Spent nuclear fuel is added to an electro-reduction cell, wherein the electro-reduction cell includes a halide salt electrolyte, and anode, and a cathode including an alloy of uranium and a first metal forming a low melting point alloy with uranium, the first metal being one or more of: iron; chromium; nickel; manganese; and cobalt. The spent nuclear fuel is electrochemically reduced at a potential sufficient to reduce plutonium and lanthanides in the spent nuclear fuel, to form a molten alloy of the first metal, uranium and higher actinides present in the spent nuclear fuel. The alloy is extracted from the electro-reduction cell while uranium oxide is present in the electro-reduction cell. The spent nuclear fuel includes uranium oxide and at least 1 mol of lanthanides per tonne of uranium in the spent nuclear fuel, and the electro-reduction cell is operated at a temperature above the melting point of the alloy.

Spent nuclear fuel is added to an electro-reduction cell, wherein the electro-reduction cell includes a halide salt electrolyte, and anode, and a cathode including an alloy of uranium and a first metal forming a low melting point alloy with uranium, the first metal being one or more of: iron; chromium; nickel; manganese; and cobalt. The spent nuclear fuel is electrochemically reduced at a potential sufficient to reduce plutonium and lanthanides in the spent nuclear fuel, to form a molten alloy of the first metal, uranium and higher actinides present in the spent nuclear fuel. The alloy is extracted from the electro-reduction cell while uranium oxide is present in the electro-reduction cell. The spent nuclear fuel includes uranium oxide and at least 1 mol of lanthanides per tonne of uranium in the spent nuclear fuel, and the electro-reduction cell is operated at a temperature above the melting point of the alloy.

There is provided a method of electrochemically reducing multiple metal oxide pellets simultaneously, the method comprising: contacting an anode and a cathode with multiple metal oxide pellets with an electrolyte, wherein the multiple metal oxide pellets are secured to the cathode; and applying an electrical potential between the anode and the cathode to reduce multiple metal oxides comprised in the multiple metal oxide pellets to its respective metals. There is also provided an electrochemical cell for electrochemically reducing multiple metal oxide pellets simultaneously.

There is provided a method of electrochemically reducing multiple metal oxide pellets simultaneously, the method comprising: contacting an anode and a cathode with multiple metal oxide pellets with an electrolyte, wherein the multiple metal oxide pellets are secured to the cathode; and applying an electrical potential between the anode and the cathode to reduce multiple metal oxides comprised in the multiple metal oxide pellets to its respective metals. There is also provided an electrochemical cell for electrochemically reducing multiple metal oxide pellets simultaneously.

A preparation method of gradient high-silicon steel by molten salt electrolysis includes: weighing the inorganic fluoride salt and the inorganic silicon salt, mixing them uniformly and then drying; heating the electrolysis container over the melting point of the electrolyte, passing the inert gas through the electrolysis container, and connecting the electrode to the power supply to perform constant current electrolysis, after the electrolysis is finished, the cathode is taken out, washed and dried, placing the dried cathode in a constant temperature region of an annealing furnace; under a protective gas atmosphere, heating the cathode to the target temperature, and maintaining the temperature for a period of time; after the heat treatment, cooling the cathode to the room temperature, during which the cathode is always placed in the furnace.

A preparation method of gradient high-silicon steel by molten salt electrolysis includes: weighing the inorganic fluoride salt and the inorganic silicon salt, mixing them uniformly and then drying; heating the electrolysis container over the melting point of the electrolyte, passing the inert gas through the electrolysis container, and connecting the electrode to the power supply to perform constant current electrolysis, after the electrolysis is finished, the cathode is taken out, washed and dried, placing the dried cathode in a constant temperature region of an annealing furnace; under a protective gas atmosphere, heating the cathode to the target temperature, and maintaining the temperature for a period of time; after the heat treatment, cooling the cathode to the room temperature, during which the cathode is always placed in the furnace.

The present invention belongs to the field of titanium metallurgy, and particularly relates to a method for preparing a titanium-aluminum alloy. The technical problem to be solved by the present invention is to provide a method for preparing a titanium-aluminum alloy, including the following steps: a. adding TiCl.sub.4 and AlCl.sub.3 to a molten electrolyte in a protective atmosphere, wherein the molten electrolyte is a mixture of at least one of alkali metal chloride or alkaline earth metal chloride and alkali metal fluoride; b. electrolyzing the mixture obtained in step a; and c. obtaining a titanium-aluminum alloy through vacuum distillation of a cathode product after electrolysis. The method of the present invention can shorten the preparation process of a titanium-aluminum alloy and reduce the manufacturing cost thereof, which is of great significance to the development of titanium alloy in practice.

Method and apparatus are provided for efficient metal distillation, and for related primary product process. Vertically stacked and gravity-driven evaporators and condensers are employed to distill metals, such metals having different volatilities. A multiple-effect thermal system of magnesium and other volatile metals is used to efficiently distill and separate metals from multiple metal alloys.

A method of direct oxide reduction includes forming a molten salt electrolyte in an electrochemical cell, disposing at least one metal oxide in the electrochemical cell, disposing a counter electrode comprising a material selected from the group consisting of osmium, ruthenium, rhodium, iridium, palladium, platinum, silver, gold, lithium iridate, lithium ruthenate, a lithium rhodate, a lithium tin oxygen compound, a lithium manganese compound, strontium ruthenium ternary compounds, calcium iridate, strontium iridate, calcium platinate, strontium platinate, magnesium ruthenate, magnesium iridate, sodium ruthenate, sodium iridate, potassium iridate, and potassium ruthenate in the electrochemical cell, and applying a current between the counter electrode and the at least one metal oxide to reduce the at least one metal oxide. Related methods of direct oxide reduction and related electrochemical cells are also disclosed.

A method of direct oxide reduction includes forming a molten salt electrolyte in an electrochemical cell, disposing at least one metal oxide in the electrochemical cell, disposing a counter electrode comprising a material selected from the group consisting of osmium, ruthenium, rhodium, iridium, palladium, platinum, silver, gold, lithium iridate, lithium ruthenate, a lithium rhodate, a lithium tin oxygen compound, a lithium manganese compound, strontium ruthenium ternary compounds, calcium iridate, strontium iridate, calcium platinate, strontium platinate, magnesium ruthenate, magnesium iridate, sodium ruthenate, sodium iridate, potassium iridate, and potassium ruthenate in the electrochemical cell, and applying a current between the counter electrode and the at least one metal oxide to reduce the at least one metal oxide. Related methods of direct oxide reduction and related electrochemical cells are also disclosed.