C01B3/22

Enhanced processes to produce value-added products from light gases

Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

Hydrogen production catalyst containing Ni3Si-based intermetallic compound, method for activating the catalyst, and hydrogen production method and device using the catalyst

A catalyst according to the present invention exhibits a catalytic action to a methanol decomposition reaction or a hydrocarbon steam-reforming reaction in a short time. The present invention provides a catalyst for producing hydrogen gas, using an Ni.sub.3Si-based intermetallic compound.

Hydrogen production catalyst containing Ni3Si-based intermetallic compound, method for activating the catalyst, and hydrogen production method and device using the catalyst

A catalyst according to the present invention exhibits a catalytic action to a methanol decomposition reaction or a hydrocarbon steam-reforming reaction in a short time. The present invention provides a catalyst for producing hydrogen gas, using an Ni.sub.3Si-based intermetallic compound.

Hydrogen extraction reactor and hydrogen extraction process using phase change materials

According to one embodiment of the present invention, there is provided a hydrogen extraction reactor, comprising a chamber including an inner space; a reaction unit which is provided to pass through the inside of the chamber and where an endothermic reaction for hydrogen extraction occurs; a heating unit which is provided to be spaced apart from the reaction unit inside the chamber and transfers heat to the inside of the chamber; and a heat transfer material which is provided between the reaction unit and the heating unit in the chamber, wherein the heat transfer material undergoes a phase transition between a gas phase and a liquid phase according to the entry and exit of heat from the heating unit or the reaction unit.

PROCESS FOR IMPROVING THE QUALITY OF HYDROGEN-BEARING ORGANIC LIQUIDS
20230174374 · 2023-06-08 ·

The present invention relates to a process for producing hydrogen from a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, said process comprising at least one step wherein said liquid is brought into contact with a filtering agent. The invention also relates to the use of a filtering agent for the purification of a liquid capable of being used in at least one hydrogenation/dehydrogenation cycle, in a hydrogen production process.

A STRUCTURED CATALYST

A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas Including at least one macroscopic structure of an electrically conductive material and at least one connector attached to the at least one macroscopic structure, wherein the macroscopic structure supports a catalytically active material.

A STRUCTURED CATALYST

A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas Including at least one macroscopic structure of an electrically conductive material and at least one connector attached to the at least one macroscopic structure, wherein the macroscopic structure supports a catalytically active material.

DEHYDROGENATION OF NEAT FORMIC ACID

A formic acid decomposition catalyst system includes organometallic complexes having formula 1:

##STR00001##

wherein: M is a transition metal; E is P, N, or C (as in imidazolium carbene); R.sub.1, R.sub.2 are independently C.sub.1-6 alkyl groups; o is 1, 2, 3, or 4; R.sub.3 are independently hydrogen, C.sub.1-6 alkyl groups, OR.sub.14, NO.sub.2, halogen; R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13, R.sub.15, R.sub.16 are independently hydrogen or C.sub.1-6 alkyl groups; R.sub.14 is a C.sub.1-6 alkyl group; and X.sup.−is a negatively charge counter ion.

DEHYDROGENATION OF NEAT FORMIC ACID

A formic acid decomposition catalyst system includes organometallic complexes having formula 1:

##STR00001##

wherein: M is a transition metal; E is P, N, or C (as in imidazolium carbene); R.sub.1, R.sub.2 are independently C.sub.1-6 alkyl groups; o is 1, 2, 3, or 4; R.sub.3 are independently hydrogen, C.sub.1-6 alkyl groups, OR.sub.14, NO.sub.2, halogen; R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13, R.sub.15, R.sub.16 are independently hydrogen or C.sub.1-6 alkyl groups; R.sub.14 is a C.sub.1-6 alkyl group; and X.sup.−is a negatively charge counter ion.

Electricity generation devices using formic acid

The present disclosure relates generally to new forms of portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power.