Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

The system includes a methane reformer, a combined cycle power generator, and a switch. The reformer is configured to react methane with steam. The combined cycle power generator includes a steam turbine, a gas turbine, a power generator, and a water boiler. The steam turbine is configured to rotate in response to receiving steam. The gas turbine is configured to rotate in response to receiving a mixture of fuel and air. The power generator is configured to convert rotational energy from the steam turbine and the gas turbine into electricity. In a first position, the switch is configured to direct exhaust from the gas turbine to the reformer, thereby providing heat to the reformer. In a second position, the switch is configured to direct exhaust from the gas turbine to the water boiler, thereby providing heat to the water boiler to generate steam.

Methods and systems for ammonia production are provided. An exemplary method includes electrolyzing water to form H.sub.2 and O.sub.2; contacting a reformer feed stream including hydrocarbons, O.sub.2 from electrolysis, and an oxidant stream including O.sub.2 and N.sub.2 to form a reformed stream including H.sub.2, CO, CO.sub.2, and N.sub.2; contacting the reformed stream with a water-gas shift catalyst to form a shifted stream including H.sub.2, CO.sub.2, and N.sub.2; separating the shifted stream to form a captured stream including CO.sub.2 and an ammonia production feed stream including H.sub.2 and N.sub.2; and reacting the ammonia production feed stream, and optionally H.sub.2 from electrolysis, to form ammonia.

A process for the co-production of methanol and ammonia is described comprising the steps of: (a) forming a first synthesis gas stream by reacting a first portion of a hydrocarbon feedstock and steam in a steam reformer, (b) forming a second synthesis gas stream in parallel to the first synthesis gas stream by reacting a second portion of the hydrocarbon feedstock with an oxygen-containing gas and steam in an autothermal reformer, (c) synthesising methanol from a first process gas comprising the first synthesis gas stream, and (d) synthesising ammonia from a second process gas prepared from the second synthesis gas stream, wherein a purge stream containing hydrogen is recovered from the methanol synthesis step (c) and a portion of the purge gas stream is fed to the autothermal reformer and/or the second synthesis gas in step (b).

A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas engine; power produced by said gas engine; is transferred to at least one power user of the process, such as a compressor; heat is re-covered from exhaust gas of said gas engine;, and at least part of said heat may be recovered as low-grade heat available at a temperature not greater than 200° C., to provide process heating to at least one thermal user of the process, such as CO2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.

Parallel co-production process for the production of methanol and urea product from a hydrocarbon containing feed-stock by means of autothermal reforming, intermediary methanol and ammonia formation and conversion of the ammonia to urea product and catalytic oxidation of the methanol to formaldehyde.

Parallel co-production process for the production of methanol and urea product from a hydrocarbon containing feed-stock by means of primary and secondary reforming, intermediary methanol and ammonia formation and conversion of the ammonia to urea product and catalytic oxidation of methanol to formaldehyde.

A process for recovering oil and gas from an underground formation by injecting an ammonia containing enhanced oil recovery formulation into the oil-bearing formation, which process comprises (i) reacting steam with methane containing gas, (ii) combining the reaction mixture obtained with further steam, (iii) removing carbon dioxide to obtain hydrogen, (iv) reacting at least part of the hydrogen with nitrogen, (v) separating off ammonia, (vi) mixing ammonia with water and injecting it into the underground formation, (vii) recovering oil and gas, (viii) separating methane from the fluid recovered from the recovery well, (ix) removing sulfur compounds, and (ix) using in step (i) the methane obtained in step (viii).

A syngas loop boiler includes a casing that surrounds a tube bundle, wherein the tube bundle includes a plurality of tubes. One end of each of the tubes is joined to a tube-sheet provided with corresponding tube-sheet inlet holes for inletting the syngas in the boiler, wherein each tube-sheet inlet hole is internally provided with at least a protective sleeve welded at both ends to corresponding surfaces of the tube-sheet inlet hole. Each tube-sheet inlet hole is provided with a first respective weld overlay placed at the inlet mouth of the tube-sheet inlet hole, so that a first end of each protective sleeve is welded to the first weld overlay. Each tube-sheet inlet hole is internally provided with at least a bore groove that contains a respective in-bore second weld overlay, so that the second end of the protective sleeve is welded to the in-bore second weld overlay. Each protective sleeve is thus welded at both ends to respective weld overlays, with the possibility of removal and re-installation without performing any post weld heat treatment.

A process for the production of ammonia and urea in an ammonia-urea integrated plant comprising an ammonia section and a tied-in urea section, wherein a hydrocarbon is reformed to produce ammonia make-up synthesis gas; said make-up gas is purified by shift conversion and removal of carbon dioxide; carbon dioxide is removed from the make-up gas by a first and a second CO2 removal sections; the first section removes CO2 by absorption with a suitable medium, and the second section removes CO2 by washing with a carbamate solution taken from the urea section; the make-up gas is reacted to produce ammonia; the CO2 removed from the make-up gas and at least part of the ammonia are used to produce urea.