escape of acid mist from each individual cell to the working environment, simultaneously with minimum power usage, and substantial global gaseous fluid contaminant reduction, far exceeding present minimum sustainability standards, in terms of human health, energy usage and environmental protection.

This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

A method of recovering metal values from metal-bearing materials such as slags and drosses includes the steps of pulverizing the material to particles less than about 100 m; leaching the pulverized material with a solution of ammonium chloride, sodium chloride, and potassium chloride; sequentially recovering at least two metals from the leachate by the addition of zinc using a sequential cementation process; and recovering zinc from the solution by electrowinning.

A method of recovering metal values from metal-bearing materials such as slags and drosses includes the steps of pulverizing the material to particles less than about 100 m; leaching the pulverized material with a solution of ammonium chloride, sodium chloride, and potassium chloride; sequentially recovering at least two metals from the leachate by the addition of zinc using a sequential cementation process; and recovering zinc from the solution by electrowinning.

The invention discloses a treatment method of a chlorine-containing zinc oxide secondary material, which comprises the following steps: 1) leaching the chlorine-containing zinc oxide secondary material I through an acid solution; 2) selectively extracting zinc through di-(2-ethylhexyl)phosphoric acid (P204)-kerosene solvent; 3) implementing stripping-electrolysis zinc recovery; 4) repeating steps 1)-4); 5) taking out the raffinate obtained from the Step (4), mixing the residual taken out raffinate with chlorine-containing zinc oxide secondary material II when balance on chlorine ion input and taking out is achieved; carrying out liquid-solid separation; leaching the separated deposit through acid raffinate of the step 1); 6) after separated solution achieves preset conditions, purifying the chlorine-containing aqueous phase; 7) evaporating and concentrating to crystallize out KCl and NaCl products. The invention is environment-friendly and energy-saving, and free from process wastewater emission; production cost is greatly reduced and secondary pollution of the current dechloridation process is eliminated thoroughly.

The invention discloses a treatment method of a chlorine-containing zinc oxide secondary material, which comprises the following steps: 1) leaching the chlorine-containing zinc oxide secondary material I through an acid solution; 2) selectively extracting zinc through di-(2-ethylhexyl)phosphoric acid (P204)-kerosene solvent; 3) implementing stripping-electrolysis zinc recovery; 4) repeating steps 1)-4); 5) taking out the raffinate obtained from the Step (4), mixing the residual taken out raffinate with chlorine-containing zinc oxide secondary material II when balance on chlorine ion input and taking out is achieved; carrying out liquid-solid separation; leaching the separated deposit through acid raffinate of the step 1); 6) after separated solution achieves preset conditions, purifying the chlorine-containing aqueous phase; 7) evaporating and concentrating to crystallize out KCl and NaCl products. The invention is environment-friendly and energy-saving, and free from process wastewater emission; production cost is greatly reduced and secondary pollution of the current dechloridation process is eliminated thoroughly.

The present disclosure provides a method for removing chlorine from a process solution in zinc hydrometallurgy, the method comprising: a step for preparing the process solution from a leaching process of leaching a zinc calcine; a step for introducing the process solution to a reactor and introducing a lead concentrate into the reactor while blowing-in oxygen; a step for solid-liquid separating of a slurry in a filtration tank, the slurry being produced in the reactor; and a step for post-processing a filtrate and a lead concentrate residue separated in the step for solid-liquid separating, wherein chlorine ions in the process solution and silver contained in the lead concentrate react with each other in the reactor to precipitate a silver chloride.

The present disclosure provides a method for removing chlorine from a process solution in zinc hydrometallurgy, the method comprising: a step for preparing the process solution from a leaching process of leaching a zinc calcine; a step for introducing the process solution to a reactor and introducing a lead concentrate into the reactor while blowing-in oxygen; a step for solid-liquid separating of a slurry in a filtration tank, the slurry being produced in the reactor; and a step for post-processing a filtrate and a lead concentrate residue separated in the step for solid-liquid separating, wherein chlorine ions in the process solution and silver contained in the lead concentrate react with each other in the reactor to precipitate a silver chloride.

The present disclosure relates to a method for removing halide from halide-containing Waelz oxide. According to the method, it is possible to effectively remove halide contained in Waelz oxide, especially insoluble fluoride such as CaF.sub.2, which are difficult to remove under atmospheric pressure conditions and present as insoluble substances. Accordingly, in the process of recovering valuable metals, an additional process for adjusting the concentration of fluorine or chlorine present in the electrolyte can be omitted, and costs can be reduced.

The present disclosure relates to a method for removing halide from halide-containing Waelz oxide. According to the method, it is possible to effectively remove halide contained in Waelz oxide, especially insoluble fluoride such as CaF.sub.2, which are difficult to remove under atmospheric pressure conditions and present as insoluble substances. Accordingly, in the process of recovering valuable metals, an additional process for adjusting the concentration of fluorine or chlorine present in the electrolyte can be omitted, and costs can be reduced.