A method for manufacturing a copper composite electrode, including contacting a conductive substrate including copper with a phosphate solution for oxidation to produce a copper phosphate structure on a surface of the conductive substrate, thus acquiring a copper phosphate composite electrode.

The present invention provides a zinc coating-forming method for drawing of metallic pipes, including a degreasing step of degreasing a material to be drawn, which is composed of any one of aluminum, an aluminum alloy, copper, and a copper alloy; a first oxidation step of forming an oxide coating on a surface of the material to be drawn, which has been degreased in the degreasing step; and a second oxidation step of forming a zinc coating on the material to be drawn, which has been coated with an oxide.

Various embodiments include a sealed laminated metal structure. This laminated metal structure has a metal layer, where the metal layer has a first surface and an opposite second surface. A material is laminated on each of the first and second surfaces of the metal layer. In some cases, the laminated metal structure is removed from a larger laminated sheet of metal. The laminated metal structure is subjected to alternating current electrolytic deburring and cleaning to remove any burrs along the perimeter edge. After deburring and cleaning, a sealer, which is a phosphate compound, is deposited on the perimeter edge of the laminated metal structure where the metal is exposed using alternating current.

Various embodiments include a sealed laminated metal structure. This laminated metal structure has a metal layer, where the metal layer has a first surface and an opposite second surface. A material is laminated on each of the first and second surfaces of the metal layer. In some cases, the laminated metal structure is removed from a larger laminated sheet of metal. The laminated metal structure is subjected to alternating current electrolytic deburring and cleaning to remove any burrs along the perimeter edge. After deburring and cleaning, a sealer, which is a phosphate compound, is deposited on the perimeter edge of the laminated metal structure where the metal is exposed using alternating current.

A steel sheet for a container includes: a steel sheet; a coated layer which contains Ni and is provided as an upper layer of the steel sheet; and a chemical treatment layer which is provided as an upper layer of the coated layer, and contains a Zr compound in an amount of 3.0 to 30.0 mg/m.sup.2 in terms of Zr metal, and a Mg compound in an amount of 0.50 to 5.00 mg/m.sup.2 in terms of Mg metal, in which the coated layer is one of the group consisting of a Ni coated layer which contains Ni in amount of 10 to 1000 mg/m.sup.2 in terms of Ni metal, and a composite coated layer which contains Ni in an amount of 5 to 150 mg/m.sup.2 in terms of Ni metal and Sn in an amount of 300 to 3000 mg/m.sup.2 in terms of Sn metal, and has an island-shaped Sn coated layer formed on an FeNiSn alloy layer.

The present disclosure provides for methods of phosphidation, catalysts formed from phosphidation, and methods of producing Hz.

There is provided a surface-treated steel sheet (1) comprising: a tin-plated steel sheet (10) obtained by tin-plating a steel sheet (11); a phosphate compound layer (20) containing tin phosphate formed on the tin-plated steel sheet (10); and an aluminum-oxygen compound layer (30) formed on the phosphate compound layer (20), a main constituent of the aluminum-oxygen compound layer being an aluminum-oxygen compound.

A surface-treated steel sheet including a tin-plated steel sheet having a tin plating on a steel sheet; a tin oxide layer formed on the tin-plated steel sheet and containing tin oxide as a main component; a composite oxide layer formed on the tin oxide layer and containing phosphoric acid and aluminum as main components; and an aluminum-oxygen compound layer formed on the composite oxide layer and containing an aluminum-oxygen compound as a main component, wherein the tin oxide layer has a thickness of 8 to 20 nm.

A surface-treated steel sheet including a tin-plated steel sheet having a tin plating on a steel sheet; a tin oxide layer formed on the tin-plated steel sheet and containing tin oxide as a main component; a composite oxide layer formed on the tin oxide layer and containing phosphoric acid and aluminum as main components; and an aluminum-oxygen compound layer formed on the composite oxide layer and containing an aluminum-oxygen compound as a main component, wherein the tin oxide layer has a thickness of 8 to 20 nm.

A surface-treated steel sheet for a container, comprising: a steel sheet, and a Zr compound film disposed on the steel sheet, wherein the Zr compound film being formed by a dipping or electrolytic treatment in a solution containing Zr ion, F ion, ammonium ion and nitrate ion; and the coating weight of the Zr compound film is 1 to 100 mg/m.sup.2 in terms of the amount of metallic Zr, and 0.1 mg/m.sup.2 or less in terms of the F amount. There is provided a steel sheet for container, which has an excellent processability in the can manufacturing, and at the same time, is excellent in drawing and ironing processability, weldability, corrosion resistance, adherence thereof to a coating material and adherence thereof to a film, and a process for producing such a steel sheet for container.