Processes for depositing functionalized nanoparticles upon a non-conductive substrate are disclosed herein. The processes may include the step of aerosolizing one or more particles into suspension within a gas, each of the one or more particles comprising functionalized nanoparticles having an electric charge. The processes may include the step the step of attracting the one or more particles onto a non-conductive substrate by a static electric charge opposite of the electric charge, wherein at least portions of the non-conductive substrate are having the static electric charge. The processes may include the step of depositing the functionalized nanoparticles onto the non-conductive substrate

Processes for depositing functionalized nanoparticles upon a non-conductive substrate are disclosed herein. The processes may include the step of aerosolizing one or more particles into suspension within a gas, each of the one or more particles comprising functionalized nanoparticles having an electric charge. The processes may include the step the step of attracting the one or more particles onto a non-conductive substrate by a static electric charge opposite of the electric charge, wherein at least portions of the non-conductive substrate are having the static electric charge. The processes may include the step of depositing the functionalized nanoparticles onto the non-conductive substrate

The present invention provides a method for concurrent electrophoretic deposition (EPD) of a membrane-electrode assembly (MEA) comprising a first MEA electrode and a second MEA electrode. The method comprises electrophoretically depositing the first MEA electrode from a suspension comprising a first precursor on a first surface of an ion permeable membrane and electrophoretically depositing the second MEA electrode from a second suspension comprising a second precursor on a second surface of the ion permeable membrane, wherein the first precursor is physically separated from and ionically connected to the second precursor by the membrane.

A method for manufacturing a dense layer that includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; and densifying the dried layer by mechanical compression and/or heat treatment. The method is characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution having a value of D50. The distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by the value D50 being at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.

A method for manufacturing a dense layer that includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; and densifying the dried layer by mechanical compression and/or heat treatment. The method is characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution having a value of D50. The distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by the value D50 being at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.

The present invention is directed to electrodepositable compositions comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising: (i) lithium-containing particles, and (ii) electrically conductive particles, wherein the composition has a weight ratio of the solid particles to the ionic resin of at least 17:1, and wherein the weight ratio of the lithium-containing particles to the electrically conductive particles is at least 3:1. The present invention is additionally directed to a battery electrode comprising a substrate and a coating applied to a surface of the substrate. The coating is deposited from the electrodepositable composition described above.

The present invention is directed to electrodepositable compositions comprising: (a) an aqueous medium; (b) an ionic resin; and (c) solid particles comprising: (i) lithium-containing particles, and (ii) electrically conductive particles, wherein the composition has a weight ratio of the solid particles to the ionic resin of at least 17:1, and wherein the weight ratio of the lithium-containing particles to the electrically conductive particles is at least 3:1. The present invention is additionally directed to a battery electrode comprising a substrate and a coating applied to a surface of the substrate. The coating is deposited from the electrodepositable composition described above.

Graphene electrodes-based supercapacitors are in demand due to superior electrochemical characteristics. However, commercial applications have been limited by inferior electrode cycle life. A method to fabricate highly efficient supercapacitor electrodes using pristine graphene sheets vertically-stacked and electrically connected to the carbon fibers which results in vertically-aligned graphene-carbon fiber nanostructure is disclosed. The vertically-aligned graphene-carbon fiber electrode prepared by electrophoretic deposition possesses a mesoporous three-dimensional architecture which enabled faster and efficient electrolyte-ion diffusion with a specific capacitance of 333.3 F g.sup.−1. The electrodes have electrochemical cycling stability of more than 100,000 cycles with 100% capacitance retention. Apart from the electrochemical double layer charge storage, the oxygen-containing surface moieties and α-Ni(OH).sub.2 present on the graphene sheets enhance the charge storage by faradaic reactions. This enables the assembled device to provide a gravimetric energy density of 76 W h kg.sup.−1 with a 100% capacitance retention even after 1,000 bending cycles.

Graphene electrodes-based supercapacitors are in demand due to superior electrochemical characteristics. However, commercial applications have been limited by inferior electrode cycle life. A method to fabricate highly efficient supercapacitor electrodes using pristine graphene sheets vertically-stacked and electrically connected to the carbon fibers which results in vertically-aligned graphene-carbon fiber nanostructure is disclosed. The vertically-aligned graphene-carbon fiber electrode prepared by electrophoretic deposition possesses a mesoporous three-dimensional architecture which enabled faster and efficient electrolyte-ion diffusion with a specific capacitance of 333.3 F g.sup.−1. The electrodes have electrochemical cycling stability of more than 100,000 cycles with 100% capacitance retention. Apart from the electrochemical double layer charge storage, the oxygen-containing surface moieties and α-Ni(OH).sub.2 present on the graphene sheets enhance the charge storage by faradaic reactions. This enables the assembled device to provide a gravimetric energy density of 76 W h kg.sup.−1 with a 100% capacitance retention even after 1,000 bending cycles.

The present invention relates to a nano-porous electrode for a super capacitor and a manufacturing method thereof, and more specifically, to a nano-porous electrode for a super capacitor and a manufacturing method thereof wherein pores are formed on the surface or inside an electrode using an electrodeposition method accompanied by hydrogen generation, thereby increasing the specific surface area of the electrode and thus improving the charging and discharging capacity, energy density, output density, and the like of a capacitor. The method for manufacturing a nano-porous electrode for a super capacitor according to the present invention manufactures a nano-porous electrode using hydrogen generated by the electrodeposition as a template to minimize the amount of metal used, so that electrode manufacturing costs can be sharply reduced, the specific surface area of the electrode can be adjusted by a simple process, and also the charging and discharging capacity, energy density, output density, and the like of a capacitor can be improved by increasing the specific surface area.