A method for improving mechanical properties by changing a gradient nanotwinned structure of metallic materials is the technical field of nanostructured metallic materials. The method uses the inherent principles of microstructure and mechanical properties of metallic materials to improve materials mechanical properties. The metallic materials has a gradient nanotwinned structure. The principles of microstructure and mechanical properties of the metallic materials mean that the mechanical properties of the metallic materials are adjusted by changing the structural gradient scale of the nanotwinned structure. The method combines two strengthening methods of nanotwins and gradient structure, and can obviously improve the mechanical properties of the metallic materials. For pure copper materials of the gradient nanotwinned structure prepared by an electrodeposition technology: the yield strength is 481±15 MPa, the tensile strength is 520±12 MPa, the uniform elongation can be 7±0.5%, and the elongation to failure can be 11.7±1.3%.

A method for improving mechanical properties by changing a gradient nanotwinned structure of metallic materials is the technical field of nanostructured metallic materials. The method uses the inherent principles of microstructure and mechanical properties of metallic materials to improve materials mechanical properties. The metallic materials has a gradient nanotwinned structure. The principles of microstructure and mechanical properties of the metallic materials mean that the mechanical properties of the metallic materials are adjusted by changing the structural gradient scale of the nanotwinned structure. The method combines two strengthening methods of nanotwins and gradient structure, and can obviously improve the mechanical properties of the metallic materials. For pure copper materials of the gradient nanotwinned structure prepared by an electrodeposition technology: the yield strength is 481±15 MPa, the tensile strength is 520±12 MPa, the uniform elongation can be 7±0.5%, and the elongation to failure can be 11.7±1.3%.

A method of producing manganese metal or EMD by leaching a source of manganese with a solution comprising sulfuric acid to form a leach solution, adding one or more sulfides generated in a sulfide recycle stage to the leach solution in order to form sulfide precipitates comprising heavy metal sulfides, removing the sulfide precipitates from the leach solution, feeding the leach solution to one or more electrolytic cells, subjecting the purified leach solution to electrolysis so as to deposit manganese metal or EMD, reacting the sulfide precipitates with an acid to generate H.sub.2S, producing one or more sulfides from the H.sub.2S for recycle. Methods of producing manganese metal and a purified manganese sulfate solution are also provided.

A method of producing manganese metal or EMD by leaching a source of manganese with a solution comprising sulfuric acid to form a leach solution, adding one or more sulfides generated in a sulfide recycle stage to the leach solution in order to form sulfide precipitates comprising heavy metal sulfides, removing the sulfide precipitates from the leach solution, feeding the leach solution to one or more electrolytic cells, subjecting the purified leach solution to electrolysis so as to deposit manganese metal or EMD, reacting the sulfide precipitates with an acid to generate H.sub.2S, producing one or more sulfides from the H.sub.2S for recycle. Methods of producing manganese metal and a purified manganese sulfate solution are also provided.

An electrolysis apparatus for the electrolytic production of oxygen from oxide-containing starting material includes at least one cathode which at least partly delimits a receiving region which in at least one operation state is configured for receiving the oxide-containing starting material and at least one anode,

wherein the electrolysis apparatus has at least one selective oxygen pump which is at least partly realized integrally with the anode.

A system for measuring a cathode current includes a conducting bar and a current measuring device. The conducting bar has a rectangular plate-like structure, and a first end of the conducting bar is vertically cut to form a plurality of long teeth. The plurality of long teeth are equally spaced at the first end of the conducting bar. The number of the plurality of long teeth is equal to the number of cathodes. The upper surface of each of the long teeth may include a raised conductive contact. Each of the conductive contacts is connected with one cathode of an upstream slot. A second end of the conducting bar is connected with a downstream slot, and the second end of the conducting bar is one end opposite to the first end. The current measuring device is disposed on the conducting bar and used for measuring the current of each cathode.

The invention relates to an electrochemical reactor for continuous copper electrodeposition at high current densities with copper sulfate electrolytes, which comprises devices and systems of functional means that are linked and operated in line, thereby forming a triad, for standardising operational conditions in a series of operative parallel reactors. The triad, installed in each existing or new electrolytic container, comprises: a gentle electrolyte agitation system (AGSEL) with means for pulsing control of the aeration volume diffused by bubbling directed into each inter-cathodic space; a duo of systems linked in line, which comprises a system of removable anode covers (CAR) for containing, confining and coalescing the acid mist; and an acid mist recycling system (SIRENA) that captures non-coalesced electrolyte aerosols and condenses the steam, returning same to the process, while the pollutants of the gaseous fluid from the reactor are substantially diluted.

The invention relates to an electrochemical reactor for continuous copper electrodeposition at high current densities with copper sulfate electrolytes, which comprises devices and systems of functional means that are linked and operated in line, thereby forming a triad, for standardising operational conditions in a series of operative parallel reactors. The triad, installed in each existing or new electrolytic container, comprises: a gentle electrolyte agitation system (AGSEL) with means for pulsing control of the aeration volume diffused by bubbling directed into each inter-cathodic space; a duo of systems linked in line, which comprises a system of removable anode covers (CAR) for containing, confining and coalescing the acid mist; and an acid mist recycling system (SIRENA) that captures non-coalesced electrolyte aerosols and condenses the steam, returning same to the process, while the pollutants of the gaseous fluid from the reactor are substantially diluted.

A liftable electrolytic vessel including at least one anchor assembly being at least partially embedded in each of two opposed core walls to provide anchorage to a lifting accessory of a lifting device; and related method for lifting the electrolytic vessel. Each anchor assembly comprises an anchor having a strap slot, and a strap connected to the anchor and extending from the anchor along and inside at least a portion of the corresponding core wall. The anchor further includes a connector which is sized and configured to receive a fastener or engage a lifting accessory such as a chain or a hook. The anchor assembly may include one anchor provided at each end of the strap. A plurality of anchor assemblies may extend vertically and horizontally within a core of the vessel to offer various anchorage points from an outer surface of the core. Design of the anchor of a first anchor assembly may differ from the design of a second anchor assembly. A lifting accessory is further designed to be securable to each anchor of the vessel.

A liftable electrolytic vessel including at least one anchor assembly being at least partially embedded in each of two opposed core walls to provide anchorage to a lifting accessory of a lifting device; and related method for lifting the electrolytic vessel. Each anchor assembly comprises an anchor having a strap slot, and a strap connected to the anchor and extending from the anchor along and inside at least a portion of the corresponding core wall. The anchor further includes a connector which is sized and configured to receive a fastener or engage a lifting accessory such as a chain or a hook. The anchor assembly may include one anchor provided at each end of the strap. A plurality of anchor assemblies may extend vertically and horizontally within a core of the vessel to offer various anchorage points from an outer surface of the core. Design of the anchor of a first anchor assembly may differ from the design of a second anchor assembly. A lifting accessory is further designed to be securable to each anchor of the vessel.