A method for manufacturing metal horological components, includes the steps of forming a multilevel mould made of a photosensitive resin, with a UV-LIGA method, and galvanically depositing a layer of at least one metal starting from a conductive layer in order to form a block that substantially reaches the upper surface of the photosensitive resin.

Silver-nickel alloy electroplating compositions and methods enable electroplating silver rich silver-nickel deposits which are bright, uniform and have a relatively low coefficient of friction. The binary silver-nickel alloy is deposited from an aqueous acid silver-nickel alloy electroplating composition. The aqueous acid silver-nickel alloy electroplating composition includes thiol compounds which shift the reduction potential of silver ions toward the reduction potential of nickel ions such that a silver rich binary silver-nickel layer is deposited on a substrate.

The invention relates to an aqueous electroplating solution for alkaline electroplating, comprising: [M(NH3)4]2+ ions, wherein M is selected from the group consisting of Pd or Pt; and organic anions selected from the group consisting of bicarbonate, carbonate, or a mixture thereof; wherein the following species, if present, are present in the following amounts: alkali metals in an amount of less than 5 g/L; compounds comprising phosphorus in an amount of less than 5 g/L; compounds comprising boron in an amount of less than 5 g/L. The invention also relates to an electroplating bath comprising the electroplating solution, and a method of forming a metal layer on a substrate by electroplating using the electroplating solution.

A method for producing metal decorations on a curved dial made of insulating material includes forming, by a method of the LIGA-UV type, a mould made of photosensitive resin and of galvanically depositing a layer of at least one metal from the conductive layer in order to form a block substantially reaching the upper surface of the photosensitive resin

A method for assembling a stone on a setting support, the stone being cut to exhibit a table, a crown, a girdle and a pavilion, including the steps of: providing a substrate coated with a pattern including an electrically conductive layer covered with a resin layer, the pattern having an inner contour delimiting a hole through the coated substrate and an outer contour corresponding to the outer contour of the desired setting support; removing the resin layer; after dissolution of the resin layer, positioning the stone in the through hole, the stone resting on the electrically conductive layer; and electrodepositing a metal layer on the electrically conductive layer to form the setting support, in order to make the stone integral with the metal layer.

A method is for manufacturing a part including a support made of an electrically non-conductive material, the support being provided with at least one recess filled with an aesthetic element made of an electrically conductive material, and the aesthetic element forms a decoration on a side of the part that is intended to be visible. The method includes inlaying by pressing a preform intended to form the aesthetic element into the at least one recess of the support, and treating the surface of the aesthetic element. The at least one recess opens in one or more places onto a side of the part that is intended to be non-visible, to respectively form one or more contact points for carrying current across the aesthetic element during the surface treatment.

An object of the present invention is to provide an electroformed part favorable for an assembly part of a timepiece or the like and a timepiece using the same. The present invention relates to an electroformed part, which is an electroformed part composed of a nickel-iron alloy constituted by nickel, iron, and unavoidable impurities, containing iron at 5 to 25% by mass, and having a roughly layered form portion in which a stacked form portion having an inclined iron content in a thickness direction is repeatedly stacked a plurality of times. It is preferred that the stacked portion is constituted by crystal grains having an average grain diameter of 50 nm or less.

Superconformally filling a recessed feature includes: contacting the recessed feature with superconformal filling composition that includes: Au(SO.sub.3).sub.2.sup.3 anions; SO.sub.3.sup.2 anions; and Bi.sup.3+ cations; convectively transporting Au(SO.sub.3).sub.2.sup.3 and Bi.sup.3+ to the bottom member of the recessed feature; subjecting the recessed feature to an electrical current to superconformally deposit gold from the Au(SO.sub.3).sub.2.sup.3 on the bottom member relative to the sidewall and the field, the electrical current providing a cathodic voltage; and increasing the electrical current subjected to the field and the recessed feature to maintain the cathodic voltage between 0.85 V and 1.00 V relative to the SSE during superconformally depositing gold on the substrate to superconformally fill the recessed feature of the article with gold as a superconformal filling of gold, the superconformal filling being void-free and seam-free.

A counterfeiting deterrent device according to one implementation of the disclosure includes a plurality of layers formed by an additive process. Each of the layers may have a thickness of less than 100 microns. At least one of the layers has a series of indentations formed in an outer edge of the layer such that the indentations can be observed to verify that the device originated from a predetermined source. According to another implementation, a counterfeiting deterrent device includes at least one raised layer having outer edges in the shape of a logo. A light source is configured and arranged to shine a light through a slit in a substrate layer of the device and past an intermediate layer to light up the outer edge of the raised layer. The layers of the device are formed by an additive process and have a thickness of less than 100 microns each.

A method for assembling a stone on a setting support, the stone being cut to exhibit a table, a crown, a girdle and a pavilion. A substrate with a recess for the stone, the recess forming, between the substrate and the stone, a peripheral free space in the vicinity of the girdle and of the zones of the crown and of the pavilion contiguous to the girdle, the peripheral free space including a bottom having a conductive surface. Electroplating, in the peripheral free space, a metal layer in the vicinity of the girdle and of the zones of the crown and of the pavilion contiguous to the girdle, so as to confine the girdle in the metal layer to form, around the girdle, the setting support. The stone and its setting support are released from the substrate.