A method is described for generating carbon-neutral electricity using purified hydrogen as an energy source. A recyclable LOHC is provided to the process for reversible dehydrogenation. Hydrogen generated by dehydrogenation is purified and electrochemically converted to electricity. Heat for maintaining the dehydrogenation reaction temperature is derived from combustion of a portion of the liquid products from dehydrogenation, the portion combusted being less than or equal to the portion of carbon-neutral component included in the recyclable LOHC.

A method is described for generating carbon-neutral electricity using purified hydrogen as an energy source. A recyclable LOHC is provided to the process for reversible dehydrogenation. Hydrogen generated by dehydrogenation is purified and electrochemically converted to electricity. Heat for maintaining the dehydrogenation reaction temperature is derived from combustion of a portion of the liquid products from dehydrogenation, the portion combusted being less than or equal to the portion of carbon-neutral component included in the recyclable LOHC.

Provided is a hydrogen storage system including a solution including ethylenediamine bisborane (EDAB) and ethylenediamine (ED), in which the hydrogen storage system is capable of performing a reversible dehydrogenation/hydrogenation reaction at a temperature of 20 C. to 200 C. in the presence of a heterogeneous metal catalyst including ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Jr), platinum (Pt), nickel (Ni), iron (Fe), cobalt (Co), or a combination thereof.

The present disclosure relates generally to portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power. In particular, an electricity generation device for powering a battery comprising a formic acid reservoir containing a liquid consisting of formic acid; a reaction chamber capable of using a catalyst and heat to convert the formic acid to hydrogen and carbon dioxide; a fuel cell that generates electricity; a delivery system for moving converted hydrogen into the fuel cell; and a battery powered by electricity generated by the fuel cell is provided.

The present disclosure relates generally to portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power. In particular, an electricity generation device for powering a battery comprising a formic acid reservoir containing a liquid consisting of formic acid; a reaction chamber capable of using a catalyst and heat to convert the formic acid to hydrogen and carbon dioxide; a fuel cell that generates electricity; a delivery system for moving converted hydrogen into the fuel cell; and a battery powered by electricity generated by the fuel cell is provided.

A catalyst composition for manufacturing a catalyst for hydrogen production based on thermochemical reaction of methanol is disclosed. The catalyst composition includes a support component and an active component. The support component includes cement and clay, wherein a weight ratio of the cement to the clay is 3/7 to 9/1. The active component includes copper oxide or a precursor of copper oxide. Based on 100 parts by weight of the support component, a content of the active component is 5 to 10 parts by weight.

The present disclosure refers in one embodiment to processes for making and transporting clean hydrogen fuel. The processes may involve hydrotreating, hydrocracking, or both hydrotreating and hydrocracking an aromatic feedstock under conditions to obtain a liquid hydrocarbon fuel. The liquid hydrocarbon fuel is hydrogenated to obtain a hydrogen-rich fuel that is transported to a dehydrogenation facility that may also be at or near a hydrogen station. The hydrogen-rich fuel is used to obtain hydrogen and a second liquid hydrocarbon fuel.

The present invention provides novel diamine-monoborane liquid organic hydrogen carriers with hydrogen storage capacities at least equivalent to prior art hydrogen carriers. The novel diamine-monoboranes of the invention provide advantages over the prior art including low cost due to the simple one-step chemical synthesis method between a diamine and a borane complex, and that the starting materials are inexpensive compared to the prior art. The novel diamine-monoboranes of the invention provide excellent dehydrogenation performance. With the presence of inexpensive and readily-available commercial catalysts, dehydrogenation occurs at ambient temperatures and pressures with high hydrogen purity. The resulting 1,3,2-diazaborolidines (cyclic diaminoboranes) are readily hydrogenated to produce the novel diamine-monoboranes of the invention. The invention also provides use of the diamine-monoboranes of the invention in a fuel cell or a portable power cell, or cell installed in conjunction with a hydrogen-burning engine. Other uses relate to transport down pipelines and in tankers.

A process and system for preparing C.sub.2 to C.sub.5 hydrocarbons includes introducing a feed stream containing hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a first reaction zone, contacting the feed stream and a hybrid catalyst in the first reaction zone, introducing a reaction zone product stream into a water removal zone that is downstream from the first reaction zone, and introducing a product stream from the water removal zone into a second reaction zone, resulting in a final stream comprising C.sub.2 to C.sub.5 hydrocarbons. The hybrid catalyst includes a methanol synthesis component and a microporous solid acid component; the microporous solid acid component is a molecular sieve having 8-MR access. The water removal zone removes at least a portion of water from the reaction zone product stream.

A process and system for preparing C.sub.2 to C.sub.5 hydrocarbons includes introducing a feed stream containing hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a first reaction zone, contacting the feed stream and a hybrid catalyst in the first reaction zone, introducing a reaction zone product stream into a water removal zone that is downstream from the first reaction zone, and introducing a product stream from the water removal zone into a second reaction zone, resulting in a final stream comprising C.sub.2 to C.sub.5 hydrocarbons. The hybrid catalyst includes a methanol synthesis component and a microporous solid acid component; the microporous solid acid component is a molecular sieve having 8-MR access. The water removal zone removes at least a portion of water from the reaction zone product stream.