A dihydrogen generator (5) comprising a chamber (10), a reservoir (260) for containing a reagent and a catalytic system (15), the chamber being impervious to dihydrogen and defining an internal chamber space (45), the reservoir being housed in the internal chamber space and comprising a reservoir wall (270, 275) impervious to a liquid and permeable to dihydrogen, the catalytic system being disposed at least partly in the reservoir and comprising a catalyst (205) for the reaction that generates dihydrogen from the reagent, the chamber comprising a discharge valve (300) for withdrawing the dihydrogen from the internal chamber space, an injection valve (295) for injecting the liquid into the reservoir and a drain valve (460) for draining the liquid from the reservoir.

A reactor system and a process for carrying out the methanol cracking and reverse water gas shift reaction of a feedstock comprising methanol to synthesis gas are provided, where the heat for the endothermic methanol cracking and reverse water gas shift reaction is provided by resistance heating.

A catalyst composition includes a liquid metal alloy having a melting point from about 20° C. to about 25° C., the liquid metal alloy including a primary metal and a secondary metal, the primary metal being aluminum and the secondary metal is selected from the group consisting of gallium, indium, and bismuth.

The present disclosure relates to a method for separating a carbon isotope and a method for concentrating a carbon isotope using the same, the method for separating a carbon isotope including: cooling a formaldehyde gas to a temperature of from 190K to 250K; and obtaining a mixed gas and residual formaldehyde by photodissociating the cooled formaldehyde gas, the mixed gas including carbon dioxide containing a carbon isotope and hydrogen.

The present disclosure relates to a method for separating a carbon isotope and a method for concentrating a carbon isotope using the same, the method for separating a carbon isotope including: cooling a formaldehyde gas to a temperature of from 190K to 250K; and obtaining a mixed gas and residual formaldehyde by photodissociating the cooled formaldehyde gas, the mixed gas including carbon dioxide containing a carbon isotope and hydrogen.

A hybrid dehydrogenation reaction system includes: an acid aqueous solution tank having an acid aqueous solution; an exothermic dehydrogenation reactor including a chemical hydride of a solid state and receiving the acid aqueous solution from the acid aqueous solution tank for an exothermic dehydrogenation reaction of the chemical hydride and the acid aqueous solution to generate hydrogen; an LOHC tank including a liquid organic hydrogen carrier (LOHC); and an endothermic dehydrogenation reactor receiving the liquid organic hydrogen carrier from the LOHC tank and generating hydrogen through an endothermic dehydrogenation reaction of the liquid organic hydrogen carrier by using heat generated from the exothermic dehydrogenation reactor.

The present disclosure relates generally to a carbon-neutral process for the generation of carbon-neutral hydrogen and carbon-neutral electricity. More specifically, the present disclosure relates to compositions, methods and apparatus employing a carbon-neutral process for generating electricity employing a liquid organic hydrogen carrier (LOHC) for supplying hydrogen for generating the carbon neutral electricity. The present disclosure also relates more specifically to carbon-neutral compositions consisting of liquid organic hydrogen carriers used for supplying hydrogen to generate electricity that may be regenerated in a carbon-neutral process using an apparatus with a net zero atmospheric emission of carbon oxides.

A method is described for generating carbon-neutral electricity using purified hydrogen as an energy source. A recyclable LOHC is provided to the process for reversible dehydrogenation. Hydrogen generated by dehydrogenation is purified and electrochemically converted to electricity. Heat for maintaining the dehydrogenation reaction temperature is derived from combustion of a portion of the liquid products from dehydrogenation, the portion combusted being less than or equal to the portion of carbon-neutral component included in the recyclable LOHC.

This invention provides a reversible hydrogen loading and discharging system and a reversible method for loading and discharging hydrogen. The system and the methods of this invention comprise ethylene glycol as a liquid organic hydrogen carrier and at least one transition metal. By reacting ethylene glycol with at least one transition metal; at least one hydrogen molecule and at least one oligoester of ethylene glycol are formed (hydrogen releasing)⋅, and by reacting at least one oligoester of ethylene glycol with at least one transition metal and at least one hydrogen molecule, at least one ethylene glycol is formed (hydrogen loading).

Hydrogen generation assemblies, hydrogen purification devices, and their components are disclosed. In some embodiments, the devices may include a permeate frame with a membrane support structure having first and second membrane support plates that are free from perforations and that include a plurality of microgrooves configured to provide flow channels for at least part of the permeate stream. In some embodiments, the assemblies may include a return conduit fluidly connecting a buffer tank and a reformate conduit, a return valve assembly configured to manage flow in the return conduit, and a control assembly configured to operate a fuel processing assembly between run and standby modes based, at least in part, on detected pressure in the buffer tank and configured to direct the return valve assembly to allow product hydrogen stream to flow from the buffer tank to the reformate conduit when the fuel processing assembly is in the standby mode.