A process for producing ammonia synthesis gas from a hydrocarbon-containing feedstock in a front-end, comprising the steps of steam reforming of said feedstock, obtaining a synthesis gas comprising hydrogen, carbon monoxide and carbon dioxide; a treatment of said synthesis gas including shift of carbon monoxide and subsequent removal of carbon dioxide, wherein the shift of the synthesis gas includes high-temperature shift with an iron-based catalyst and at a temperature greater than 300? C. and the global steam-to-carbon ratio of the front end is 2.6 or less; a corresponding plant and a method for revamping a front-end of an ammonia plant are also disclosed.

A sintered refractory product having the form of a block and consisting of a granulate formed by all the grains having a size larger than 100 m, referred to as coarse grains, and a matrix binding the coarse grains and consisting of the grains having a size smaller than or equal to 100 m, the granulate representing between 45% and 90% by mass of the product, the product having a composition such that, in a mass percentage based on the oxides: Al.sub.2O.sub.3>80%, SiO.sub.2<15%, Na.sub.2O<0.15%, Fe.sub.2O.sub.3<0.05%, CaO<0.1%, the other oxides forming the remainder up to 100%, and the Na.sub.2O content in the matrix being greater than 0.010%, in a mass percentage based on the mass of the product.

A process is described for the production of formaldehyde, comprising (a) subjecting methanol to oxidation with air in a formaldehyde production unit thereby producing a formaldehyde-containing stream; (b) separating said formaldehyde-containing stream into a formaldehyde product stream and a formaldehyde vent gas stream; wherein the vent gas stream, optionally after treatment in a vent gas treatment unit, is passed to one or more stages of: (i) synthesis gas generation, (ii) carbon dioxide removal, (iii) methanol synthesis or (iv) urea synthesis.

Process for producing a chemical product, comprising subjecting hydrocarbon feed and further reforming reactant to an endothermal reaction whereby a primary reformate is formed, in a primary fired heat-recuperating reformer reaction unit, comprising a catalyst zone and a primary reformate passage way arranged to transfer heat from said reformate to said catalyst zone; optionally subjecting the primary reformate to a secondary reforming reaction, thereby forming a secondary reformate; and using primary reformate or second reformate as a heat exchange medium to supply reaction heat to an endothermal reaction, which endothermal reaction is carried out in a parallel heat-exchanger reactor.

A method of direct reduction of iron (DRI) is disclosed, the method comprising generating metallic iron by removing oxygen from iron ore using a reducing gaseous mixture with excess carbon monoxide that produces an excess CO.sub.2 by-product is provided. CO.sub.2 by-product is optionally sequestered. A system for carrying out the method is also disclosed.

A process for making recycle content ammonia by reacting hydrogen with nitrogen. At least a portion of the hydrogen is obtained directly or indirectly by molecular reforming a mixed plastic waste or pyrolysis product feedstock. The molecular reforming can be a steam reforming process or a partial oxidation process, such as a partial oxidation gasifier, to generate the syngas used as a source of hydrogen. The recycle content associated with the ammonia can be obtained from the mixed plastic waste, the recycle content in the pyrolysis product, such as pyoil or pygas, or the recycle content in the syngas or the purified hydrogen stream from the syngas.

A process and/or system for producing biomethane, hydrogen, or fuel, fuel intermediate, and/or chemical product from the biomethane or hydrogen. The biomethane and/or hydrogen is produced in a process that converts biomass to biomethane. In certain embodiments, the biomethane production process includes anaerobic digestion, which produces biogas and digestate. Carbon-containing material (e.g., derived from the biomass) is stored and/or used as part of at least one carbon capture and storage process, where the carbon-containing material includes (i) carbon dioxide produced from the biomethane production process (e.g., produced from anaerobic digestion), and (ii) carbon-containing material obtained or derived from residue of the biomethane production process, and optionally includes (iii) carbon dioxide produced from the hydrogen production process.

The invention relates to a process for separating carbon dioxide from CO.sub.2-containing gases and an apparatus for providing carbon dioxide for the synthesis of urea.

A process for producing ammonia synthesis gas from a hydrocarbon-containing feedstock, with steps of primary reforming, secondary reforming with an oxidant stream, and further treatment of the synthesis gas including shift, removal of carbon dioxide and methanation, wherein the synthesis gas delivered by secondary reforming is subject to a medium-temperature shift (MTS) at a temperature between 200 and 350 C., and primary reforming is operated with a steam-to-carbon ratio lower than 2. A corresponding method for revamping an ammonia plant is disclosed, where an existing HTS reactor is modified to operate at medium temperature, or replaced with a new MTS reactor, and the steam-to-carbon ratio in the primary reformer is lowered to a value in the range 1-52, thus reducing inert steam in the flow rate trough the equipments of the front-end.

A process is described for the production of formaldehyde, comprising (a) subjecting methanol to oxidation with air in a formaldehyde production unit thereby producing a formaldehyde-containing stream; (b) separating said formaldehyde-containing stream into a formaldehyde product stream and a formaldehyde vent gas stream; wherein the vent gas stream, optionally after treatment in a vent gas treatment unit, is passed to one or more stages of: (i) synthesis gas generation, (ii) carbon dioxide removal, (iii) methanol synthesis or (iv) urea synthesis.