C01B7/07

Process for producing magnesium metal by dehydrating dihydrate magnesium chloride
10617995 · 2020-04-14 · ·

The present description relates to a process for producing magnesium metal from dihydrate magnesium chloride comprising the steps of dehydrating MgCI.sub.2.2H.sub.2O with anhydrous hydrochloric acid (HCI) to obtain anhydrous magnesium chloride in an inert environment, releasing the mixture of hydrous HCI and protection gas; and electrolyzing the anhydrous magnesium chloride in an electrolytic cell fed with hydrogen gas under free oxygen atmosphere content, wherein magnesium metal and anhydrous hydrogen chloride are produced, wherein a part of the hydrous HCI is passed through a scrubbing unit to obtain a hydrochloric acid solution, the other part of the hydrochloric chloride gas is dehydrated by contact with a desiccant agent in a drying unit to produce anhydrous HCI, and wherein the anhydrous HCI produced by at least one of the electrolytic cell and the drying unit is reused to dehydrate the of MgCI.sub.2.2H.sub.2O.

Hydrogen gas recovery system and hydrogen gas separation and recovery method

A hydrogen gas recovery system according to the present ingestion is configured by a condensation and separation apparatus (A) that condenses and separates chlorosilanes from a hydrogen-containing reaction exhaust gas exhausted from a polycrystalline silicon production step, a compression apparatus (B) that compresses the hydrogen-containing reaction exhaust gas, an absorption apparatus (C) that absorbs and separates hydrogen chloride by contacting the hydrogen-containing reaction exhaust gas with an absorption liquid, a first adsorption apparatus (D) comprising an adsorption column filled with activated carbon for adsorbing and removing methane, hydrogen chloride, and part of the chlorosilanes each contained in the hydrogen-containing reaction exhaust gas, a second adsorption apparatus (E) comprising an adsorption column filled with synthetic zeolite that adsorbs and removes methane contained in the hydrogen-containing reaction exhaust gas, and a gas line (F) that recovers a purified hydrogen gas having a reduced concentration of methane.

Method for producing hydrogen chloride
10611636 · 2020-04-07 · ·

Provided is a method for producing a hydrogen chloride that is capable of efficiently producing a hydrogen chloride with a simple facility. The hydrogen chloride is produced by a method including causing an inert gas to be in gas-liquid contact with a hydrochloric acid in which a concentration is 20 mass % to 50 mass %, distilling the hydrochloric acid with which the inert gas is in gas-liquid contact in the gas-liquid contact and separating a hydrogen chloride from the hydrochloric acid to obtain a crude hydrogen chloride, dehydrating the crude hydrogen chloride obtained in the separating, and compressing and liquefying the dehydrated crude hydrogen chloride obtained in the dehydrating, and purifying the liquid crude hydrogen chloride by distillation.

Method for producing hydrogen chloride
10611636 · 2020-04-07 · ·

Provided is a method for producing a hydrogen chloride that is capable of efficiently producing a hydrogen chloride with a simple facility. The hydrogen chloride is produced by a method including causing an inert gas to be in gas-liquid contact with a hydrochloric acid in which a concentration is 20 mass % to 50 mass %, distilling the hydrochloric acid with which the inert gas is in gas-liquid contact in the gas-liquid contact and separating a hydrogen chloride from the hydrochloric acid to obtain a crude hydrogen chloride, dehydrating the crude hydrogen chloride obtained in the separating, and compressing and liquefying the dehydrated crude hydrogen chloride obtained in the dehydrating, and purifying the liquid crude hydrogen chloride by distillation.

METHOD FOR PRODUCING POTASSIUM SULFATE FROM POTASSIUM CHLORIDE AND SULFURIC ACID

A process is provided for producing potassium sulfate from potassium chloride and sulfuric acid. The process entails mixing potassium chloride with the water to form a potassium chloride slurry which is mixed with recycled sulfuric acid to form a K.sup., Ct, SO.sub.4.sup.2 acid mixture. This mixture is subjected to a crystallization process that produces potassium sulfate crystals and a hydrochloric acid-water vapor. The hydrochloric acid is separated from the hydrochloric acid-water vapor to form a hydrochloric acid solution.

Hydrochloric acid purification process and plant

Disclosed is a process for treating a gas stream containing hydrochloric acid, hydrofluoric acid, a fluorinated compound and halogenated organic compounds, wherein the gas stream is subjected to: (a) a step of washing with an acid solution to obtain a washed gas stream; (b) a step of adiabatic absorption in an aqueous solution of the hydrochloric acid contained in said washed gas stream, to collect a solution of hydrochloric acid; (c) a step of adsorption on activated carbon of the impurities present in said hydrochloric acid solution, to obtain a purified hydrochloric acid solution and a gas stream containing said fluorinated compound; and (d) a step of bringing said purified hydrochloric acid solution into contact with a silica gel. Also disclosed is a plant for the implementation of this process, and also a process for preparing a fluorinated compound comprising the catalytic pyrolysis of an organofluorine compound.

Storage medium and method for separating, storing and transporting chlorine from chlorine-containing gases

The invention relates to a storage medium and to a method for using a storage medium based on ionic compounds, which can reversibly absorb and store chlorine and chlorine from process gases, and which can release the same again by changing the ambient conditions, wherein the storage medium can be reused for this task after discharge.

METHOD FOR FLEXIBLY CONTROLLING THE USE OF HYDROCHLORIC ACID FROM CHEMICAL PRODUCTION

The invention relates to a method for flexibly controlling the use of hydrochloric acid having an HCl concentration of at least 10 wt %, in particular at a volume flow rate of at least 1 m.sup.3/h, obtained from a continuous chemical production process (A). In the method, purified hydrochloric acid (54) from a hydrochloric acid store (E) is optionally fed to a dispatch station (H), an HCl electrolysis station (F) and a chloralkali electrolysis station (L), which are consumption points for the hydrochloric acid, or to a neutralisation station (G) in that if one or more of said consumption points (H, F, L) is not available or if there are bottlenecks at the consumption points (H, F, L), the hydrochloric acid (54) is fed to the neutralisation station (G) and neutralised with concentrated alkali solution (55), in particular with concentrated sodium hydroxide solution, and the resulting salt solution (56) is fed either to the chloralkali process station (L) or to a disposal station (M).

Method and device for regeneration of hydrochloric acid
10494259 · 2019-12-03 · ·

The subject matter of the present invention is a method to extract or recover hydrochloric acid from hydrochloric acid solutions containing metal by means of pyrohydrolytic treatment, followed by absorption and/or condensation of the gaseous hydrogen chloride thus formed in order to form hydrochloric acid. According to the invention, a first partial flow of the hydrochloric acid solution containing metal undergoes pyrohydrolytic treatment and a second partial flow of the metal-containing solution is fed to the absorption column. A device for implementing the process according to the invention is also the subject of the present invention.

Method and device for regeneration of hydrochloric acid
10494259 · 2019-12-03 · ·

The subject matter of the present invention is a method to extract or recover hydrochloric acid from hydrochloric acid solutions containing metal by means of pyrohydrolytic treatment, followed by absorption and/or condensation of the gaseous hydrogen chloride thus formed in order to form hydrochloric acid. According to the invention, a first partial flow of the hydrochloric acid solution containing metal undergoes pyrohydrolytic treatment and a second partial flow of the metal-containing solution is fed to the absorption column. A device for implementing the process according to the invention is also the subject of the present invention.