Devices and methods for purifying lithium from lithium salts, including those with low concentration of lithium salts, are provided. A molten composition comprising a lithium salt is electrolyzed with an anode in contact with the molten composition and a cathode separated from the molten composition by a solid electrolyte capable of conducting lithium ions.

Electrochemical cells and methods are described that can be utilized for the recovery of tritium directly from a molten lithium metal solution without the need for a separation or concentration step prior to the electrolytic recovery process. The methods and systems utilize an ion conducting electrolyte that conducts either lithium ion or tritide ion across the electrochemical cell.

The application is directed towards methods for purifying an aluminum feedstock material. A method provides: (a) feeding an aluminum feedstock into a cell (b) directing an electric current into an anode through an electrolyte and into a cathode, wherein the anode comprises an elongate vertical anode, and wherein the cathode comprises an elongate vertical cathode, wherein the anode and cathode are configured to extend into the electrolyte zone, such that within the electrolyte zone the anode and cathode are configured with an anode-cathode overlap and an anode-cathode distance; and producing some purified aluminum product from the aluminum feedstock.

Lead from lead acid battery scrap is recovered in two separate production streams as clean grid lead and as high-purity lead without smelting. In preferred aspects, lead recovery is performed in a continuous process that uses an aqueous electroprocessing solvent and electro-refining. Spent electroprocessing solvent and/or base utilized to treat lead paste from the lead acid battery scrap can be recycled to the recovery process.

A system for extracting oxygen from powdered metal oxides, the system comprising a container comprising an electrolyte in the form of meltable or molten salt, at least one cathode, at least one anode, a power supply, and a conducting structure, wherein the cathode is shaped as a receptacle having a porous shell, which has an upper opening, the cathode being arranged in the electrolyte with the opening protruding over the electrolyte, wherein the conducting structure comprises a plurality of conducting elements and gaps between the conducting elements, wherein the power supply is connectable to the at least one cathode and the at least one anode to selectively apply an electric potential across the cathode and the anode, wherein the conducting structure is insertable into the cathode, such that the conducting elements reach into an inner space of the cathode, wherein the conducting structure is electrically connectable to the cathode, and wherein the system is adapted for reducing at least one respective metallic species of at least one metal oxide of feedstock inside the shell of the cathode with inserted conducting structure by applying the electric potential, wherein the potential is greater than the dissociation potential of the at least one metal oxide.

Systems and processes for the production of lithium metal from molten salts. Systems can include a ceramic tube affixed by or to a freeze-composite. The freeze-composite includes a matrix, of a salt and a dispersed phase. The freeze is maintained with a cooling collar to maintain a temperature below the melting point of the salt. Systems can include a molten-catholyte and a molten-anolyte each adjacent to separate surfaces of the ceramic tube. The freeze-composite forms a fluidic and non-conductive barrier between the molten-catholyte and the molten-anolyte. Processes include a freeze-composite affixed to the ceramic tube. The ceramic tube is adjacent to a composite collar which is adjacent to a cooling collar; The cooling fluid is passed through the cooling collar. A molten-catholyte is passed along a first surface of the ceramic tube. A molten-anolyte is passed along to a second surface of the ceramic tube.

Systems and processes for the production of lithium metal from molten salts. Systems can include a ceramic tube affixed by or to a freeze-composite. The freeze-composite includes a matrix, of a salt and a dispersed phase. The freeze is maintained with a cooling collar to maintain a temperature below the melting point of the salt. Systems can include a molten-catholyte and a molten-anolyte each adjacent to separate surfaces of the ceramic tube. The freeze-composite forms a fluidic and non-conductive barrier between the molten-catholyte and the molten-anolyte. Processes include a freeze-composite affixed to the ceramic tube. The ceramic tube is adjacent to a composite collar which is adjacent to a cooling collar; The cooling fluid is passed through the cooling collar. A molten-catholyte is passed along a first surface of the ceramic tube. A molten-anolyte is passed along to a second surface of the ceramic tube.

A reduced iron production method using an electrowinning method and reduced iron is provided. The method includes, preparing a mixture by mixing, a solid electrolyte containing sodium peroxide (Na.sub.2O.sub.2) and boron oxide (B.sub.2O.sub.3), with iron oxide (Fe.sub.2O.sub.3); and putting the mixture in an electrowinning device provided with an anode and an insoluble cathode and heating to form a molten oxide and then applying a voltage to the anode and the cathode to form iron on the cathode.

Therefore, by reducing iron oxide through an electrowinning method, a reduced iron in a pure iron state can be obtained. Although it is very difficult to obtain pure iron by refining an iron ore, by using the electrowinning method in which the composition of an electrolyte is controlled and electrolysis conditions are controlled, reduced iron that is pure can be obtained.

The application is directed towards systems and methods for aluminum purification. A system, comprising: a cell defining a chamber having upper portion and lower portion; the lower portion including a cathode molten material collection area; an anode structure disposed in the upper portion vertically aligned above the lower portion; a cathode structure disposed in the upper portion vertically aligned above the cathode molten material collection area; and a liquid electrolyte within the chamber in fluid communication with the anode structure and the cathode structure, the liquid electrolyte having electrolyte density; the anode structure is configured to receive impure aluminum having impure aluminum density greater than the electrolyte density, and the cathode structure captures purified aluminum having purified aluminum density greater than the electrolyte density, the cathode structure defining a cathode flow path along which purified aluminum can flow.

This aluminum smelter comprises a row of cells (50) arranged transversely in relation to the length of the row, the cells (50) individually comprising an anode (52), rising and connecting electrical conductors (54) running upwards along the two opposite longitudinal edges of the cell (50) to route the electrolysis current towards the anode (52), and a cathode (56) through which pass cathode conductors (55) connected to cathode outputs connected to linking conductors to route the electrolysis current to the rising and connecting electrical conductors of the next cell (50). Furthermore the aluminum smelter comprises a compensating electrical circuit separate from the electrical circuit through which the electrolysis current flows, running beneath the cells (50), through which a compensating current may flow beneath the cells (50) in a direction opposite to the overall direction of flow of the electrolysis current.